Abstract
New complexes of Cu2+, Hg2+, and Cd2+ with a recently synthesized Schiff base derived from 2-(3-hydroxy-1-methylbut-2-enylideneamino)pyridine-3-ol were applied for their simultaneous determination with artificial neural networks. A new analytical method using principal component-feed forward neural networks (PC-FFNNs) and principal component-radial basis function networks (PC-RBFNs) was used. Spectral data was reduced using principal component analysis and subjected to ANNs. The data obtained from synthetic mixtures of metal ions were processed by PC-FFNNs and PC-RBFNs. Performances of the proposed methods were tested with regard to relative standard error of prediction. Limit of detections and limit of quantifications were determined. The results obtained by PC-FFNNs and PC-RBFNs were compared to each other. Under the working conditions, the proposed methods were successfully applied to simultaneous determination of Hg2+, Cu2+, and Cd2+ in different water and soil samples. Concentrations of metal ions in the samples were also determined by flame atomic absorption spectrometry (FAAS) and standard addition method. The amounts of metal ions obtained by the proposed methods were in good agreement with those obtained by FAAS and standard addition method.
Similar content being viewed by others
References
Abbasi Tarighat, M., & Afkhami, A. (2012). Simultaneous spectrophotometric determination of Cu(II), Co(II) and Ni(II) using ratio spectra-continuous wavelet transformation in some food and environmental samples. Journal of Brazilian Chemical Society, 00, 1–8.
Abbasi Tarighat, M., Mohammadizadeh, M. R., & Abdi, G. R. (2013). Simultaneous spectrophotometric determination of Cd2+, Cu2+ and Zn2+ in rice and vegetal samples with dimethyl-spiro[isobenzofurane-1,6′-pyrorolo [2, 3-d] pyrimidine]-2′, 3, 4, 5′(1′H,3′H,7′H) tetraone using wavelet transformation-feed forward neural networks. Journal of Agricultural and Food Chemistry, 61, 6832–6840.
Abbasi-Tarighat, M., Shahbazi, E., & Niknam, K. H. (2013). Simultaneous determination of Mn2+ and Fe3+ as 4, 4′ [(4-cholorophenyl) methylene] bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) complexes in some foods, vegetable and water samples by artificial neural networks. Food Chemistry, 138, 991–997.
Afkhami, A., & Abbasi-Tarighat, M. (2009). Application of continuous wavelet transformation to the simultaneous kinetic determination of binary mixtures. Talanta, 78, 424–431.
Afkhami, A., Abbasi-Tarighat, M., & Bahram, M. (2008a). Artificial neural networks for determination of enantiomeric composition of α-phenylglycine using UV spectra of cyclodextrin host guest complexes comparison of feed-forward and radial basis function networks. Talanta, 75, 91–96.
Afkhami, A., Madrakian, T., & Abbasi-Tarighat, M. (2008b). Simultaneous determination of calcium, magnesium and zinc in different foodstuffs and pharmaceutical samples with continuous wavelet transforms. Food Chemistry, 109, 660–669.
Afkhami, A., Abbasi-Tarighat, M., & Khanmohammadi, H. (2009). Simultaneous determination of Co2+, Ni2+, Cu2+ and Zn2+ ions in foodstuffs and vegetables with a new Schiff base using artificial neural networks. Talanta, 77, 995–1001.
Amune, M., Christiana, O., & Samuel, K. (2012). Comparison of digestion methods for the determination of metal levels in soils in Itakpe Kogi State, Nigeria. International Journal of Pure and Applied Sciences and Technology, 13, 42–48.
Andrade-Garda, J. M. (2009). Basic chemometric techniques in atomic spectroscopy. Royal Society of Chemistry, 232.
Bressy, F. C., Brito, G. B., Barbosa, I. S., Teixeira, L. S. G., & Korn, M. G. A. (2013). Determination of trace element concentrations in tomato samples at different stages of maturation by ICP OES and ICP-MS following microwave-assisted digestion. Microchemica Journal, 109, 145–149.
Czél, B., Woodbury, K. A., & Gróf, G. (2014). Simultaneous estimation of temperature-dependent volumetric heat capacity and thermal conductivity functions via neural networks. International Journal of Heat and Mass Transfer, 68, 1–13.
