Abstract
Metal sulfide/carbon composite reveals to be a prospective electrode material for lithium-ion batteries due to the synergy of the two components, and their structure greatly determines the electrochemical performance. We herein have successfully fabricated an in situ encapsulation of Ni3S2 nanoparticles into carbon nanowalls (Ni3S2/CNWs) with three-dimensional interconnected porous structures, which are synthesized assisted by cation adsorption and following hydrothermal process. The abundant mesoporous carbon nanowalls are used as both conductive matrix and protective layer to alleviate the volume change of Ni3S2. Benefiting from the superior theoretical capacity of Ni3S2 and unique structure of CNWs, Ni3S2/CNWs-1 anodes show the high discharge capacity of 906 mAh g−1 at 200 mA g−1 after cycling 200 times, outstanding rate capacity of 567 mAh g−1 at 5 A g−1 and super-long cycling life of 666 mAh g−1 at 2 A g−1 after cycling 1000 times. More importantly, the button-type full cells based on Ni3S2/CNWs-1 anodes and LiFePO4 cathodes present excellent cycling stability and practicality.
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References
Wu N, Yang Y, Jia T, Li T, Li F, Wang Z (2020) Sodium-tin metal-organic framework anode material with advanced lithium storage properties for lithium-ion batteries. J Mater Sci 55:6030–6036. https://doi.org/10.1007%2Fs10853-020-04436-6
Shuang W, Kong L, Zhong M, Wang D, Liu J, Bu XH (2018) Rational design of Co embedded N, S-codoped carbon nanoplates as anode materials for high performance lithium-ion batteries. Dalton Trans 47:12385–12392
Yu XW, Manthiram A (2018) Electrode-electrolyte interfaces in lithium-based batteries. Energy Environ Sci 11:527–543
Meng L, Guo R, Li F, Ma Y, Peng J, Zhao J, Sang Z, Li T, Luo Y, Lu Y, Sun X (2020) Hierarchical porous LixV2O4/C anode assembled with nanoflake for high-performance lithium-ion battery. J Mater Sci 55:5522–5533. https://doi.org/10.1007/s10853-020-04388-x
Liu Y, Zhong M, Kong L, Li A, Sun X, Wang D, Bu XH (2019) Fe1−xS/nitrogen and sulfur co-doped carbon composite derived from a nanosized metal-organic framework for high-performance lithium-ion batteries. Inorg Chem Front 6:50–56
Duan W, Yan W, Yan X, Munakata H, Jin Y, Kanamura K (2015) Synthesis of nanostructured Ni3S2 with different morphologies as negative electrode materials for lithium ion batteries. J Power Sources 293:706–711
Geng H, Kong SF, Wang Y (2014) NiS nanorod-assembled nanoflowers grown on graphene: morphology evolution and Li-ion storage applications. J Mater Chem A 2:15152–15158
Lin YM, Qiu ZZ, Li DZ, Ullah S, Hai Y, Xin HL, Liao WD, Yang B, Fan HS, Xu J, Zhu CZ (2018) NiS2@CoS2 nanocrystals encapsulated in N-doped carbon nanocubes for high performance lithium/sodium ion batteries. Energy Storage Mater 11:67–74
Jin RC, Zhou JH, Guan YS, Liu H, Chen G (2014) Mesocrystal Co9S8 hollow sphere anodes for high performance lithium ion batteries. J Mater Chem A 2:13241–13244
Wang Y, Niu YB, Li CM (2017) The effect of the morphologies of Ni3S2 anodes on the performance of lithium-ion batteries. ChemSel 2:4445–4451
Zhang S, Lin R, Yue W, Niu F, Ma J, Yang X (2017) Novel synthesis of metal sulfides-loaded porous carbon as anode materials for lithium-ion batteries. Chem Eng J 314:19–26
