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Transformations of benzylvinylsilanes in presence of alkylation catalysts

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    An investigation was made of the behavior of benzylvinylsilanes of general formula CH2 = CHSi(R2)CH2 \(\begin{array}{*{20}c} / \hfill & { - - - - } \hfill & \backslash \hfill \\ {\backslash \backslash } \hfill & { - - } \hfill & {//} \hfill \\ \end{array} \), (R = CH3, C2H5, Cl) in presence of various alkylation catalysts.

  2. 2.

    In presence of aluminum chloride benzyldimethylvinylsilane and benzyldichlorovinylsilane in benzene solution undergo cyclization by intramolecular alkylation.

  3. 3.

    In absence of solvent benzylvinylsilanes react in presence of aluminum chloride with formation of condensation products containing bicyclic groups.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences, USSR

    V. M. Vdovin, N. S. Nametkin, E. Sh. Finkel'shtein & V. D. Oppengeim

Authors
  1. V. M. Vdovin
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  2. N. S. Nametkin
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  3. E. Sh. Finkel'shtein
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  4. V. D. Oppengeim
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Vdovin, V.M., Nametkin, N.S., Finkel'shtein, E.S. et al. Transformations of benzylvinylsilanes in presence of alkylation catalysts. Russ Chem Bull 13, 429–434 (1964). https://doi.org/10.1007/BF00844156

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  • DOI: https://doi.org/10.1007/BF00844156

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