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Deposition, characterizations and photoelectrochemical performance of nanocrystalline Cu–In–Cd–S–Se thin films by hybrid chemical process

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Abstract

Nanocrystalline, uniform, pentanary mixed metal chalcogenide (PMMC) thin films of copper indium cadmium sulfoselenide (CuInCd(SSe)3) were successfully synthesized using simple, self-organized, arrested precipitation technique in an aqueous alkaline medium. The optical, structural, morphological, compositional and electrical properties of synthesized thin films were investigated as a function indium (In3+) concentration. An optical absorption study revealed that direct allowed transition and band gap energy decreases typically from 1.46 to 1.25 eV. The X-ray diffraction studies revealed that the PMMC thin films have a nanocrystalline nature and crystallite size increases with the increase in the In3+ concentration. Tuning of surface morphology from nanospheres to peas-like morphology with uniform, well-adhered distributed throughout the substrate surface were observed by field emission scanning electron microscopy micrographs. The high-resolution transmission electron microscopy images and selected area electron diffraction pattern were illustrated that compactly interconnected particles with nanocrystalline nature. Energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy results confirmed that synthesized thin films had an appropriate chemical purity. The electrical conductivity and thermoelectric power measurement indicates that, the films have n-type conductivity. A photoelectrochemical conversion efficiency of 2.40% was achieved with a current density of 2.87 mA/cm2. The developed route may provide an alternative approach to synthesize multinary metal chalcogenide thin-film solar cell. Furthermore, we have developed a predictive model of a CICSSe thin-film solar cell using the artificial neural network. The proposed model is useful for the integrated development environment for the predictive modeling and design of high-efficient solar cells.

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References

  1. Gao MR, Xu YF, Jiang J, Yu SH (2013) Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices. Chem Soc Rev 42:2986

    Article  Google Scholar 

  2. Santiago FF, Belmonte GG, Sero IM, Bisquert J (2011) Characterization of nanostructured hybrid and organic solar cells by impedance spectroscopy. Phys Chem Chem Phys 13:9083

    Article  Google Scholar 

  3. Waldau AJ (2004) Status of thin film solar cells in research, production and the market. Sol Energy 77:667

    Article  Google Scholar 

  4. Afzaal M, O’Brien P (2006) Recent developments in II–VI and III–VI semiconductors and their applications in solar cells. J Mater Chem 16:1597

    Article  Google Scholar 

  5. Selinsky RS, Ding Q, Faber MS, Wright JC, Jin S (2013) Quantum dot nanoscale heterostructures for solar energy conversion. Chem Soc Rev 42:2963

    Article  Google Scholar 

  6. Lewis NS (2007) Toward cost-effective solar energy use. Science 315:798

    Article  Google Scholar 

  7. Lewis NS, Nocera DG (2006) Powering the planet: chemical challenges in solar energy utilization. Proc Natl Acad Sci USA 103:15729

    Article  Google Scholar 

  8. Balzani V, Credi A, Venturi M (2008) Photochemical conversion of solar energy. Chemsuschem 1:26

    Article  Google Scholar 

  9. Kamat PV, Tvrdy K, Baker DR, Radich JG (2010) Beyond photovoltaics: semiconductor nanoarchitectures for liquid-junction solar cells. Chem Rev 110:6664

    Article  Google Scholar 

  10. Gratzel M (2001) Photoelectrochemical cells. Nature 414:338

    Article  Google Scholar 

  11. Sheikh A, Yengantiwar A, Deo M, Kelkar S, Ogale S (2013) Near-field plasmonic functionalization of light harvesting oxide-oxide heterojunctions for efficient solar photoelectrochemical water splitting: the AuNP/ZnFe2O4/ZnO system. Small 9(12):2091

    Article  Google Scholar 

  12. Zou Y, Li D, Yang D (2012) Colloidal synthesis of monodisperse quaternary CuInSSe nanocrystals. Mater Chem Phys 132:865

    Article  Google Scholar 

  13. Arnou P, Cooper CS, Malkov AV, Bowers JW, Walls JM (2015) Solution-processed CuIn(S, Se)2 absorber layers for application in thin film solar cells. Thin Solid Films 582:31

    Article  Google Scholar 

  14. Khot KV, Mali SS, Pawar NB, Kharade RR, Mane RM, Kondalkar VV, Patil PB, Patil PS, Hong C, Kim JH, Heo J, Bhosale PN (2014) Development of nanocoral-like Cd(SSe) thin films using an arrested precipitation technique and their application. New J Chem 38:5964

