Skip to main content
SpringerLink
Log in

Chemioselectivity in cinnamaldehyde hydrogenation induced by shape selectivity effects in Pt-Y zeolite catalysts

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Platinum and rhodium particles encapsulated in Y-type zeolite are much more selective for the hydrogenation of cinnamaldehyde to cinnamyl alcohol than active charcoal-supported platinum and rhodium catalysts. The good selectivity is interpreted in terms of molecular constraints in the zeolite micropores which favour an end-on adsorption of the molecule via the C = O group on the encapsulated metal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P.B. Venuto and P.S. Landis, Adv. Catal. 18 (1968) 259–371.

    Google Scholar 

  2. W.F. Hölderich, in:Proc. 7th Int. Zeolite Conf., Tokyo, 1986, eds. Murakami et al. (Kodanska, Tokyo, 1986) p. 709; Ibid, in:Proc. 8th Int. Zeolite Conf., Amsterdam, 1989, eds. P.A. Jacobs and R.A. Van Santen (Elsevier, Amsterdam, 1989) pp. 69–93.

    Google Scholar 

  3. H. Van Bekkum and H.W. Kouwenhoven, in:Heterogeneous Catalysis and Fine Chemicals, eds. M. Guisnet et al. (Elsevier, Amsterdam, 1988) pp. 45–59.

    Google Scholar 

  4. D. Chiche, A. Fimiels, C. Gauthier and P. Geneste, Appl. Catal. 30 (1987) 365.

    Google Scholar 

  5. P. Rylander, in:Catalytic Hydrogenation in Organic Syntheses (Academic Press, New York, 1979) pp. 74–80.

    Google Scholar 

  6. P. Gallezot, in:Proc. 6th Int. Zeolite Conf., Reno, 1983, eds. D. Olson and A. Bisio (Butterworths, Guildford, 1984) pp. 352–367 and references therein.

    Google Scholar 

  7. D. Richard, P. Fouilloux and P. Gallezot, in:Proc. 9th Int. Congr. on Catalysis, eds. M.J. Phillips and M. Ternan, Vol. 3 (the Chemical Institute of Canada, Ottawa, 1988) pp. 1074–1081.

    Google Scholar 

  8. A. Giroir-Fendler, D. Richard and P. Gallezot, in:Heterogeneous Catalysis and Fine Chemicals, eds. M. Guisnet et al. (Elsevier, Amsterdam, 1988) p. 171.

    Google Scholar 

  9. D. Goupil, P. Fouilloux and R. Maurel, React. Kinet. Catal. Letters 35 (1987) 185.

    Google Scholar 

  10. Z. Poltarzewski, S. Galvagno, R. Pietropaolo and P. Staiti, J. Catal. 102 (1986) 190.

    Google Scholar 

  11. D. Richard, J. Ockelford, A. Giroir-Fendler and P. Gallezot, Cat. Lett. 3 (1989) 53.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut de Recherches sur la Catalyse, 2, av. Albert Einstein, 69626, Villeurbanne cédex, France

    P. Gallezot, A. Giroir-Fendler & D. Richard

  2. Davy Faraday Research Laboratory, Royal Institution, 21, Albemarle St., WIX4BS, London, UK

    D. Richard

Authors
  1. P. Gallezot
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Giroir-Fendler
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. Richard
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gallezot, P., Giroir-Fendler, A. & Richard, D. Chemioselectivity in cinnamaldehyde hydrogenation induced by shape selectivity effects in Pt-Y zeolite catalysts. Catal Lett 5, 169–174 (1990). https://doi.org/10.1007/BF00763949

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00763949

Search

Navigation