Abstract
A geochemical survey of fumarolic and submerged gases from fluid discharges located in the Nea Kameni and Palea Kameni islets (Santorini Island, Greece) was carried out before, during, and after the unrest related to the anomalously high seismic and ground deformation activity that affected this volcanic system since January 2011. Our data show that from May 2011 to February 2012, the Nea Kameni fumaroles showed a significant increase of H2 concentrations. After this period, an abrupt decrease in the H2 contents, accompanied by decreasing seismic events, was recorded. A similar temporal pattern was shown by the F−, Cl−, SO4 2−, and NH4 + concentrations in the fumarolic condensates. During the sharp increase of H2 concentrations, when values up to 158 mmol/mol were measured, the δ13C–CO2 values, which prior to January 2011 were consistent with a dominant CO2 thermometamorphic source, have shown a significant decrease, suggesting an increase of mantle CO2 contribution. Light hydrocarbons, including CH4, which are controlled by chemical reactions kinetically slower than H2 production from H2O dissociation, displayed a sharp increase in March 2012, under enhanced reducing conditions caused by the high H2 concentrations of May 2011–February 2012. The general increase in light hydrocarbons continued up to July 2012, notwithstanding the contemporaneous H2 decrease. The temporal patterns of CO2 concentrations and N2/Ar ratios increased similarly to that of H2, possibly due to sealing processes in the fumarolic conduits that diminished the contamination related to the entrance of atmospheric gases in the fumarolic conduits. The compositional evolution of the Nea Kameni fumaroles can be explained by a convective heat pulse from depth associated with the seismic activation of the NE–SW-oriented Kameni tectonic lineament, possibly triggered by either injection of new magma below Nea Kameni island, as apparently suggested by the evolution of the seismic and ground deformation activity, or increased permeability of the volcanic plumbing system resulting from the tectonic movements affecting the area. The results of the present study demonstrate that the geophysical and geochemical signals at Santorini are interrelated and may be precursory signals of renewed volcanic activity and encourage the development of interdisciplinary monitoring program to mitigate the volcanic risk in the most tourist-visited island of the Mediterranean Sea.
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References
Alexandri M, Papanikolaou D, Nomikou P, Ballas D (2003) Santorini volcanic field. New insights based on swath bathymetry. Proceedings of the IUGG conference, Sapporo, Japan
Anderson RB (1984) The Fischer–Tropsch reaction. Academic, London
Arriaga M-CS, Tsompanakis Y, Samaniego F (2008) Geothermal manifestations and earthquakes in the caldera of Santorini, Greece: an historical perspective. Proceedings of the XXXIII workshop on Geothermal Reservoir Engineering, Stanford University, Stanford, California, pp 28–30, SGP-TR-185
Arvanitides N, Galanopoulos V, Kalogeropoulos S, Skamnelos G, Papavassiliou C, Paritsis S, Boström K (1988) Drilling at Santorini volcano, Greece—a joint Greek–Swedish project to explore an ore-forming hydrothermal system. Eos 69:578–579
Arvanitides N, Boström K, Kalogeropoulos S, Paritsis S, Galanopoulos V, Papavassiliou C (1990) Geochemistry of lavas, pumice and veins in drill core GPK-1, Palaea Kameni, Santorini. In: Hardy DA, Keller J, Galanopoulos VP, Flemming NC, Druitt TH (eds) Thera and the Aegean world III, vol 2. The Thera Foundation, London, pp 266–279
Barberi F, Carapezza ML (1994) Helium and CO2 soil gas emission from Santorini (Greece). Bull Volcanol 56:335–342
Bohnhoff M, Rische M, Meier T, Endrun B, Harjes H-P, Stavrakakis G (2004) A temporary seismic network on the Cyclades (Aegean Sea, Greece). Seismol Res Lett 75:352–357