    Article  Google Scholar 

  15. Purohit A, Chander S, Nehra SP, Dhaka MS (2015) Effect of air annealing on structural, optical, morphological and electrical properties of thermally evaporated CdSe thin films. Physica E 69:342

    Article  Google Scholar 

  16. Kumar V, Sharma SK, Dwivedi DK (2012) Crystallographic, optical and electrical properties of low zinc content cadmium zinc sulphide composite thin films for photovoltaic applications. J Alloys Compd 512:351

    Article  Google Scholar 

  17. Gruszecki T, Holmstorm B (1993) Preparation of thin films of polycrystalline CdSe for solar energy conversion I. A. literature survey. Sol Energy Mater Sol Cells 31:227

    Article  Google Scholar 

  18. Heo J, Ahn H, Lee R, Han Y, Kim D (2003) Influence of ITO surface modification on the growth of CdS and on the performance of CdS/CdTe solar cells. Sol Energy Mater Sol Cells 75:193

    Article  Google Scholar 

  19. Xiong WW, Zhang G, Zhang Q (2014) New strategies to prepare crystalline chalcogenides. Inorg Chem Front 1:292

    Article  Google Scholar 

  20. Aldakov D, Lefrancois A, Reiss P (2013) Ternary and quaternary metal chalcogenide nanocrystals: synthesis, properties and applications. J Mater Chem C 1:3756

    Article  Google Scholar 

  21. Pawar NB, Kharade SD, Mali SS, Mane RM, Hong CK, Patil PS, Bhosale PN (2014) Effect of indium(III) content on photoelectrochemical performance of MoBi(2 − x)In x S5 thin films. Solid State Sci 35:10

    Article  Google Scholar 

  22. Khot KV, Mali SS, Pawar NB, Kharade RR, Mane RM, Patil PB, Patil PS, Hong CK, Kim JH, Heo J, Bhosale PN (2015) Simplistic construction of cadmium sulfoselenide thin films via a hybrid chemical process for enhanced photoelectrochemical performance. RSC Adv 5:40283

    Article  Google Scholar 

  23. Shen S, Zhao L, Zhou Z, Guo L (2008) Enhanced photocatalytic hydrogen evolution over Cu-doped ZnIn2S4 under visible light irradiation. J Phys Chem C 112:16148

    Article  Google Scholar 

  24. Kose S, Atay F, Bilgin V, Akyuz I, Ketenci E (2010) Optical characterization and determination of carrier density of ultrasonically sprayed CdS: Cu films. Appl Surf Sci 256:4299

    Article  Google Scholar 

  25. Cheng KW, Huang C, Yu Y, Li C, Shu C, Liu WL (2011) Photoelectrochemical performance of Cu-doped ZnIn2S4 electrodes created using chemical bath deposition. Sol Eng Mater Sol Cells 95:1940

    Article  Google Scholar 

  26. Khallaf H, Chai G, Lupan O, Chow L, Park S, Schulte A (2009) Characterization of gallium-doped CdS thin films grown by chemical bath deposition. Appl Surf Sci 255:4129

    Article  Google Scholar 

  27. Herberholz R, Carter MJ (1996) Investigation of the chalcogen interdiffusion in CuIn(TeSe)2 thin films. Sol Energy Mater Sol Cells 44:357

    Article  Google Scholar 

  28. Cullity BD (1957) The elements of X-ray diffraction, 1st edn. Addison Wesley Publishing Company Inc., Boston

    Google Scholar 

  29. Dai P, Zhang G, Chen Y, Jiang H, Feng Z, Lin Z, Zhan J (2012) Porous copper zinc tin sulfide thin film as photocathode for double junction photoelectrochemical solar cells. Chem Commun 48:3006

    Article  Google Scholar 

  30. Khot KV, Ghanwat VB, Bagade CS, Mali SS, Bhosale RR, Bagali AS, Dongale TD, Bhosale PN (2016) Synthesis of SnS2 thin film via non vacuum arrested precipitation technique for solar cell application. Mater Lett 180:23–26

    Article  Google Scholar 

  31. Gordilloa G, Calderon C, Bartolo-Perez P (2014) XPS analysis and structural and morphological characterization of Cu2ZnSnS4 thin films grown by sequential evaporation. Appl Surf Sci 305:506

    Article  Google Scholar 

  32. Riha SC, Parkinson BA, Prieto AL (2009) Solution-based synthesis and characterization of Cu2ZnSnS4 nanocrystals. J Am Chem Soc 131:12054

