Skip to main content
Log in

Determination of uranium isotopes in environmental samples

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The determination of isotopes of uranium by alpha spectrometry in different environmental components (sediments, soil, water, plants and phosphogypsum) is presented and discussed in this paper. The alpha spectrometry is a very convenient and good technique for activity concentration of natural uranium isotopes (234U, 235U, 238U) in environmental samples and provides the most accurate determination of isotopic activity ratios between 234U and 238U. The analysis were provided information about possible sources of high concentrations of uranium in the examined sites determined by anthropogenic sources. The calculation of values 234U/238U in all analyzed samples was applied to identifying natural or anthropogenic uranium origin. Activity concentration of uranium isotopes in analyzed environmental samples shows that measurement of uranium levels is of great importance for environmental and safety assessment especially in contaminated areas (phosphogypsum waste heap).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Capannesi G, Rosada A, Manigrasso M, Avino P (2012) J Radioanal Nucl Chem 291:163

    Article  CAS  Google Scholar 

  2. Boryło A, Nowicki W, Skwarzec B (2009) J. Environ. Anal. Chem 89:8

    Google Scholar 

  3. Nagy S, Závodská L, Mátel L, Lesný J (2009) Acta Tech Jaurinensis 2(1):19

    Google Scholar 

  4. Skwarzec B, Boryło A, Kosińska A, Radzajewska S (2010) Nukleonika 55(2):187

    CAS  Google Scholar 

  5. Boryło A, Skwarzec B (2011) Radiochim Acta 99:1

    Article  Google Scholar 

  6. Andreou G, Efstathiou M, Pashalidis I (2012) J Radioanal Nucl Chem 291:865

    Article  CAS  Google Scholar 

  7. Wang X, Peng G, Yang Y, Wang Y, He T (2012) J Radioanal Nucl Chem 291:825

    Article  CAS  Google Scholar 

  8. Sam A, Holm E (1995) Sci Total Environ 162:173

    Article  CAS  Google Scholar 

  9. Bolivar JP, García-Tenorio R, García-León M (1996) Radioanal. Nucl. Chem 214:77

    Article  CAS  Google Scholar 

  10. Martinez-Aguirre A, Garcia-León M (1997) J Environ Radioact 34:45

    Article  CAS  Google Scholar 

  11. Meinrath A, Schneider P, Meinrath G (2003) J Environ Radioact 64:175

    Article  CAS  Google Scholar 

  12. Skwarzec B (1995) Polon, uran i pluton w ekosystemie południowego Bałtyku. Rozprawy i monografie. Instytut Oceanologii PAN, Sopot (1995) (in Polish)