Bohnhoff M, Rische M, Meier T, Becker D, Stavrakakis G, Harjes H-P (2006) Micro seismic activity in the Hellenic Volcanic Arc, Greece, with emphasis on the seismotectonic setting of the Santorini–Amorgos zone. Tectonophysics 423(1–4):17–33
Bond A, Sparks RSJ (1976) The Minoan eruption of Santorini, Greece. J Geol Soc London 132:1–16
Böstrom K, Widenfalk L (1984) The origin of iron-rich muds at the Kameni Islands, Santorini, Greece. Chem Geol 42:203–216
Brombach T, Caliro S, Chiodini G, Fiebig J, Hunzike J, Raco B (2003) Geochemical evidence for mixing of magmatic fluids with seawater, Nisyros hydrothermal system, Greece. Bull Volcanol 65:505–516
Carey S, Bell KLC, Nomikou P, Vougioukalakis G, Roman C, Cantner K, Bejelou K, Bourbouli M, Martin Fero J (2011) Exploration of the Coloumbo Volcanic Rift Zone. New frontiers in ocean exploration. The E/V Nautilus 2010 field season. March 2011. Oceanography 24(1):24–25
Capasso G, Carapezza ML, Federico C, Inguaggiato S, Rizzo A (2005) Geochemical monitoring of the 2002–2003 eruption at Stromboli volcano (Italy): precursory changes in the carbon and helium isotopic composition of fumarole gases and thermal waters. Bull Volcanol 68:118–134
Chiodini G, Cioni R, Di Paola GM, Dotsika E, Fytikas M, Guidi M, Leonis C, Lyberopoulou V, Magro G, Marini L, Meletlidis S, Michelot JL, Poutoukis D, Raco B, Russo M, Virgili G (1998) Geochemistry of Santorini fluids. In: Casale R, Fytikas M, Sigvaldasson G, Vougioukalakis GE (eds) The European laboratory volcanoes. Proceedings of the 2nd Workshop, Santorini, Greece, 2–4 May 1996, EUR 18161 EN, European Commission, Luxembourg, pp. 193–232
Chiodini G, Marini L (1998) Hydrothermal gas equilibria: the H2O–H2–CO2–CO–CH4 system. Geochim Cosmochim Acta 62:2673–2687
Chiodini G, Marini L, Russo M (2001) Geochemical evidence for the existence of high-temperature hydrothermal brines at Vesuvio volcano, Italy. Geochim Cosmochim Acta 65:2129–2147
Chiodini G, Brombach T, Caliro S, Cardellini C (2002) Geochemical indicators of possible ongoing volcanic unrest at Nisyros Island (Greece). Geophys Res Lett 29:1759. doi:10.1029/2001GL014355
Chiodini G, Avino R, Brombach T, Caliro S, Cardellini C, De Vita S, Frondini F, Granieri D, Marotta E, Ventura G (2004) Fumarolic and diffuse soil degassing west of Mount Epomeo, Ischia, Italy. J Volcanol Geotherm Res 133:291–309
CRC (2001) In: Lide DR (ed) Handbook of chemistry and physics, 82nd edn. CRC, Boca Raton
Dando PR, Stüben D, Varnavas SP (1999) Hydrothermalism in the Mediterranean Sea. Progr Oceanogr 44:333–367
Dimitriadis IM, Panagiotopoulos DG, Papazachos CB, Hatzidimitriou PM, Karagianni EE, Kane I (2005) Recent seismic activity (1994–2002) of the Santorini volcano using data from local seismological network. In: Fytikas M, Vougioukalakis G (eds) The South Aegean active volcanic arc: present knowledge and future perspectives: developments in volcanology, vol 7. Elsevier, Amsterdam, pp 185–203
Dimitriadis I, Karagianni E, Panagiotopoulos DG, Papazachos C, Hatzidimitriou P, Bohnhoff M, Rische M, Meier T (2009) Seismicity and active tectonics at Coloumbo Reef (Aegean Sea, Greece): monitoring an active volcano at Santorini Volcanic Center using a temporary seismic network. Tectonophysics 465:136–149
Dimitriadis I, Papazachos C, Panagiotopoulos D, Hatzidimitriou P, Bohhoff M, Rische M, Meier T (2010) P and S velocity structures of the Santorini–Coloumbo volcanic system (Aegean Sea, Greece) obtained by non-linear inversion of travel times and its tectonic implications. J Volcanol Geoth Res 195:13–30
Dotsika E, Poutoukis D, Michelot JL, Raco B (2009) Natural tracers for identifying the origin of the thermal fluids emerging along the Aegean volcanic arc (Greece): evidence of arc-type magmatic water (ATMW) participation. J Volcanol Geoth Res 179:19–32
