Skip to main content

Effect of Zinc on Solidification and Aging Behaviour of Magnesium Alloys Containing Rare Earths

  • Conference paper
  • First Online:
Magnesium Technology 2020

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

  • 1847 Accesses

Abstract

Magnesium sheet continuously creates a great interest with potentials in a wide range of technically advanced applications. The interest was initially driven by a reduction in fuel consumption within transportation sectors and was later expanded to consumer electronic housings, components in electrification of vehicles, and aerospace applications. In a search for alloys with suitable formability , a particular attention is paid to Mg–Zn –RE (rare earth ) grades. It is known that the presence of Zn in binary Mg–Zn alloys leads to enhanced strength and ductility. However, the effect of Zn on alloy formability in the presence of rare earths is less pronounced. In this report, the solidification and aging behavior of Mg–xZn–1Nd (x = 1, 2, 4 wt%) alloys are described. To analyze the phase nucleation and growth during melting and solidification, the Universal Metallurgical Simulator and Analyzer (UMSA) was used. Hardness values of Mg–Zn –Nd alloys increased with increasing Zn contents both in as-cast and after heat treatments with changes being accompanied by the alloy structure refinement. The results are discussed in terms of the role Zn plays in properties of magnesium alloys containing rare earths. Increasing Zn content in the Mg-xZn-1Nd alloy sheets led to a moderate increase in ultimate tensile strength and yield stress but substantial reduction in ductility.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. F. Cerwinski, “Magnesium Alloys - Design, Processing and Applications,” InTech, pp. 299, January 14, 2011.

    Google Scholar 

  2. A. Luo, R. K. Mishra and R. K. Sachdev, “High-Ductility Magnesium-Zinc-Cerium Extrusion Alloys,” Scripta Materialia, vol. 64, pp. pp. 410-413., 2011.

    Google Scholar 

  3. R. K. Mishra, “Influence of Cerium on Texture and Ductility of Magnesium Extrusions,” Scripta Materialia,, vol. 59, pp. pp. 562-565., 2008.

    Google Scholar 

  4. C. Bettles and M. Gibson, “Current wrought magnesium alloys: strengths and weaknesses,” JOM, pp. pp. 26-49, May 2005.

    Google Scholar 

  5. F. Czerwinski, “The reactive element effect on high temperature oxidation of magnesium,” Int. Mater. Rev., vol. 50, no. 5, p. pp. 264–296., 2015.

    Google Scholar 

  6. J. Robson, “Effect of rare earth additions on the texture of wrought magnesium alloys: the role of grain boundary segregation,” Metallurgical and Materials Transaction A, vol. 48, no. 8, pp. pp. 3205-3212, 2014.

    Google Scholar 

  7. K. U. Kainer, “The current state of technology and potential for further development of magnesium applications,” Magnesium Alloys and Technologies, pp. pp. 1-22, 2003.

    Google Scholar 

  8. “Magnesium and Magnesium Alloys,” in ASM Speciality Handbook, 1999, pp. pp. 12-25.

    Google Scholar 

  9. M. A. Gibson, M. Easton, V. Tyag, M. Murray and G. Dunlop, “Magnesium Technology 2008,” in TMS, 2008.

    Google Scholar 

  10. A. Luo, R. K. Mishra, B. R. Powell and A. K. Sachdev, “Materials Science Form. Trans. Tech Publi 5, 69 (2012),” vol. 69, 2012.

    Google Scholar 

  11. Magnesium and Magnesium Alloys, ASM Speciality Handbook, September 1999.

    Google Scholar 

  12. L. Gill, G. Lorimer and P. Lyon, “Microstructure and property relationship of Mg-RE-Zn,” Germany, International Conference on Magnesium Alloys and their Applications.

    Google Scholar 

  13. A. Javaid, F. Czerwinski, R. Zavadil and M. Aniolek, “Solidification characteristics of magnesium alloys with addition of rare earth elements, In: TMS Magnesium,” TMS magnesium Technology 2014, 2014.

    Google Scholar 

  14. Y. He, A. Javaid and E. Essadiqi, “Numerical simulation and experimental study of the solidification of a wedge-shaped AZ31 Mg alloy casting,” Can. Metall. Quartly, vol. 48, p. pp. 145–156, (2009.

    Google Scholar 

  15. A. Javaid, A. Hadadzadeh and F. Czerwinski, “Solidification beheviour of diluted Mg-Zn-Nd alloys,” Journal of Alloys and Compounds, vol. 782, pp. 132-148, 2019.

    Google Scholar 

  16. J. Yan, Y. Sun, F. Xue, S. Xue and W. Tao, “Yan, J.; SunMicrostructure and mechanical properties in cast magnesium–neodymium binary alloys,” Mater. Sci. Eng. A, vol. 476, p. 366–371, 2008.

    Google Scholar 

  17. T. Chia, M. Easton and M. G. N. J. N. S. Zhu, “The effect of alloy composition on the microstructure and tensile properties of binary Mg-RE alloys,” Intermetallics, vol. 17, pp. 481-490, 2009.

    Google Scholar 

  18. A. Javaid, M. Kozdras and F. Czerwinski, “Overcoming barriers to magnesium rolling,” Adv. Mater. Process, vol. 176, no. 4, p. 16–21, 2018.

    Google Scholar 

  19. C. Bettles, M. Gibson and S. Zhu, Mater. Sci. Eng. A, vol. 505, p. 6, 2009.

    Google Scholar 

  20. D. Choudhuri, D. Jaeger, M. Gibbson and R. Banerjee, Sripta Mater., vol. 86, p. 32, 2014.

    Google Scholar 

  21. L. Gill, G. Lorimer and P. Lyon, “Microstructure and property relationships of Mg-RE-Zn-Zr,” in DGM International Conference on Magnesium Alloys and their Applications, Germany, 2003.

    Google Scholar 

Download references

Acknowledgements

The authors would like to thank the Innovative Casting team at CanmetMATERIALS for casting experiments, Marta Aniolek for assistance with thermal analysis, and Renata Zavadil with microscopy.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Javaid .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Javaid, A., Czerwinski, F. (2020). Effect of Zinc on Solidification and Aging Behaviour of Magnesium Alloys Containing Rare Earths. In: Jordon, J., Miller, V., Joshi, V., Neelameggham, N. (eds) Magnesium Technology 2020. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-36647-6_55

Download citation

Publish with us

Policies and ethics