  13. Bou-Rabee F, Bakir Y, Bem H (1995) Environ. Int 21:293

    Article  CAS  Google Scholar 

  14. Bagatti D, Cantone MC, Giussani A, Veronese I, Roth P, Werner E, Höllriegl V (2003) J Environ Radioact 65:357

    Article  CAS  Google Scholar 

  15. Sam AK, Ahmed MMO, El Khangi FA, El Nigumi YO, Holm E (1999) J Environ Radioact 42:65

    Article  CAS  Google Scholar 

  16. Browne E, Firestone FB (1986) Table of radioactive isotopes (V.S. Shirley (red.). Wiley, New York

    Google Scholar 

  17. Bourdon B, Turner S, Henderson GM, Lundstrom CC (2003) Rev Miner Geochem 52:1

    Article  CAS  Google Scholar 

  18. Fleischer RL, Raabe OG (1978) Geochim Cosmochim Acta 42:973

    Article  CAS  Google Scholar 

  19. Skwarzec B, Boryło A, Strumińska DI (2004) J Water Air Soil Pollut 159:165

    Article  CAS  Google Scholar 

  20. Jia G, Belli M, Sansone U, Rosamilia S, Gaudino S (2006) J. Environ Radioact 89:172

    Article  CAS  Google Scholar 

  21. Zouridakis N, Ochsenkűhn KM, Savidou A (2002) J Environ Radioact 61:225

    Article  CAS  Google Scholar 

  22. Skwarzec B (1997) Chem Anal (Warsaw) 42:107

    CAS  Google Scholar 

  23. Skwarzec B, Strumińska DI, Boryło A (2006) Nukleonika 51:45

    Google Scholar 

  24. El-Taher A (2010) Appl. Radiat. Isot 68:1189

    Article  CAS  Google Scholar 

  25. Pawuła A (1995) Ochrona Środowiska 3:23

    Google Scholar 

  26. Krtil J, Kuvik V (1988) J Radioanal Nucl Chem 121(2):36

    Article  Google Scholar 

  27. Tosheva Z, Stoyanova K, Nikolchev L (2004) J Environ Radioact 72:47

    Article  CAS  Google Scholar 

  28. Uralbekov BM, Smodis B, Burkitbayev M (2011) J Radioanal Nucl Chem 289:805

    Article  CAS  Google Scholar 

  29. Montoya EH, Mendoza PA, Redregal PS, Baltuano OR, Cohen IM (2012) J Radioanal Nucl Chem 291:175

    Article  CAS  Google Scholar 

  30. Montero MPR, Sánchez AM, Lourtau AMC (2004) Nucl Instrum Methods Phys Res B 213:429

    Article  Google Scholar 

  31. Forte M, Rusconi R, Margini C, Abbate G, Maltese S, Badaloamenti, Bellinzona S (2001) Radiat Prot Dosim 97(4):325

    Article  CAS  Google Scholar 

  32. Dai X, Kramer-Tremblay S (2011) J Radioanal Nucl Chem 289:461

    Article  CAS  Google Scholar 

  33. Schaumlöffel D, Giusti P, Zoriy MV, Pickhardt C, Szpunar J, Łobiński R, Becker JS (2005) J. Anal. At. Spectrom 20:17

    Article  Google Scholar 

  34. Yoshida S, Muramatsu Y, Tagami K (2001) Environ Sci Technol 35:4174

    Article  CAS  Google Scholar 

  35. Santos JS, Teixeira LSG, Santos WNL, Lemos VA (2010) Anal Chim Acta 674:143

    Article  CAS  Google Scholar 

  36. Misra NL, Dhara S, Singh Mudher KD (2006) Spectrochim Acta B 61:1166

    Article  Google Scholar 

  37. Konstantinou M, Pashalidis I (2004) Mediterr Mar Sci 5(1):55

    Google Scholar 

  38. Skwarzec B (2009) Determination of radionuclides in aquatic environment. In: Namieśnik J, Szefer P (eds) Analytical measurement in aquatic environments. Tylor & Francis, London, p 241

    Chapter  Google Scholar 

  39. Kigashi K (1971) Science 173:47

    Article  Google Scholar 

  40. Fleischer RL (1980) Science 207:979

    Article  CAS  Google Scholar 

  41. Goldstein SJ, Rodriguez MJ, Lujan N (1997) Health Phys 72:10

    Article  CAS  Google Scholar 

  42. Skwarzec B, Tuszkowska A, Boryło A (2010) Oceanologia 52(4):1

    Article  Google Scholar 

  43. Singh J, Singh L, Kher S (2004) Radiat Meas 36:517

    Article  Google Scholar 

  44. Uyanik A, Tinkiliç M (1999) Turk J Chem 23:275

    CAS  Google Scholar 

  45. Szefer P (984) Studia i Materiały Oceanologiczne, pp 171

  46. Uścinowicz Sz, Zachowicz J (1991) Objaśnienia do Mapy geologicznej dna Bałtyku 1:200 000, Arkusze Łeba, Słupsk. Państwowy Instytut Geologiczny, Warszawa (in Polish)

  47. Porcelli D, Andersson PS, Wasserburg GJ, Ingri J, Baskaran M (1997) Geochim Cosmochim Acta 19:4095

    Article  Google Scholar 

  48. Skwarzec B (2002) Radiochemia środowiska i ochrona radiologiczna. Zeszyty Zielonej Akademii, Wydawnictwo DJ s.c., Gdańsk (in Polish)

  49. Skwarzec B (2009) Polonium, uranium and plutonium radionuclides in aquatic environment of Poland and southern Baltic In: Baltic coastal zone no 13, part II, Pomeranian University, Słupsk, pp 127

  50. Skwarzec B, Boryło A, Strumińska D (2002) J Environ Radioact 61:345

    Article  CAS  Google Scholar 

  51. Boryło A, Skwarzec B, Olszewski G (2012) J Environ Sci Health A 47:675

    Google Scholar 

  52. Aslani MAA, Akyil S, Aytas S, Gurboga G, Eral M (2005) Radiat Meas 39(2):129

    Article  CAS  Google Scholar 

  53. Salbu B, Janssens K, Lind OC, Proost K, Gijsels L, Danesic PR (2005) J. Environ. Radioactiv 78:125

    Article  CAS  Google Scholar 

  54. Gavrilescu M, Pavel LV, Cretescu I (2009) J Hazard Mater 163:475

    Article  CAS  Google Scholar 

  55. Al-Saad KA, Amr MA, Ismail A, Helal AI (2010) J Environ Chem Ecotoxicol 2(4):60

    CAS  Google Scholar 

  56. Lee MH, Lee CW (2001) Talanta 54:181

    Article  CAS  Google Scholar 

  57. Sansone U, Stellato L, Jia G, Rosamilia S, Gaudino S, Barbizzi S, Belli M (2001) Radiat Prot Dosim 97(4):317

    Article  CAS  Google Scholar 

  58. Rosamilia S, Gaudino S, Sansone U, Belli M, Jeran Z, Ruisi S, Zucconi L (2004) J Atmos Chem 49:447

    Article  CAS  Google Scholar 

  59. Loppi S, Di Lella A, Frati L, Protano G, Pirintsos SA, Riccobono F (2004) J Atmos Chem 49:437

    Article  CAS  Google Scholar 

  60. Bikit IS, Slivka JM, Krmar MD, Veskiović MJ, Ćonkić LU, Varga EZ, Ćuričić SM, Mrda DS (2001) Arch Oncol 9(4):241

    Google Scholar 

Download references

Acknowledgments

The author would like to thank the Polish Ministry of Higher Education and Sciences for the financial support of this work under Grant DS/8120-4-0176-1.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Boryło.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Boryło, A. Determination of uranium isotopes in environmental samples. J Radioanal Nucl Chem 295, 621–631 (2013). https://doi.org/10.1007/s10967-012-1900-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-012-1900-1

Keywords

Navigation