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Fluoro functional groups substituted cobalt(II), iron(II) phthalocyanines and their catalytic properties on benzyl alcohol oxidation

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Abstract

In this study, phthalocyanine complexes (Co and Fe) bearing (2-{2-[3-(trifluoromethyl)phenoxy]ethoxy}ethoxy) groups at peripheral position were synthesized using the phthalonitrile derivative and characterized by IR, 1H-NMR, UV–Vis and mass spectrometry. Catalytic activity of Co(II) and Fe(II) phthalocyanines were investigated in the oxidation of benzyl alcohol with different oxygen sources. Determination of the optimal conditions for oxidation of benzyl alcohol, the catalytic reactions were carried out change the reaction temperature, oxidant/cat ratio, types of oxidants and subst./catalyst ratio.

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Acknowledgments

This study was supported by the Research Fund of Karadeniz Technical University, Project No: 10440.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Karadeniz Technical University, 61080, Trabzon, Turkey

    Ayşe Aktaş, Ece Tuğba Saka, Zekeriya Biyiklioglu & Halit Kantekin

  2. Department of Energy Systems Engineering, Faculty of Technology, Karadeniz Technical University, 61830, Trabzon, Turkey

    İrfan Acar

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  1. Ayşe Aktaş
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  2. İrfan Acar
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Correspondence to İrfan Acar.

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Aktaş, A., Acar, İ., Saka, E.T. et al. Fluoro functional groups substituted cobalt(II), iron(II) phthalocyanines and their catalytic properties on benzyl alcohol oxidation. J Incl Phenom Macrocycl Chem 86, 183–190 (2016). https://doi.org/10.1007/s10847-016-0650-z

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