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Magnetic Properties and the Arrangement of Molecular Oxygen Adsorbed in the Microporous Coordination Polymer Cd(bpndc)(bpy)

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Abstract

The magnetic properties of O2 adsorbed in the microporous coordination polymer Cd(bpndc)(bpy) were investigated by means of high-field magnetization measurement. The magnetization of adsorbed O2 has a paramagnetic-like behavior in the low-field region and increases steeply above 50 T. The experiment results suggest that the half of adsorbed O2 that forms O2–O2 dimer causes the metamagnetic-like behavior and the remaining O2 causes paramagnetic-like behavior owing to nearly isolated spin. A possible arrangement of O2 is suggested.

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Authors and Affiliations

  1. Graduate School of Natural Science and Technology, Okayama University, Okayama, 700-8530, Japan

    A. Hori, T. Yamaguchi & T. C. Kobayashi

  2. Institute for Solid State Physics, The University of Tokyo, Kashiwa, Chiba, 277-8581, Japan

    A. Matsuo & K. Kindo

  3. Graduate School of Engineering, Kyoto University, Katsura, 615-8510, Japan

    D. Tanaka & S. Kitagawa

  4. Institute for Integrated Cell-Material Sciences, Kyoto University, Kyoto, 606-8501, Japan

    S. Kitagawa

  5. JST Kitagawa Integrated Pore Project, ERATO, Kyoto, 600-8815, Japan

    S. Kitagawa

Authors
  1. A. Hori
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  2. T. Yamaguchi
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  3. T. C. Kobayashi
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  4. A. Matsuo
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  5. K. Kindo
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  6. D. Tanaka
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  7. S. Kitagawa
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Correspondence to A. Hori.

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Hori, A., Yamaguchi, T., Kobayashi, T.C. et al. Magnetic Properties and the Arrangement of Molecular Oxygen Adsorbed in the Microporous Coordination Polymer Cd(bpndc)(bpy). J Low Temp Phys 159, 122–125 (2010). https://doi.org/10.1007/s10909-009-0084-8

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  • DOI: https://doi.org/10.1007/s10909-009-0084-8

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