Druitt TH, Mellors RA, Pyle DM, Sparks RSJ (1989) Explosive volcanism on Santorini, Greece. Geol Mag 126:95–126
Druitt TH, Francaviglia V (1992) Caldera formation on Santorini and the physiography of the islands in the late Bronze Age. Bull Volcanol 54:484–493
Evans WC, White LD, Rapp JB (1998) Geochemistry of some gases in hydrothermal fluids from the southern Juan de Fuca ridge. J Geophys Res 15:305–313
Fiebig J, Chiodini G, Caliro S, Rizzo A, Spangenberg J, Hunziker JC (2004) Chemical and isotopic equilibrium between CO2 and CH4 in fumarolic gas discharges: generation of CH4 in arc magmatic-hydrothermal systems. Geochim Cosmochim Acta 68(10):2321–2334
Fischer TP, Sturchio NC, Stix J, Arehart GB, Counce D, Williams SN (1997) The chemical and isotopic composition of fumarolic gases and spring discharges from Galeras Volcano, Colombia. J Volcanol Geotherm Res 77:229–253
Fouque F (1879) Santorin et ses Eruptions. Masson et Cie, Paris
Francalanci L, Vougioukalakis G, Perini G, Manetti P (2005) A west–east traverse along the magmatism of the south Aegean volcanic arc in the light of volcanological, chemical and isotope data. In: Fytikas M, Vougioukalakis G (eds) The South Aegean active volcanic arc: present knowledge and future perspectives: developments in volcanology, vol 7. Elsevier, Amsterdam, pp 65–111
Friedrich W (2000) Fire in the sea, the Santorini Volcano: natural history and the legend of Atlantis. Cambridge University Press, Cambridge
Fytikas M, Innocenti F, Manetti P, Mazzuoli R, Peccerillo A, Villari L (1984) Tertiary to Quaternary evolution of volcanism in the Aegean region. In: Dixon JE, Robertson AHF (eds) The geological evolution of the Eastern Mediterranean. Special Publ. Geol. Soc., vol 17, pp. 687–699
Fytikas M, Kolios N, Vougioukalakis GE (1990a) Post-Minoan volcanic activity on the Santorini volcano. Volcanic hazard and risk. Forecasting possibilities. In: Hardy DA, Keller J, Galanopoulos VP, Flemming NC, Druitt TH (eds) Thera and the Aegean World III Vol.2. The Thera Foundation, London, pp 183–198
Fytikas M, Karydakis G, Kavouridis TH, Kolios N, Vougioukalakis G (1990b) Geothermal research on Santorini. In: Hardy DA, Keller J, Galanopoulos VP, Flemming NC, Druitt TH (eds) Thera and the Aegean World III, vol 2. The Thera Foundation, London, pp 241–249
Georgalas G (1953) L' éruption du volcan de Santorini en 1950. Bull Volcanol 13:39–55
Georgalas GC (1962) Active volcanoes in the world including solfatara fields. Intern Volcan Assoc 12:1–40
Giggenbach WF (1975) A simple method for the collection and analysis of volcanic gas samples. Bull Volcanol 39:132–145
Giggenbach WF (1980) Geothermal gas equilibria. Geochim Cosmochim Acta 44:2021–2032
Giggenbach WF (1987) Redox processes governing the chemistry of fumarolic gas discharges from White Island, New Zealand. Appl Geochem 2:143–161
Giggenbach WF (1992) The composition of gases in geothermal and volcanic systems as a function of tectonic setting. Proc. Int. Symp. Water–Rock. Interaction WRI-8:873–878
Giggenbach WF (1997) Relative importance of thermodynamic and kinetic processes in governing the chemical and isotopic composition of carbon gases in high-heatflow sedimentary basins. Geochim Cosmochim Acta 61:3763–3785
Giggenbach WF, Garcia N, Londoño A, Rodriguez L, Rojas N, Calvache ML (1990) The chemistry of fumarolic vapor and thermal-spring discharges from the Nevado del Ruiz volcanic–magmatic–hydrothermal system, Colombia. J Volcanol Geotherm Res 42:13–39
Heiken G, McCoy F (1984) Caldera development during the Minoan eruption, Thera, Cyclades, Greece. J Geophys Res 89(B10):8441–8462
Hoefs J (1973) Stable isotope geochemistry. Springer, Berlin
ISMOSAV (2008) Website of the Institute for the Study and Monitoring of the Santorini Volcano. http://ismosav.santorini.net/.
