Abstract
If all other things are equal, nanopowders will sinter faster and at lower temperatures than larger powders. However, the increased surface area to volume ratio of these materials presents additional processing challenges that correspond to greater difficulty in achieving the goal of sintering for finer powders. This is not related to the “nano” effects as described in previous chapters, but to powder characteristics that can strongly influence the sintering behavior. These characteristics can be seen as the “real life” parameters, such as agglomeration state and contaminations that if not addressed properly can confuse sintering tendencies and complicate sintering effects at the nanoscale. This chapter presents the effects that may contribute to nanosintering and the importance of adequate processing of nanopowders for achieving optimum sintering behavior.
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Notes
- 1.
Hamaker constant provides the means to determine an interaction parameter from the Van der Waals pair potential.
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This chapter was written with support from the National Science Foundation under grant DMR 0503017.
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Kelly, J.P., Graeve, O.A. (2012). Effect of Powder Characteristics on Nanosintering. In: Castro, R., van Benthem, K. (eds) Sintering. Engineering Materials, vol 35. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-31009-6_4
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