Abstract
Group VIII metals are used as catalysts for a number of reactions involving the molecules H2, CO, O2, NO and NH3. This paper will outline and discuss the differences in behaviour of the Group VIII metal surfaces in reactions of oxygen with hydrogen and carbon monoxide; nitric oxide with hydrogen and carbon monoxide; carbon monoxide with hydrogen; and ammonia with nitric oxide and oxygen. It will be shown that the differences in activity and selectivity of the various metals can be understood on the basis of the behaviour of these metals in the adsorption of the gases CO, NO, O2, H2 and NH3.
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References
B.E. Nieuwenhuys. Surf.Sci. 126 (1983) 307 and refs. therein. In order to limit the number of references the reader is referred to [1] for refs. to most of the papers published before 1983.
F. Haber, Z.Elektrochem. 16 (1910) 24.
A. Mittasch, Adv.Catal. 2 (1950) 8.
E.M. McCash, S.F. Parker, J. Pritchard and M.A. Chesters, Surf. Sci. 215 (1989) 36.
R.D. Ramsier and J.T. Yates, Surf.Sci.Rep. 12 (1991) 243. and refs. therein
J.B. Benzinger, Appl.Sci.Sci., 6 (1980) 10.
M.Th.Karapetyants and M.K.Karapetyants, Handbook of Thermodynamic Constants (Ann Arbor-Humphrey Science, Ann Arbor, 1970)
G. Brodén, T.N. Rhodin, C. Brucker, R. Bendow and Z. Hurych, Surf. Sci. 59 (1976) 59.
B.E. Nieuwenhuys, Surf.Sci. 105 (1981) 50.
K. Christmann, Surf.Sci.Rep. 9 (1988) 1
J.W.Davenport, P.J.Estrup, Chem.Phys.Solid State Surf.& Het.Catal. 3A (199) 39, eds. D.A.King and D.P.Woodruff, Elsevier/Amsterdam
J.L. Gland, B.A. Sexton and G.B. Fisher, Surf.Sci., 95 (1980) 58.
J.P.Campuzano, Chem.Phys.Solid State Surf.& Het.Catal. 3A (1991) 389, eds. D.A.King and D.P.Woodruff, Elsevier/Amsterdam
G. Blyholder, J.Phys.Chem. 68 (1964) 277.
P.S. Bagus, C.J. Nelin, C.W. Bauschlicher, J. Vac. Sci. Technol. A2 (1984) 905
W. Muller, P.S. Bagus, J. Vac. Sci. Technol. A3 (1985) 1623
G. Rangelov, N. Memmel, E. Bertel, V. Dose, Surf.Sci. 251 (1991) 96.
R.P. Eischens, W.A. Pliskin and S.A. Francis, J.Chem.Phys. 22 (1954) 178.
N. Sheppard and T.T. Nguyen in Adv.IR and Raman Spectr. Vol.5, eds. R.E. Hester and R.J.H. Clark, (Heyden, London, 1978)
D.A.King, Chem.Phys.Solid Slate Surf.& Het.Catal. 3A (1990) 39, eds.D.A.King and D.P.Woodruff, Elsevier/Amsterdam
C.N.R. Rao and P. Ranga Rao, Surf.Sci.Rep. 13 (1991) 22.
R.M. Wolf, J.W. Bakker and B.E. Nieuwenhuys, Surf.Sci. 246 (1991) 13.
A. Sandell, A. Nilsson and N. Martensson, Surf.Sci., 241 (1991) L1 and refs.therein
T.H. Lin and G.A. Somorjai, Surf.Sci., 107 (1981) 57.
R.J. Gorte, L.D. Schmidt and J.L. Gland, Surf. Sci., 109 (1981) 36.
R.I. Masel, Cat. Rev. Sci. Eng. 28 (1986) 33.
G.B. Fisher and J.L. Gland, Surf. Sci. 94 (1980) 44.
G.B. Fisher and B.A. Sexton, Phys. Rev. Lett. 44 (1980) 68.
F. Solymosi, J. Molec. Catal. 65 (1991) 33.
H.A.C.M. Hendrickx, A.P.J.M. Jongenelis and B.E. Nieuwenhuys, Surf.Sci. 154 (1985) 50.
L.H. Dubois and G.A. Somorjai, Surf.Sci. 91 (1980) 514. and refs. therein
M.F.H.van Tol, A.Gielbert, R.M.Wolf, A.B.K.Lie and B.E.Nieuwenhuys, Surf.Sci., accepted for publication
C. Benndorf and T.E. Madey, Surf.Sci. 135 (1983) 16.
Y. Zhou, S. Akhter and J.M. White, Surf.Sci. 202 (1988) 35.
T. Sasaki, T. Aruga, H. Kuroda and Y. Iwasawa, Surf.Sci.Lett. 224 (1989) L969
B.A. Sexton and G.E. Mitchell, Surf.Sci. 99 (1980) 53.