Klein FW (1988) User's guide to HYPOINVERSE, a program for VAX computers to solve for earthquake locations. US Geol. Surv. Open-File Rept. 88
Le Pichon X, Angelier J (1979) The Hellenic arc and trench system: a key to the neotectonic evolution of the eastern Mediterranean area. Tectonophysics 60:1–42
Martini M (1993) Water and fire: Vulcano Island from 1977–1991. Geochem J 27:297–303
Lowernstern JB, Janik CJ (2003) The origin of reservoir liquids and vapors from the Geysers Geothermal Field, California. Soc Econ Geol Spec Publ 10:181–195
McKenzie DP (1972) Active tectonics of the Mediterranean region. Geophys J Royal Astron Soc 30:109–185
Montegrossi G, Tassi F, Vaselli O, Buccianti A, Garofalo K (2001) Sulphur species in volcanic gases. Anal Chem 73:709–715
Mountrakis DM et al (1996) Active deformation of Santorini. Proceed. 2nd Workshop European Lab. Volcanoes, Santorini, Greece, pp 13–22
Nagao K, Kita I, Matsuda J-I, Mitropoulos P (1991) Noble gas isotope geochemistry of volcanic gases from the Aegean island arc. Bull Geol Soc Greece 25(2):33–41
Newman AV et al (2012) Recent geodetic unrest at Santorini Caldera, Greece. Geophys Res Lett 39:L06309. doi:1029/2012GL051286
Nomikou P, Carey S, Papanikolaou D, Croff Bell K, Sakellariou D, Alexandri M, Bejelou K (2012a) Submarine volcanoes of the Coloumbo volcanic zone NE of Santorini Caldera, Greece. Glob Planet Change 90–91:135–151
Nomikou P, Papanikolaou D, Alexandri M, Sakellariou D, Rousakis G (2012b) Submarine volcanoes along the Aegean Volcanic Arc. Tectonophysics Special issue on the Aegean: a natural laboratory for tectonics. doi:10.1016/j.tecto.2012.10.001
Panagiotopoulos DG et al (1996) Seismic monitoring at the Santorini volcano. Proc. of 2nd Workshop on European Laboratory Volcanoes, Santorini, Greece, pp 311–324
Papageorgiou E, Foumelis M, Parcharidis I (2012) Long- and short-term deformation monitoring of Santorini Volcano: unrest evidence by InSAR Analysis. IEEE J Selected Topics in Appl Earth Obs Remote Sensing 5:1531–1537
Papazachos BC, Comninakis PE (1971) Geophysical and tectonic features of the Aegean arc. J Geophys Res 76:8517–8533
Papazachos BC, Panagiotopoulos DG (1993) Normal faults associated with volcanic activity and deep rupture zones in the southern Aegean volcanic arc. Tectonophysics 220:301–308
Papazachos CB, Panagiotopoulos D, Newman AV, Stiros S, Vougioukalakis G, Fytikas M, Laopoulos T, Albanakis K, Vamvakaris D, Karagianni E, Feng L, Psimoulis P, Moschas F (2012) Quantifying the current unrest of the Santorini volcano: evidence from a multiparametric dataset, involving seismological, geodetic, geochemical and other geophysical data. Geophys Res Abs, vol 14, EGU2012-14405, EGU General Assembly, 22–27 April 2012, Vienna, Austria.