Dondeti, S., Kannan, K., & Manavalan, R. (2005). Principal component artificial neural network calibration models for simultaneous spectrophotometric estimation of phenobarbitone and phenytoin sodium in tablets. Acta Chimica Slovenica, 52, 138–144.
Eshaghi, Z., Ali Hoseini, H., Mohammadi-Nokhandani, S. & Ebrahimi, J. (2013). Pseudo-stir bar hollow fiber solid/liquid phase microextraction combined with anodic stripping voltammetry for determination of lead and cadmium in water samples, Journal of Advanced Research, doi 10.1016/j.jare.2013.11.003
Gupta, S., Pandotra, P., Gupta, A. P., Dhar, J. K., Sharma, G., Ram, G., Husain, Y. M. K., & Bedi, S. (2010). Volatile (As and Hg) and non-volatile (Pb and Cd) toxic heavy metals analysis in rhizome of Zingiber officinale collected from different locations of North Western Himalayas by atomic absorption spectroscopy. Food and Chemical Toxicology, 48, 2966–2971.
Hasani, M, Yaghoubi, L. & Abdollahi H. (2006). H-point standard addition method for simultaneous determination of Fe(II), Co(II) and Cu(II) in micellar media with simultaneous addition of three analytes. Talanta, 28, 1528–1535.
Huang, C. H., & Hu, B. (2008). Silica-coated magnetic nanoparticles modified with γ-mercaptopropyltrimethoxysilane for fast and selective solid phase extraction of trace amounts of Cd, Cu, Hg, and Pb in environmental and biological samples prior to their determination by inductively coupled plasma mass spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 63, 437–444.
Ji, H., Li, S., Xin, H., & Cao, H. (2010). Simultaneous determination of calcium and magnesium in water using artificial neural network spectro-photometric method. Journal of Ocean University of China, 9, 229–234.
Li, C. P., & Jiang, S. J. (2003). Electrothermal vaporization inductively coupled plasma-mass spectrometry for the determination of Cr, Cu, Cd, Hg and Pb in rice flour. Analytica Chimica Acta, 495, 143–150.
Locatelli, C., & Melucci, D. (2012). Voltammetric determination of ultra-trace total mercury and toxic metals in meals. Food Chemistry, 130, 460–466.
Meucci, V., Laschi, S., Minunni, M., Pretti, C., Intorre, L., Soldani, G., & Mascini, M. (2009). An optimized digestion method coupled to electrochemical sensor for the determination of Cd, Cu, Pb and Hg in fish by square wave anodic stripping voltammetry. Talanta, 77, 1143–1148.
Mohammadi, K. H., & Abdeshah, M. (2012). Synthesis and characterization of some new 2 amino-3-hydroxypyridine schiff base compounds and their interactions with group 13 metal ions, synthesis and reactivity in inorganic. Metal-Organic, and Nano-Metal Chemistry, 42, 329–335.
Patterson, D. W. (1996). Artificial neural networks: theory and applications. Singapore: Prentice Hall.
Sardans, J., Montes, F., & Peñuelas, J. (2010). Determination of As Cd, Cu, Hg and Pb in biological samples by modern electrothermal atomic absorption spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 65, 97–112.
Shankar, T. N. (2008). Neural networks. New Delhi: Laxmi Publications Pvt Limited.
Tashkhourian, J., Hormozi-Nezhad, M. R., & Khodaveisi, J. (2011). Application of silver nanoparticles and principal component-artificial neural network models for simultaneous determination of levodopa and benserazide hydrochloride by a kinetic spectrophotometric method. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 82, 25–30.
Wong, S. L., & Lye, E. D. (2008). Lead, mercury and cadmium levels in Canadians. Health Reports, 19, 31–36.
Zupan, J., & Gastiger, J. (1999). Neural network in chemistry and drug design (2nd ed.). New York: Wily.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tarighat, M.A., Mohammadi, K. Simultaneous spectrophotometric determination of Cu2+, Hg2+, and Cd2+ ions using 2-(3-hydroxy-1-methylbut-2-enylideneamino)pyridine-3-ol. Environ Monit Assess 187, 197 (2015). https://doi.org/10.1007/s10661-015-4411-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10661-015-4411-z