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Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy-substituted phthalocyanines

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Abstract

The synthesis of novel, symmetrical, tetrasubstituted metal-free and metallo-phthalocyanines (zinc, cobalt, manganese, indium) bearing four [7-(trifluoromethyl)quinolin-4-yl]oxy units has been reported. The new compounds were characterized using UV-Vis, IR, 1H NMR, and mass spectroscopic data. The wavelength of the Q band is related to the metal coordinated at the center of the phthalocyanine rings and follows the order Mn > In > Zn > Co. The phthalocyanines displayed good solubility in organic solvents such as chloroform, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, and toluene.

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Scheme 1
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Acknowledgments

This work was supported by the Research Fund of the Technical University of Istanbul (project no: 33434) and TUBITAK (project no: 110T800).

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Authors and Affiliations

  1. Department of Chemistry, Istanbul Technical University, Maslak, 34469, Istanbul, Turkey

    Halit Koçan & Ayfer Kalkan Burat

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  1. Halit Koçan
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  2. Ayfer Kalkan Burat
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Correspondence to Ayfer Kalkan Burat.

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Koçan, H., Burat, A.K. Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy-substituted phthalocyanines. Monatsh Chem 144, 171–177 (2013). https://doi.org/10.1007/s00706-012-0790-9

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  • DOI: https://doi.org/10.1007/s00706-012-0790-9

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