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A novel synthesis of (3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4-vinylbenzyl)-9H-carbazole), alternating polymer formation, characterization, and capacitance measurements

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Abstract

In this work, (3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4-vinylbenzyl)-9H-carbazole) (EDOTVBCz) comonomer was chemically synthesized and characterized by Fourier transform infrared (FTIR), proton nuclear magnetic resonance, and carbon nuclear magnetic resonance spectroscopy. EDOTVBCz was electrocoated on glassy carbon electrode (GCE) in various initial molar concentrations ([EDOTVBCz]0 = 1.0, 1.5, 2.0, and 3.0) in 0.1 M lithium perchlorate (LiClO4)/acetonitrile (CH3CN). P(EDOTVBCz)/GCE was characterized by cyclic voltammetry, FTIR reflectance-attenuated total reflection spectroscopy, scanning electron microscopy–energy dispersive X-ray analysis, atomic force microscopy, and electrochemical impedance spectroscopy (EIS). EIS was used to determine the capacitive behaviors of modified GCE via Nyquist, Bode magnitude, Bode phase, and admittance plots. The highest low-frequency capacitance value was obtained as C LF = ∼2.35 mF cm−2 for [EDOTVBCz]0 = 3.0 mM. Double-layer capacitance of the polymer/electrolyte system was calculated as C dl = ∼2.78 mF cm−2 for [EDOTVBCz]0 = 1.0 and 3.0 mM. The maximum phase angle was obtained as θ = ∼76.7o for [EDOTVBCz]0 = 1.0, 1.5, 2.0, and 3.0 mM at the frequency of 20.6 Hz. AC impedance spectra of P(EDOTVBCz)/LiClO4/CH3CN was obtained by performing electrical equivalent circuit model of R(Q(R(CR))) with linear Kramers–Kronig test.

SEM-EDX analysis of P(EDOTVBCz)/CFME EDX point analysis inset: SEM point analysis, [EDOTVBCz]0 = 3 mM. Chronoamperometric method of constant potential at 1.6 V, 300 s in 0.1 M LiClO4/CH3CN

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Acknowledgement

This work supported by The Scientific & Technological Council of Turkey (TUBITAK)-TBAG-110T791 Project.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Namik Kemal University, Degirmenalti Campus, Tekirdag, 59030, Turkey

    Murat Ates, Nesimi Uludag, Tolga Karazehir & Fatih Arican

  2. Department of Chemistry, Faculty of Arts and Sciences, Istanbul Technical University, Istanbul, Maslak, Turkey

    Tolga Karazehir

Authors
  1. Murat Ates
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  2. Nesimi Uludag
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  3. Tolga Karazehir
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  4. Fatih Arican
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Correspondence to Murat Ates.

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Ates, M., Uludag, N., Karazehir, T. et al. A novel synthesis of (3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4-vinylbenzyl)-9H-carbazole), alternating polymer formation, characterization, and capacitance measurements. J Solid State Electrochem 17, 2417–2427 (2013). https://doi.org/10.1007/s10008-013-2117-0

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  • DOI: https://doi.org/10.1007/s10008-013-2117-0

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