Abstract
The standard gaseous enthalpy of formation for methyl fluoride is estimated by five methods, all of which are in remarkable agreement with each other and which deviate significantly from the available experimental values. The suggested derived value is 225.4±3.2 kJ/mol.
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References
Cox, J. D.; Pilcher, G.Thermochemistry of Organic and Organometallic Compounds; Academic Press: London, 1970.
Pedley, J. B.; Naylor, R. D.; Kirby, S. P.Thermochemical Data of Organic Compounds; Chapman and Hall: London, 1986.
Wagman, D. D.; Evans, W. H.; Parker, V. B.; Schumm, R. H.; Halow, I.; Bailey, S. M.; Chumey, K. L.; Nuttall, R. L.The NBS Tables of Chemical Thermodynamic Properties, J. Phys. Chem. Ref. Data 1982,11, Suppl. No. 2.
Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N.JANAF Thermochemical Tables (3rd ed.),J. Phys. Chem. Ref. Data 1985,14, Suppl. No. 1.
Lias, S. G.; Karpas, Z.; Liebman, J. F.J. Am. Chem. Soc. 1985,107, 6089.
Politzer, P.J. Am. Chem. Soc. 1969,91, 6235.
Screttas, C. S.; Micha-Screttas, M.J. Org. Chem. 1989,54, 5132.
Luo, Y-R.; Benson, S. W.J. Phys. Chem. 1988,92, 5255;
Luo, Y-R.; Benson, S. W.J. Am. Chem. Soc. 1989,111, 2480
Luo, Y-R.; Benson, S. W.Acc. Chem. Res. 1992,25, 375.
Dias, A. R.; Martinho Simoes, J. A.; Teixeira, C.; Airoldi, C.; Chagas, A. P.J. Organometal. Chem. 1987,335, 71.
Martinho Simoes, J. A. InEnergetics of Organometallic Species; Martinho Simoes, J. A. Ed.; NATO ASI Series, Kluwer: Dordrecht, 1992.
Diogo, H. P.; Simoni, J. A.; Minas da Piedade, M. E.; Dias, A. R.; Martinho SimŌes, J. A.J. Am. Chem. Soc. 1993,11, 2764.
Carson, A. S.; Laye, P. G.; Pedley, J. B.; Welsby, A. M.J. Chem. Thermo. 1993,25, 261.
Cox, J. D.; Wagman, D. D.; Medvedev, V. A. Eds.,CODATA Key Values for Thermodynamics; Hemisphere: New York, 1989.
Montgomery, R. L.; Rossini, F. D.J. Chem. Thermo. 1978,10, 471.
Liebman, J. F.; Crawford, K. S.; Slayden, S. W. InThe Chemistry of Functional Groups Supplement S: The Chemistry of Sulphur-Containing Functional Groups; Patai, S. Rappoport, Z., Eds.; Wiley: Chichester, 1993.
Slayden, S. W.; Liebman, J. F. InThe Chemistry of Functional Groups Supplement E: The Chemistry of Hydroxyl, Ether and Peroxide Groups; S. Patai, Ed.; Wiley: Chichester, 1993; Vol. 2.
Leal, J. P.; Martinho SimŌes, J. A.Organometallics 1993,12, 1442.
Sana, M.; Leroy, G.; Wilante, C.Organometallics 1991,10, 264.
Prosen, E. J.; Johnson, W. H.; Rossini, F. D.J. Res. Natl. Bur. Stand. 1946,37, 51;
Sellers, P.; Stridh, G.; Sunner, S.J. Chem. Eng. Data 1978,23, 250. Also see Ref. 1.
Benson, S. W.Chem. Rev. 1978,78, 239.
Woolf, A. A.Adv. Inorg. Chem. Radiochem. 1981,24, 1;J. Fluor. Chem. 1978,11, 307;1982,20, 627;1986,32, 453.
Liebman, J. F. InFluorine-Containing Molecules: Structure, Reactivity, Synthesis, and Applications; Liebman, J. F.; Greenberg, A.; Dolbier, W. R., Jr., Eds.; VCH: New York, 1988.
Kunkel, D. L.;Fant, A. D.;Liebman, J. F.J. Mol. Struct. 1993,300, 509.
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Liebman, J.F., SimÕes, J.A.M. & Slayden, S.W. The enthalpy of formation of methyl fluoride. Struct Chem 6, 65–69 (1995). https://doi.org/10.1007/BF02263529
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DOI: https://doi.org/10.1007/BF02263529