Papoutsis I, Papanikolaou X, Floyd M, Hyeun JK, Kontoes C, Paradissis D, Zacharis V (2013) Mapping inflation at Santorini volcano, Greece, using GPS and InSAR. Geophys Res Lett ISSN 1944–8007. doi:10.1029/2012GL054137
Parks MM, Biggs J, England P, Mather TA, Nomikou P, Palamartchouk K, Papanikolaou X, Paradissis D, Parsons B, Pyle DM, Raptakis C, Zacharis V (2012) Evolution of Santorini Volcano dominated by episodic and rapid fluxes of melt from depth. Nat Geosci 1–6. doi:10.1038/NGEO1562
Peeters E (1978) Trace elements in the volcanic waters of Thera and Milos. In: Doumas C (ed) Thera and the Aegean World I. The Thera Foundation, London, pp 307–310
Perissoratis C (1995) The Santorini volcanic complex and its relation to the stratigraphy and structure of the Aegean arc, Greece. Mar Geol 128:37–58
Pichler H, Kussmaul S (1980) Comments on the geological map of the Santorini islands. In: Doumas C (ed) Thera and the Aegean World II. The Thera Foundation, London, pp 413–427
Piper DJW, Perissoratis C (2003) Quaternary neotectonics of the South Aegean arc. Mar Geol 198:259–288
Piper DJW, Pe-Piper G, Perissoratis C, Anastasakis G (2004) Submarine volcanic rocks around Santorini and their relationship to faulting. Proc. 5th Int. Symp. on Eastern Medit. Geol., Thessaloniki, Greece, 14–20 April 2004, pp. 873–876.
Pushkina ZV (1967) Iron, manganese, silicon, phosphorous, boron and aluminium in seawater in the area of Santorini volcano. Lithol Mineral Res 2:218–225
Pushkina ZV (1968) Copper, cobalt, vanadium, molybdenum and zinc in the sea and ooze waters of the volcano of Santorini. Lithol Mineral Res 6:883–886
Pyle DM (1990) New estimates for the volume of the Minoan eruption. In: Hardy DA, Keller J, Galanopoulos VP, Flemming NC, Druitt TH (eds) Thera and the Aegean World III, vol 2. The Thera Foundation, London, pp 113–121
Rollinson H (1993) Using geochemical data. Longman, London, p 352
Rouwet D, Inguaggiato S, Taran Y, Varley N, Santiago JA (2009) Chemical and isotopic compositions of thermal springs, fumaroles and bubbling gases at Tacanà Volcano (Mexico–Guatemala): implications for volcanic surveillance. Bull Volcanol 71:319–335
Sakellariou D, Sigurdsson H, Alexandri M, Carey S, Rousakis G, Nomikou P, Georgiou P, Ballas D (2010) Active tectonics in the Hellenic Volcanic Arc: the Coloumbo submarine volcanic zone. Bull Geol Soc Greece XLIII/2:1056–1063.
