Abstract
The use of tetrakis(trimethylsilyl)silane as a qualitative chemical shift standard and as a quantitative internal standard for carbon-13 NMR spectroscopy of coals and the use of samarium(II) iodide as a reagent for the realization of more quantitative spectroscopic results through the selective removal of organic free radicals from coal are discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Miknis, F.P. The preceding chapter in this monograph.
Miknis, F.P.; Sullivan, M.J.; Bartuska, V.J.; Maciel, G.E. Org. Geochem., 1981, 3, 19.
Hagamann, E.W.; Chambers, R.R.; Woody, M.C. Anal. Chem., 1986, 58, 387.
Botto, R.G.; Wilson, R.; Winans, R.E. Energy and Fuels, 1987, 1, 173.
Muntean, J.V.; Stock, L.M.; Botto, R.E. J. Mag. Res., 76 1988, 000. In press.
Muntean, J.V.; Stock, L.M.; Botto, R.E. Energy and Fuels, 1988, 2, 000. In press.
Gilman, H.; Smith, L.L. J. Am. Chem. Soc., 1964, 86, 1454.
Girard, P.; Namy, J.L.; Kagan, H.B. J. Am. Chem. Soc., 1980, 102, 2693.
Axelson, D.E. “Solid State Nuclear Magnetic Resonance of Fossil Fuels: An Experiment Approach”, Multiscience: Canada, 1985.
Earl, W.L.; Vanderhart, D.L. J. Magn. Reson., 1982, 48, 35.
Vanderhart, D.L. J. Chem. Phys., 1986, 84, 1196.
Retcofsky, H.L. Coal Science, 1982, 1, 43.
Morss, L.R. “Standard Potentials in Aqueous Solution”, Chapter 20; Bard, A.J.; Parsons, R. and Jordon, J., Eds., Marcel Dekker: New York and Basel, 1985.
Molander, G.A.; Etter, J.B. J. Org. Chem., 1986, 51, 1778.
Wind, R.; Duijvestijn, M.J.; van der Lugt, C.; Schmidt, J.; Vriend, H. Fuel, 1987, 66, 876.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1988 Kluwer Academic Publishers
About this chapter
Cite this chapter
Stock, L.M., Muntean, J.V., Botto, R.E. (1988). A New Approach for Quantitative 13C NMR Spectroscopy of Coal. In: Yürüm, Y. (eds) New Trends in Coal Science. NATO ASI Series, vol 244. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3045-2_6
Download citation
DOI: https://doi.org/10.1007/978-94-009-3045-2_6
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-7869-6
Online ISBN: 978-94-009-3045-2
eBook Packages: Springer Book Archive