Li D, Li X, Hou X, Sun X, Liu B, He D (2014) Building a Ni3S2 nanotube array and investigating its application as an electrode for lithium ion batteries. Chem Commun 50:9361–9364
Du JM, Kang DJ (2007) A shape-controlled method to functionalize multiwalled carbon nanotubes with Ni3S2. Inorg Chem 46:10307–10311
Wu XY, Li SM, Xu YY, Wang B, Liu JH, Yu M (2019) Hierarchical heterostructures of NiO nanosheet arrays grown on pine twig-like beta-NiS@Ni3S2 frameworks as free-standing integrated anode for high-performance lithium-ion batteries. Chem Eng J 356:245–254
Jiang JL, Ma C, Yang YB, Ding JJ, Ji HM, Shi SJ, Yang G (2018) Synergetic interface between NiO/Ni3S2 nanosheets and carbon nanofiber as binder-free anode for highly reversible lithium storage. Appl Surf Sci 441:232–238
Guerra A, Achour A, Vizireanu S, Dinescu G, Messaci S, Hadjersi T, Boukherroub R, Coffinier Y, Pireaux JJ (2019) ZnO/carbon nanowalls shell/core nanostructures as electrodes for supercapacitors. Appl Surf Sci 481:926–932
Kim AY, Ardhi REA, Liu G, Kim JY, Shin HJ, Byun D, Lee JK (2019) Hierarchical hollow dual Core-Shell carbon nanowall-encapsulated p–n SnO/SnO2 heterostructured anode for high-performance lithium-ion-based energy storage. Carbon 153:62–72
Wang XH, Shi B, Wang XQ, Gao J, Zhang C, Yang ZZ, Xie HF (2017) One-step synthesis of V2O5/Ni3S2 nanoflakes for high electrochemical performance. J Mater Chem A 5:23543–23549
Liu W, Xu H, Qin H, Lv Y, Zhu G, Lei X, Lin F, Zhang Z, Wang L (2020) Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes. J Mater Sci 55:4382–4394. https://doi.org/10.1007/s10853-019-04313-x
Huang P, Zhang M, Kang J, Feng H, Su Q, Du G, Yu Y, Xu B (2019) Rapid microwave-irradiation synthesis of ZnCo2O4/ZnO nanocrystals/carbon nanotubes composite as anodes for high-performance lithium-ion battery. J Mater Sci 54:4154–4167. https://doi.org/10.1007/s10853-018-3119-1
Shuang W, Huang H, Kong LJ, Zhong M, Li A, Wang DH, Xu YH, Bu XH (2019) Nitrogen-doped carbon shell-confined Ni3S2 composite nanosheets derived from Ni-MOF for high performance sodium-ion battery anodes. Nano Energy 62:154–163
Wang W, Zeng P, Li J, Zhao Y, Chen M, Shao J, Fang Z (2018) Ultrathin nanosheets assembled hierarchical Co/NiSx@C hollow spheres for reversible lithium storage. ACS Appl Nano Mater 1:3435–3445
Kong L, Zhu J, Shuang W, Bu XH (2018) Nitrogen-doped wrinkled carbon foils derived from MOF nanosheets for superior sodium storage. Adv Energy Mater 8:1801515
Li J, Li J, Chen T, Lu T, Mai W, Pan L (2019) Metal chelate induced in situ wrapping of Ni3S2 nanoparticles into N, S-codoped carbon networks for highly efficient sodium storage. Inorg Chem Front 6:694–704
Tang T, Cui S, Chen W, Hou H, Mi L (2019) Bio-inspired nano-engineering of an ultrahigh loading 3D hierarchical Ni@NiCo2S4/Ni3S2 electrode for high energy density supercapacitors. Nanoscale 11:1728–1736
Qie L, Chen WM, Xiong XQ, Hu CC, Zou F, Hu P, Huang YH (2015) Sulfur-doped carbon with enlarged interlayer distance as a high-performance anode material for sodium-ion batteries. Adv Sci 2:1500195
