Abstract
Ionization potentials of Aln Nam , and Con Nam were measured. Appreciable decrease in the Ip value was observed as a general tendency when Na atoms are doped to the Al or Co clusters. In Al-Na systems, Ip increases when the total number of electrons satisfies the electronic shell closing. Reactivity change toward hydrogen adsorption was found to have nothing to do with the behaviors of the change in the ionization potentials of Con Nam.
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© 1992 Springer Science+Business Media Dordrecht
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Kaya, K., Nakajima, A., Naganuma, T., Hoshino, K. (1992). Electronic Structure and Reactivity of Bimetallic Clusters Containing Sodium Atoms. In: Jena, P., Khanna, S.N., Rao, B.K. (eds) Physics and Chemistry of Finite Systems: From Clusters to Crystals. NATO ASI Series, vol 374. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2645-0_27
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DOI: https://doi.org/10.1007/978-94-017-2645-0_27
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