Abstract
Zirconia nanoparticles synthesized by the sol–gel method were surface modified by the coupling agent, 3-(trimethoxy silyl) propyl methacrylate (MSMA), containing C=C bonds. These particles were then UV-cured together with the hexa-functional monomer, dipentaethritol hexaacrylate (DPHA), to prepare transparent coatings that exhibited antistatic property on plastic substrates. FTIR and solid 29SiNMR were used to analyze the chemical bonds in the formed particles and coatings. Dynamic light scattering measurement of the modified ZrO2 sol indicated a relatively small particle size distribution, 1.5–20 nm, with a maximum intensity at ~5.5 nm. These particles dispersed uniformly in the organic host, poly(DPHA), as was manifested by the high resolution SEM images of the coatings. Antistatic performance of the coatings was examined based on the surface resistivity measurements. A resistivity of 7.74 × 108 Ω/□ suited to common antistatic applications could be attained for coatings containing 10% inorganic component. In addition, all of the prepared coatings were very hard with pencil hardness 7H–8H, and they attached perfectly to the PMMA substrate according to the peel test.
Similar content being viewed by others
References
Rosner, RB, “Conductive Materials for ESD Applications: An Overview.” IEEE Trans. Device Mater. Reliab., 1 9–16 (2001)
Burlingame, NH, “Electro-Static Dissipative Zirconia.” US Patent 6,136,232, 2000
Hoeks, TL, Leenders, CA, van de Grampel, RD, “Method of Making Thermoplastic Composition Containing an Antistatic Agent.” US Patent 7,429,628, 2008
Dontula, N, Heath, TA, Chang, S, “Extrudable Antistatic Tielayers.” US Patent 7,521,173, 2009
Ozawa, H, Aoki, F, “Polyimide Powder for Antistatic Polyimide Molded Product and Polyimide Molded Product Thereby.” US Patent 7,754,108, 2010
Haas, KH, Amberg-Schwab, S, Rose, K, “Functionalized Coating Materials Based on Inorganic-Organic Polymers.” Thin Solid Films, 351 198–202 (1999)
Delattre, L, “Design of Homogeneous Hybrid Materials through a Careful Control of the Synthetic Procedure.” J. Sol-Gel. Sci. Technol., 8 567–570 (1997)
Monte, FD, Cheben, P, Grover, CP, Mackenzie, JD, “Preparation and Optical Characterization of Thick-Film Zirconia and Titania Ormosils.” J. Sol-Gel. Sci. Technol., 15 73–85 (1999)
Zhao, J, Fan, W, Wu, D, Sun, Y, “Synthesis of Highly Stabilized Zirconia Sols from Zirconium n-Propoxide-Diglycol System.” J. Non-Cryst. Solids, 261 15–20 (2000)
Voelkel, J, “Improvement in Quality of Sol-Gel Derived Zirconia Multilayer Coatings by Polymeric Additive.” Mol. Cryst. Liquid Cryst., 354 503–509 (2000)
Villegas, MA, “Chemical and Microstructural Characterization of Sol-Gel Coatings in the ZrO2-SiO2 System.” Thin Solid Films, 382 124–132 (2001)
Caracoche, MC, Rivas, PC, Cervera, MM, Caruso, R, Benavídez, E, Sanctis, O, “Nanostructural Study of Sol-Gel-Derived Zirconium Oxides.” J. Mater. Res., 18 208–215 (2003)
Caruso, R, Sanctis, O, Macías-García, A, Benavidez, E, Mintzer, SR, “Influence of pH Value and Solvent Utilized in the Sol-Gel Synthesis on Properties of Derived ZrO2 Powders.” J. Mater. Processing Technol., 152 299–303 (2004)
Ehrhart, G, Capoen, B, Robbe, O, Boy, Ph, Turrell, S, Bouazaoui, M, “Structural and Optical Properties of n-Propoxide Sol-Gel Derived ZrO2 Thin Films.” Thin Solid Films, 496 227–233 (2006)
Schmidt, T, Mennig, M, “New Method for the Preparation and Stabilization of Nanoparticulate t-ZrO2 by a Combined Sol-Gel and Solvothermal Process.” J. Am. Ceram. Soc., 90 1401–1405 (2007)
Lianga, L, Xu, Y, Wu, D, Sun, Y, “A Simple Sol-Gel Route to ZrO2 Films with High Optical Performances.” Mater. Chem. Phys., 114 252–256 (2009)
Chen, CC, Lin, DJ, Don, TM, Huang, FH, Cheng, LP, “Preparation of Organic-Inorganic Nano-Composites for Antireflection Coatings.” J. Non-Cryst. Solids, 354 3828–3835 (2008)
Lee, CK, Don, TM, Lai, WC, Chen, CC, Lin, DJ, Cheng, LP, “Preparation and Properties of Nano-Silica Modified Negative Acrylate Photoresist.” Thin Solid Films, 516 8399–8407 (2008)
Chang, CC, Cheng, LP, Huang, FH, Lin, CY, Hsieh, CF, Wang, WH, “Preparation and Characterization of TiO2 Hybrid Sol for UV-Curable High-Refractive-Index Organic-Inorganic Hybrid Thin Films.” J. Sol-Gel. Sci. Technol., 55 199–206 (2010)
Huang, FH, Chang, CC, Oyang, TY, Chen, CC, Cheng, LP, “Preparation of Almost Dispersant-Free Colloidal Silica with Superb Dispersiblility in Organic Solvents and Monomers.” J. Nanopart. Res., 13 3885–3897 (2011)
Chang, CC, Oyang, TY, Hwang, FH, Chen, CC, Cheng, LP, “Preparation of Polymer/Silica Hybrid Hard Coatings with Enhanced Hydrophobicity on Plastic Substrates.” J. Non-Cryst. Solids, 358 72–76 (2012)
Chang, CC, Chen, CM, Hwang, FH, Chen, CC, Cheng, LP, “Preparation of Polymer/Silica Composite Antiglare Coatings on Poly(Ethylene Terphathalate) (PET) Substrates.” J. Coat. Technol. Res. (2012). doi:10.1007/s11998-011-9392-4
Rankin, SE, Macosko, CW, McCormick, AV, “Sol-Gel Polycondensation Kinetic Modeling: Methylethoxysilanes.” AIChE J., 44 1141–1156 (1998)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chang, CC., Hwang, FH., Hsieh, CY. et al. Preparation and characterization of polymer/zirconia nanocomposite antistatic coatings on plastic substrates. J Coat Technol Res 10, 73–78 (2013). https://doi.org/10.1007/s11998-012-9427-5
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-012-9427-5