Abstract
Resonance Ionization Mass Spectrometry (RIMS) is a sensitive and selective method for ultratrace analysis of long-lived radioisotopes and isotope ratio measurements. It provides extremely high isobaric suppression and good overall efficiency. The experimental limits of detection are as low as 106 atoms per sample and isotopic selectivities of 5×1012 have been obtained. The widespread potential of RIMS, using different experimental arrangements, is demonstrated for the determination of the radiotoxic isotopes Pu-238 to Pu-244 and Sr-89/Sr-90 in various environmental samples as well as for Ca-41 in nuclear reactor components and biomedical samples.
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Trautmann, N., Passler, G. & Wendt, K.D.A. Ultratrace analysis and isotope ratio measurements of long-lived radioisotopes by resonance ionization mass spectrometry (RIMS). Anal Bioanal Chem 378, 348–355 (2004). https://doi.org/10.1007/s00216-003-2183-8
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DOI: https://doi.org/10.1007/s00216-003-2183-8