Wang F, Zhu Y, Tian W, Lv X, Zhang H, Hu Z, Zhang Y, Ji J, Jiang W (2018) Co-doped Ni3S2@CNT arrays anchored on graphite foam with a hierarchical conductive network for high-performance supercapacitors and hydrogen evolution electrodes. J Mater Chem A 6:10490–10496
Xu H, Zhu G, Hao B (2020) Metal-organic frameworks derived flower-like Co3O4/nitrogen doped graphite carbon hybrid for high-performance sodium-ion batteries. J Mater Sci Technol 35:100–108
Wang C, Han Q, Xie R, Wang B, He T, Xie W, Tang Q, Li Y, Xu J, Yu B (2020) Fabrication of petal-like Ni3S2 nanosheets on 3D carbon nanotube foams as high-performance anode materials for Li-ion batteries. Electrochim Acta 331:135383
Zhu JS, Hu GZ (2016) Facile synthesis of three-dimensional porous Ni3S2 electrode with superior lithium ion storage. Mater Lett 166:307–310
Zhao C, Shen Z, Tu F, Hu Z (2020) Template directed hydrothermal synthesis of flowerlike NiSex/C composites as lithium/sodium ion battery anodes. J Mater Sci 55:3495–3506. https://doi.org/10.1007/s10853-019-04200-5
Ge P, Zhang C, Hou H, Wu B, Zhou L, Li S, Wu T, Hu J, Mai L, Ji X (2018) Anions induced evolution of Co3X4 (X = O, S, Se) as sodium-ion anodes: The influences of electronic structure, morphology, electrochemical property. Nano Energy 48:617–629
Song Y, Chen ZL, Li YM, Wang QC, Fang F, Zhou YN, Hu LF, Sun DL (2017) Pseudocapacitance-tuned high-rate and long-term cyclability of NiCo2S4 hexagonal nanosheets prepared by vapor transformation for lithium storage. J Mater Chem A 5:9022–9031
Hou BH, Wang YY, Liu DS, Gu ZY, Feng X, Fan HS, Zhang TF, Lü CL, Wu XL (2018) N-doped carbon-coated Ni1.8Co1.2Se4 nanoaggregates encapsulated in N-doped carbon nanoboxes as advanced anode with outstanding high-rate and low-temperature performance for sodium-ion half/full batteries. Adv Funct Mater 28:1805444
Zhang Z, Zhao H, Xia Q, Allen J, Zeng Z, Gao C, Li Z, Du X, Świerczek K (2016) High performance Ni3S2/Ni film with three dimensional porous architecture as binder-free anode for lithium ion batteries. Electrochim Acta 211:761–767
Dong X, Deng ZP, Huo LH, Zhang XF, Gao S (2019) Large-scale synthesis of NiS@N and S co-doped carbon mesoporous tubule as high performance anode for lithium-ion battery. J Alloys Compd 788:984–992
Fan HS, Yu H, Wu XL, Zhang Y, Luo ZZ, Wang HW, Guo YY, Madhavi S, Yan QY (2016) Controllable preparation of square nickel chalcogenide (NiS and NiSe2) nanoplates for superior Li/Na ion storage properties. ACS Appl Mater Inter 8:25261–25267
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant No. 51902040), the China Postdoctoral Science Foundation (No. 2017M622996), the China Postdoctoral Science Special Foundation (No. 2018T110959), the Sichuan Science and Technology Program (No. 19YYJC0129 and 20YYJC3821), and the Open Foundation of State Key Laboratory of Electronic Thin Films and Integrated Devices of UESTC (KFJJ201915).
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Chen, HJ., Wang, Y., Ma, XD. et al. Cation-adsorption-assisted Ni3S2/carbon nanowalls composites with three-dimensional interconnected porous structures for high-performance lithium-ion battery anodes. J Mater Sci 55, 17081–17093 (2020). https://doi.org/10.1007/s10853-020-05203-3
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DOI: https://doi.org/10.1007/s10853-020-05203-3