Abstract
Sixty-five million year old continental flood basalts crop out on Qeqertarssuaq Island and the Nuussuaq Peninsula in West Greenland, and they include ∼1,000 m of picritic lavas and discrete 10- to 50-m-thick members of highly contaminated basalts. On Qeqertarssuaq, the lavas are allocated to the Vaîgat and Maligât Formations of which the former includes the Naujánguit member, which consists of picrites with 7–29 wt% MgO, 80–1,400 ppm Ni, 5.7–9.4 ppb Pt and 4.2–12.9 ppb Pd. The Naujánguit member contains two horizons of contaminated basalts, the Asûk and Kûgánguaq, which have elevated SiO2 (52–58 wt%) and low to moderate MgO (7.5–12.8 wt%). These lavas are broadly characterized by low Cu and Ni abundances (average, 40 ppm Ni and 45 ppm Cu) and very low Pt (0.16–0.63 ppb) and Pd (0.13–0.68 ppb) abundances, and in the case of the Asûk, they contain shale xenoliths and droplets of native iron and troilite. The contaminated basalts from Nuussuaq, the B0 to B4 members, are also usually Ni-, Cu-, and platinum-group elements (PGE)-depleted. The geochemical signatures (especially the ratios of incompatible trace elements such as Th/Nb) of all of the contaminated basalts from Qeqertarssuaq and some of those from Nuussuaq record what appears to be a chemical contribution from deltaic shales that lie immediately below the lavas. This suggests that the contamination of the magmas occurred during the migration of the magmas through plumbing systems developed in sedimentary rocks, and hence, at a high crustal level. Nickel, Cu, and PGE depletion together with geochemical signatures produced by crustal contamination are also a feature of Siberian Trap basalts from the Noril’sk region. These basalts belong to the 0- to 500-m thick, ∼5,000- to 10,000-km3 Nadezhdinsky Formation, which is centered in the Noril’sk Region. A major difference between Siberia and West Greenland is that PGE depletion in the Nadezhdinsky Formation samples with the lowest Cu and Ni contents is much more severe than that of the West Greenland contaminated basalts. Moreover, the volumes of the contaminated and metal-depleted volcanic rocks in West Greenland pale is significant when compared to the Nadezhdinsky Formation; local centers rarely contain more than 15 thin flows with a combined thickness of <50 m and more typically 10–20 m, so the volume of the eruptive portions of each system is probably two orders of magnitude smaller than the Nadezhdinsky edifice. The West Greenland centres are juxtaposed along fault zones that appear to be linked to the subsidence of the Tertiary delta, and so emplacement along N–S structures appears to be a principal control on the distribution of lavas and feeder intrusions. This leads us to suggest that the Greenland system is small and segregation of sulphide took place at high levels in the crust, whereas at Noril’sk, the saturation event took place at depth with subsequent emplacement of sulphide-bearing magmas into high levels of the crust. As a consequence, it may be unreasonable to expect that the West Greenland flood basalts experienced mineralizing processes on the scale of the Noril’sk system.
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Acknowledgement
Inco Limited is thanked for the permission to publish this manuscript. Falconbridge Limited is thanked for financing the field investigation and parts of the laboratory studies. Tony Green and Kevin Olshefsky are thanked for the numerous discussions and for logistic support during the initial phases of this work. PGE determinations were made by Troy Richardson at the Geoscience Labs where the method was set up using funding secured by RRK and PCL from the Natural Sciences and Engineering Research Council, Undergraduate Research Incentive Fund and Inco Limited.
Asger Ken Pedersen is thanked for his encouragement and help with the regional stratigraphy of the lavas. We acknowledge comments from the following reviewers: Nick Arndt, Tony Naldrett and Mei-Fu Zhou. Bernd Lehmann is particularly thanked for his very thorough editing.
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ESM Table 1
Analytical quality control data for the PGE (XLS 19 kb)
ESM Table 2
PGE data for samples from Qeqertarssuaq and Nuussuaq; see Lightfoot et al. (1993) for complete major, trace element, and Sr-, Nd-, and Pb-isotope data (XLS 82 kb)
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Keays, R.R., Lightfoot, P.C. Siderophile and chalcophile metal variations in Tertiary picrites and basalts from West Greenland with implications for the sulphide saturation history of continental flood basalt magmas. Miner Deposita 42, 319–336 (2007). https://doi.org/10.1007/s00126-006-0112-4
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DOI: https://doi.org/10.1007/s00126-006-0112-4