Sabatier P, Senderens JB (1897) Action du nickel sur l’éthylène. Synthèse de l’éthane. C R Acad Sci Paris 124:1358–1360
Seewald JS (1994) Evidence for metastable equilibrium between hydrocarbons under hydrothermal conditions. Nature 370:285–287
Shimizu A, Sumino H, Nagao K, Notsu K, Mitropoulos P (2005) Variation in noble gas isotopic composition of gas samples from the Aegean arc, Greece. J Volcanol Geotherm Res 140:321–339
Sigurdsson H, Carey S, Alexandri M, Vougioukalakis G, Croff KL, Roman C, Sakellariou D, Anagnostou C, Rousakis G, Ioakim C, Gogou A, Ballas D, Misaridis T, Nomikou P (2006) Marine investigations of Greece’s Santorini volcanic field. Eos 87(34):337–342
Sparks RSJ, Wilson CJN (1990) The Minoan deposits: an overview of their characteristics and interpretation. In: Hardy DA, Keller J, Galanopoulos VP, Flemming NC, Druitt TH (eds) Thera and the Aegean World III, vol 2. The Thera Foundation, London, pp 89–99
Taran YA, VArley NR, Inguaggiato S, Cienfuegos E (2010) Geochemistry and H2- and CH4-enriched hydrothermal fluids of Socorro Island, Revillagigedo Archipelago, Mexico. Evidence for serpentinization and abiogenic methane. Geofluids 10:542–555
Tedesco D, Nagao K (1996) Radiogenic 4He, 21Ne and 40Ar in fumarolic gases at Vulcano island: implication for the subducted African continental plate beneath Italy. Earth Planet Sci Lett 144:517–528
Varnavas SP, Cronan DS (1988) Arsenic, antimony and bismuth in sediments and waters from the Santorini hydrothermal field, Greece. Chem Geol 67:295–305
Varnavas SP, Cronan DS (2005) Submarine hydrothermal activity off Santorini and Milos in the Central Hellenic Volcanic Arc: a synthesis. Chem Geol 224:40–54
Vaselli O, Tassi F, Minissale A, Montegrossi G, Duarte E, Fernandez E, Bergamaschi F (2003) Fumarole migration of fluid geochemistry at Poás Volcano (Costa Rica) from 1998 to 2001. Spec Mem Geol Soc London (UK) 213:247–262
Vaselli O, Tassi F, Duarte E, Fernandez E, Poreda RJ, Delgado Huertas A (2010) Evolution of fluid geochemistry at the Turrialba volcano (Costa Rica) from 1998 to 2008. Bull Volcanol 72:397–410
Vougioukalakis GE, Mitropoulos D, Perissoratis C, Andrinopoulos A, Fytikas M (1994) The submarine volcanic centre of Coloumbo, Santorini, Greece. Bull Soc Geol Greece XXX 3:351–360
Vougioukalakis GE, Francalanci L, Sbrana A, Mitropoulos D (1995) The 1649–1650 Coloumbo submarine volcano activity, Santorini, Greece. In: Barberi F, Casale R, Fratta M (eds) The European laboratory volcanoes, workshop proceeding. European Commission, European Science Foundation, Luxembourg, pp 189–192
Vougioukalakis GE, Fytikas M (2005) Volcanic hazards in the Aegean area, relative risk evaluation, monitoring and present state of the active volcanic centers. In: Fytikas M, Vougioukalakis G (eds) The South Aegean active volcanic arc: present knowledge and future perspectives: developments in volcanology, vol 7. Elsevier, Amsterdam, pp 161–183
Acknowledgments
This work was partly supported by ISMOSAV (http://ismosav.santorini.net), the Municipality of Thera, and the Greek Earthquake Planning and Protection Organization and by the Laboratory of Fluid and Rock Geochemistry of the Department of Earth Sciences and CNR-IGG of Florence. J. Cabassi is warmly thanked for his help during the analyses of the fumarolic condensates. We thank two anonymous reviewers for their useful suggestions that helped us to improve an early version of the manuscript.
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Tassi, F., Vaselli, O., Papazachos, C.B. et al. Geochemical and isotopic changes in the fumarolic and submerged gas discharges during the 2011–2012 unrest at Santorini caldera (Greece). Bull Volcanol 75, 711 (2013). https://doi.org/10.1007/s00445-013-0711-8
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DOI: https://doi.org/10.1007/s00445-013-0711-8