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Molecular Magnetism of Metal Complexes and Light-Induced Phase Transitions

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Modern Mössbauer Spectroscopy

Part of the book series: Topics in Applied Physics ((TAP,volume 137))

Abstract

One of the most attractive research in the field of molecular solids is multifunctional molecular magnets coupled with spin, charge and photon, and single-molecular magnet/single-chain magnet toward spintronics. In this chapter, we focus on the molecular magnetism and its related light-induced phase transitions from the viewpoint of Mössbauer spectroscopy. In the Sect. 6.1, the outline of this chapter is described. In the Sect. 6.2, static and dynamic spin crossover phenomena between the high-spin and low-spin states, and the spin frustration system induced by dynamic spin crossover phenomena for [MnIIFeIII(C2O3S)3] complex are described. In the Sect. 6.3, metal complexes showing charge transfer phase transitions such as Prussian blue analogous complexes and [FeIIFeIII(C2O2S2)3] complexes and their photo-induced phase transitions are described. In the Sect. 6.4, various kinds of molecular magnets including single molecular chain magnets are described.

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Abbreviations

CTPT:

Charge transfer phase transition

CTIST:

Charge transfer induced spin transition

IVCT:

Inter-valence charge transfer

HS:

High spin

LS:

Low spin

HTP:

High temperature phase

LTP:

Low temperature phase

IS :

Isomer shift

QS :

Quadrupole splitting

LIESST:

Light induced excited spin state trapping

T CT :

Critical temperature of charge transfer phase transition

SP:

Spiropyran

SMMs:

Single-molecule magnets

SCMs:

Single-chain magnets

SIMs:

Single-ion magnets

QTM:

Quantum tunneling of magnetization.

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Acknowledgements

In this chapter, our contributed original research has been created in collaboration with Profs. M. Enomoto (Tokyo University of Science), M. Itoi (Nihon University), M. Okubo (The University of Tokyo), K. Kagesawa (Tohoku University), T. Matsuo (Kinki University), Y. Kobayashi (University of Electro-Communications), T. Kajiwara (Nara Women’s University), K. Tamao (Toyota Riken), M. Yamashita (Tohoku University), M. Seto (Kyoto University), H. Sawa (Nagoya University), E. Nishibori (Tsukuba University), Drs. N. Kida (Mitsubishi Chemical Co.), Y. Ono (Mitsubishi Chemical Co.), I. Watanabe (RIKEN). We wish to thank all the collaborators. This work has partly been supported by Toyota Physical and Chemical Research Institute, and a Grant-in-Aid for Science Research from the Ministry of Education, Science, Sports and culture.

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Authors and Affiliations

  1. Toyota Physical and Chemical Research Institute, Yokomichi 41-1, Nagakute, Aichi, 480-1192, Japan

    Norimichi Kojima

  2. Division of Chemistry, Institute of Liberal Education, Nihon University School of Medicine, Oyaguchi Kamimachi 30-1, Itabashi-ku, Tokyo, 173-8610, Japan

    Atsushi Okazawa

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  1. Shizuoka Institute of Science and Technology, Fukuroi, Shizuoka, Japan

    Yutaka Yoshida

  2. University of Leuven, Leuven, Belgium

    Guido Langouche

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Kojima, N., Okazawa, A. (2021). Molecular Magnetism of Metal Complexes and Light-Induced Phase Transitions. In: Yoshida, Y., Langouche, G. (eds) Modern Mössbauer Spectroscopy. Topics in Applied Physics, vol 137. Springer, Singapore. https://doi.org/10.1007/978-981-15-9422-9_6

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