D.G. Löffler and L.D. Schmidt, Surf. Sci. 59 (1976) 19.
H. Conrad, G. Ertl and J. Küppers, Surf. Sci. 76 (1978) 32.
R.M. Lambert and C.M. Comrie, Surf.Sci. 46 (1974) 6.
P.A. Thiel, W.H. Weinberg and J.T. Yates, J. Chem. Phys. 71 (1979) 164.
D.A. King, Faraday Disc. Chem. Soc. 87 (1989) 30.
R.F. van Slooten and B.E. Nieuwenhuys, J.Catal. 122 (1990) 42.
G.A. Kok, A. Noordermeer and B.E. Nieuwenhuys, Surf. Sci. 135 (1983) 6.
B.E. Koel, D.E. Peebles and J.M. White, Surf. Sci. 107 (1981) L367
P.R. Norton in “Chem. Phys. Solid Surfaces and Heterogenous Catalysis”, eds. D.A. King and D.P. Woodruff (Elsevier, Amsterdam, 1982), Vol.4, chapt.2
B.A. Gurney and W. Ho, J.Chem.Phys. 87 (1987) 556.
G.E. Mitchell and J.M. White, Chem. Phys. Lett. 135 (1987) 8.
D.S.Y. Hsu, M.A. Hoffbauer and M.C. Lin, Surf.Sci. 184 (1987) 2.
S. Ljunström, B. Kasemo, A. Rosén, T. Wahnström and E. Fridell, Surf.Sci. 216 (1989) 6.
T. Engel and H. Kuipers, Surf.Sci. 90 (1979) 18.
S.D. Gardner, G.B. Hoflund, B.T. Upchurch, D.R. Schryer, E.J. Kielin and J. Schryer, J. Catal. 129 (1991) 11.
T. Engel and G. Ertl, J.Chem.Phys. 69 (1978) 126.
N.W. Cant, P.C. Hicks and B.S. Lennon, J. Catal. 54 (1978) 37.
J. Siera, F. Rutten and B.E. Nieuwenhuys, Catal. Today, 10 (1991) 35.
M.F.H. van Tol, J. Siera, P.D. Cobden and B.E. Nieuwenhuys, Surf. Sci. 274 (1992) 63. and M.F.H.van Tol, A.Gielbert and B.E.Nieuwenhuys, Catal.Lett. 16 (1992) 29.
B.C. Sales, J.E. Turner and M.B. Maple, Surf.Sci. 114 (1982) 38.
G. Ertl, Adv. Catal. 37 (1990) 21.
M. Boudart and F. Rumpf, React.Kinet.Catal.Lett. 35 (1987) 9.
T.P. Kobylinski and B.W. Taylor, J.Catal. 33 (1974) 37.
K.C. Taylor, Catal.Sci.Techn., eds. J.R.Andersson and M.Boudart (Springer-Verlag-Berlin) 5 (1984) 11.
H. Hirano, T. Yamada, K. Tanaka, J. Siera, P. Cobden and B.E. Nieuwenhuys, Surf.Sci. 262 (1992) 97. and proc. 10th ICC, Budapest, 1992, paper 015
M. Iwamoto, H. Yahiro, K. Tanda, N. Mizuno, Y. Mine and S. Kagawa, J. Phys. Chem. 95 (1991) 372.
Y. Li and W.K. Hall, J.Catal. 129 (1991) 20.
H. Bosch and F. Janssen, Catal.Today 4 (1988) 39.
B. Harisson, A.F. Diwell and M. Wyatt, Plat. Met. Rev. 29 (1985) 5.
V. Ponec, Stud. Surf. Sci. & Catal. 64 (1991) 117. and Catalysis Today 12 (1992) 22.
A. Ozaki and K. Aika, Catal.Sci.Techn., eds. J.R.Andersson and M.Boudart (Springer-Verlag-Berlin) 1 (1981) 8.
R. Brill, Ber.Bunsenges.Phys.Chem. 75 (1971) 45.
G. Ertl, Catal.Rev.Sci.Eng. 21 (1980) 20.
N.D. Spencer, R.C. Schoonmaker and G.A. Somorjai, J. Catal. 74 (1982) 12.
F.C.M.J.M. van Delft, B.E. Nieuwenhuys, J. Siera and R.M. Wolf, Iron and Steel Inst.Japan Intern. 29 (1989) 550. and refs.therein
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Nieuwenhuys, B.E. (1993). Adsorption and Reactions of CO, NO, H2 and O2 on Group VIII Metal Surfaces. In: Joyner, R.W., van Santen, R.A. (eds) Elementary Reaction Steps in Heterogeneous Catalysis. NATO ASI Series, vol 398. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1693-0_10
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