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A New Approach for Quantitative 13C NMR Spectroscopy of Coal

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New Trends in Coal Science

Part of the book series: NATO ASI Series ((ASIC,volume 244))

Abstract

The use of tetrakis(trimethylsilyl)silane as a qualitative chemical shift standard and as a quantitative internal standard for carbon-13 NMR spectroscopy of coals and the use of samarium(II) iodide as a reagent for the realization of more quantitative spectroscopic results through the selective removal of organic free radicals from coal are discussed.

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References

  1. Miknis, F.P. The preceding chapter in this monograph.

    Google Scholar 

  2. Miknis, F.P.; Sullivan, M.J.; Bartuska, V.J.; Maciel, G.E. Org. Geochem., 1981, 3, 19.

    Article  CAS  Google Scholar 

  3. Hagamann, E.W.; Chambers, R.R.; Woody, M.C. Anal. Chem., 1986, 58, 387.

    Article  Google Scholar 

  4. Botto, R.G.; Wilson, R.; Winans, R.E. Energy and Fuels, 1987, 1, 173.

    Article  CAS  Google Scholar 

  5. Muntean, J.V.; Stock, L.M.; Botto, R.E. J. Mag. Res., 76 1988, 000. In press.

    Google Scholar 

  6. Muntean, J.V.; Stock, L.M.; Botto, R.E. Energy and Fuels, 1988, 2, 000. In press.

    Google Scholar 

  7. Gilman, H.; Smith, L.L. J. Am. Chem. Soc., 1964, 86, 1454.

    Article  CAS  Google Scholar 

  8. Girard, P.; Namy, J.L.; Kagan, H.B. J. Am. Chem. Soc., 1980, 102, 2693.

    Article  CAS  Google Scholar 

  9. Axelson, D.E. “Solid State Nuclear Magnetic Resonance of Fossil Fuels: An Experiment Approach”, Multiscience: Canada, 1985.

    Google Scholar 

  10. Earl, W.L.; Vanderhart, D.L. J. Magn. Reson., 1982, 48, 35.

    CAS  Google Scholar 

  11. Vanderhart, D.L. J. Chem. Phys., 1986, 84, 1196.

    Article  CAS  Google Scholar 

  12. Retcofsky, H.L. Coal Science, 1982, 1, 43.

    CAS  Google Scholar 

  13. Morss, L.R. “Standard Potentials in Aqueous Solution”, Chapter 20; Bard, A.J.; Parsons, R. and Jordon, J., Eds., Marcel Dekker: New York and Basel, 1985.

    Google Scholar 

  14. Molander, G.A.; Etter, J.B. J. Org. Chem., 1986, 51, 1778.

    Article  CAS  Google Scholar 

  15. Wind, R.; Duijvestijn, M.J.; van der Lugt, C.; Schmidt, J.; Vriend, H. Fuel, 1987, 66, 876.

    Article  CAS  Google Scholar 

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© 1988 Kluwer Academic Publishers

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Stock, L.M., Muntean, J.V., Botto, R.E. (1988). A New Approach for Quantitative 13C NMR Spectroscopy of Coal. In: Yürüm, Y. (eds) New Trends in Coal Science. NATO ASI Series, vol 244. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3045-2_6

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  • DOI: https://doi.org/10.1007/978-94-009-3045-2_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7869-6

  • Online ISBN: 978-94-009-3045-2

  • eBook Packages: Springer Book Archive

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