Abstract
The phase relations of the ternary system Cu-In-Se were studied at 750° C by quenching experiments. Special attention was given to the region CuInSe2In2Se3-In4Se3. Only four ternary phases with extended homogeneity ranges were found to exist. They were characterized by X-ray powder diffraction, electron microprobe analysis (EK8PA)' end optical microscopy. Differential thermal analysis (DTA) investigations allowed us to construct theT-x diagram of the Cu2Se-In2Se3. out between 47 and 100 mol% In2Se3. Besides, it was also possible to give a tentative diagram of the solid-liquid equilibria at 750° C and to get some information on the sub-solid existence fields beside the Cu2Se-In2Se3 cut.
Similar content being viewed by others
References
R. A. Mickelsen, in Proceedings of the Polycrystalline Thin Film Review Meeting, Golden (Colorado), May 1983 (Solar Energy Research Institute Publication CP 211-1985).
L. S. Palatnik, Ju. F. Komnik andË. I. Rogacëva,Ukr. Fiz. Ž. 9 (1964) 862.
L. S. Palatnik andË. I. Rogacëva,Dokl. AN SSSR 174 (1967) 80.
D. M. Ganbarov, G. G. Gusejnov andZ. Karaev,Izv. AN SSSR, Neorg. Mater. 8 (1972) 2211.
J. Parkes, R. D. Tomlinson, andM. J. Hampshire,J. Cryst. Growth 20 (1973) 315.
C. Manolikas, J. v. Landuyt,R. de Ridder, andS. Amelinckx,Phys. Status Solidi (a) 55 (1979) 709.
V. T. Tagirov, N. F. Gachramanov, A. G. Gusejnov andF. M. Aliev,Kristallografija 25 (1980) 411.
C. Djega-Mariadassou, A. Rimsky, R. Lesueur andH. J. Albany, in Proceedings of the 4th International Conference on Ternary and Multinary Compounds, Tokyo, 1980,Jpn J. Appl. Phys., Suppl. 19(3) (1980) 89.
B. Schumann, G. Kühn, U. Boehnke, andH. Neels,Kristallografija 26 (1981) 1195.
T. I. Konešova, A. A. Babicyna, andV. T. Kalinnikov,Izv. AN SSSR, Neorg. Mater. 18 (1982) 1483.
M. Fearheiley andK. J. Bachmann, in Proceedings of the Symposium on Materials and New Processing Technologies for Photovoltaics, Princeton, 1983 (ECS Publication 8311, 1983) p. 469.
K. J. Bachmann, M. Fearheiley, Y. H. Shing andN. Tran,Appl. Phys. Lett. 44 (1984) 407.
J. C. W. Folmer, J. A. Turner, R. Noufi andD. Cahen,J. Electrochem. Soc. 132 (1985) 1319.
G. Kühn andU. Boehnke,J. Cryst. Growth 61 (1983) 415.
S. Wagner, in Proceedings of the Electrochemical Society Meeting, San Francisco, May 1983, p. 410.
K. D. Becker andS. Wagner,Phys. Rev. B27 (1983) 5240.
H. J. v. Bardeleben,J. Appl. Phys. 56 (1984) 321.
A. Köhler, thesis (Diplomarbeit), Karl-Marx-Universität Leipzig (1983).
H. L. Hwang, C. M. Fou, S. Shea, V. Dalton, M. H. Yang andC. S. Shen, in Proceedings of the 6th International Conference on Ternary and Multinary Compounds, Caracas, August 1984,Prog. Cryst. Growth Charact. 10 (1984) 175.
L. S. Palatnik andË. I. Rogacëva,Izv. AN SSSR, Neorg. Mater. 2 (1966) 478.
R. Lesueur, C. Djega-Mariadassou, P. Charpin andH. J. Albany, in Proceedings of the Third International Conference on Ternary Compounds, Edinburgh, 1977,Inst. Phys. Conf. Ser. 35 (1977) 15.
H. Schrauber, H. Grell, K.-O, BACKHAUS andK. Fichtner, private communication.
S. Popović, A. Tonejc, B. Gržeta-Plenković, B. Ćelustka andR. Trojko,J. Appl. Cryst. 12 (1979) 416.
J. C. Mikkelsen Jr,J. Electronic Mater. 10 (1981) 541.
M. Kokta, J. R. Carruthers,M. Grasso, H. M. Kasper andB. Tell,ibid. 5 (1976) 69.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Boehnke, U.C., Kühn, G. Phase relations in the ternary system Cu-In-Se. J Mater Sci 22, 1635–1641 (1987). https://doi.org/10.1007/BF01132385
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01132385