    Article  Google Scholar 

  33. Li WJ, Zhou YN, Fu ZW (2011) Fabrication and lithium electrochemistry of InSe thin film. Appl Surf Sci 257:2881

    Article  Google Scholar 

  34. Merdes S, Steigert A, Ziem F, Lauermann I, Klenk R, Hergert F, Kaufmann CA, Schlatmann R (2015) Influence of Cu(In, Ga)(Se, S)2 surface treatments on the properties of 30 × 30 cm2 large are a modules with atomic layer deposited Zn(O, S) buffers. Thin Solid Films 574:28

    Article  Google Scholar 

  35. Liu T, Hua Y, Chang W (2014) Characterization of Cu2−x Se thin films synthesized from electrochemical deposition. Mater Sci Eng, B 180:33

    Article  Google Scholar 

  36. Salunkhe MM, Khot KV, Patil PS, Bhave TM, Bhosale PN (2015) Novel route for the synthesis of surfactant-assisted MoBi2(Se0.5Te0.5)5 thin films for solar cell applications. New J Chem 39:3405

    Article  Google Scholar 

  37. Ronge J, Bosserez T, Martel D, Nervi C, Boarino L, Taulelle F, Decher G, Bordiga S, Martens JA (2014) Monolithic cells for solar fuels. Chem Soc Rev 43:7963

    Article  Google Scholar 

  38. Bignozzi CA, Caramori S, Cristino V, Argazzi R, Meda L, Tacca A (2013) Nanostructured photoelectrodes based on WO3: applications to photooxidation of aqueous electrolytes. Chem Soc Rev 42:2228

    Article  Google Scholar 

  39. Jana A, Bhattacharya C, Sinha S, Datta J (2009) Study of the optimal condition for electroplating of Bi2S3 thin films and their photoelectrochemical characteristics. J Solid State Electrochem 13:1339

    Article  Google Scholar 

  40. Fonash SJ (2010) Solar cell device physics, 2nd edn. Elsevier, Amsterdam

    Google Scholar 

  41. Hou H, Jiang Y, Li J, Yu S, Wang C (2012) Enhanced photoelectric performance of Cu2x Se nanostructure by doping with In3+. J Mater Chem 22:1950

    Article  Google Scholar 

  42. Dongale TD, Patil KP, Vanjare SR, Chavan AR, Gaikwad PK, Kamat RK (2015) Modelling of nanostructured memristor device characteristics using artificial neural network. J Comput Sci 11:82

    Article  Google Scholar 

  43. Dongale TD, Jadhav PR, Navathe GJ, Kim JH, Karanjkar MM, Patil PS (2015) Development of nano fiber MnO2 thin film electrode and cyclic voltammetry behavior modeling using artificial neural network for supercapacitor application. Mater Sci Semicond Process 36:43

    Article  Google Scholar 

  44. Dongale TD, Katkar SV, Khot KV, More KV, Delekar SD, Bhosale PN, Kamat RK (2016) Simulation of randomly textured tandem silicon solar cells using quadratic complex rational function approach along with artificial neural network. J Nanoeng Nanomanuf 6:103

    Article  Google Scholar 

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Acknowledgements

One of the authors Dr. Kishorkumar V. Khot is very much thankful to Department of Science and Technology (DST), New Delhi, for providing DST-INSPIRE fellowship for financial support (Registration No. IF130751). This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2009-0094055).

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Authors and Affiliations

  1. Materials Research Laboratory, Department of Chemistry, Shivaji University, Kolhapur, India

    Kishorkumar V. Khot & Popatrao N. Bhosale

  2. Department of General Engineering and Sciences, Sharad Institute of Technology, College of Engineering, Yadrav, Ichalkaranji, India

    Kishorkumar V. Khot

  3. Computational Electronics and Nanoscience Research Laboratory, School of Nanoscience and Biotechnology, Shivaji University, Kolhapur, India

    Tukaram D. Dongale

  4. Polymer Energy Materials Laboratory, Department of Advanced Chemical Engineering, Chonnam National University, Gwangju, South Korea

    Sawanta S. Mali & Chang Kook Hong

  5. Embedded System and VLSI Research Laboratory, Department of Electronics, Shivaji University, Kolhapur, 416004, India

    Rajanish K. Kamat

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  1. Kishorkumar V. Khot
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  2. Tukaram D. Dongale
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  3. Sawanta S. Mali
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Correspondence to Kishorkumar V. Khot or Popatrao N. Bhosale.

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Khot, K.V., Dongale, T.D., Mali, S.S. et al. Deposition, characterizations and photoelectrochemical performance of nanocrystalline Cu–In–Cd–S–Se thin films by hybrid chemical process. J Mater Sci 52, 9709–9727 (2017). https://doi.org/10.1007/s10853-017-1124-4

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