Skip to main content

Nanoscaled Boehmites’ Modes of Action in a Polymer and its Carbon Fiber Reinforced Plastic

  • Chapter
  • First Online:
Adaptive, tolerant and efficient composite structures

Part of the book series: Research Topics in Aerospace ((RTA))

Abstract

Laminates of carbon fiber reinforced plastic (CFRP), which are manufactured by injection technology, are reinforced with boehmite particles. This doping strengthens the laminates, whose original properties are weaker than those of prepregs. Besides the shear strength, compression strength and the damage tolerance, the mode of action of the nanoparticles in resin and in CFRP is also analyzed. It thereby reveals that the hydroxyl groups and even more a taurine modification of the boehmites’ surface alter the elementary polymer morphology. Consequently a new flow and reaction comportment, lower glass transition temperatures and shrinkage, as well as a changed mechanical behavior occur. Due to a structural upgrading of the matrix (higher shear stiffness, reduced residual stress), a better fiber-matrix adhesion, and differing crack paths, the boehmite nanoparticles move the degradation barrier of the material to higher loadings, thus resulting in considerably upgraded new CFRP.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Fu, S., Feng, X., Lauke, B., Mai, Y.: Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate-polymer composites. Compos. B 39, 933–961 (2008)

    Article  Google Scholar 

  2. Mahrholz, T., Stängle, J., Sinapius, M.: Quantitation of the reinforcement effect of silica nanoparticles in epoxy resins used in liquid composite moulding processes. Compos. A 40, 235–243 (2009)

    Article  Google Scholar 

  3. Schilde, C., Arlt, C., Kwade, A.: Influence of dispersing process in the production of nanoparticle composites. Chem. Ing. Tech. 81(6), 775–783 (2009)

    Article  Google Scholar 

  4. Shahid, N., Villate, R., Barron, A.: Chemically functionalized alumina nanoparticle effect on carbon fiber/epoxy composites. Compos. Sci. Technol. 65, 2250–2258 (2005)

    Article  Google Scholar 

  5. Arlt, C.: Nanoscaled boehmites’ modes of action in a polymer and its carbon fiber reinforced plastic under compression load. Doctoral Thesis, Otto-von-Guericke-Universität Magdeburg (2011)

    Google Scholar 

  6. Hosseinpour, D., Guthrie, J., Berg, J., Stolarski, V.: The effect of interfacial contribution to the mechanical properties of automotive topcoats. Prog. Org. Coat. 54, 1882–1887 (2005)

    Article  Google Scholar 

  7. Shukla, D., Kaisisomayajula, S., Parameswaran, V.: Epoxy composites using functionalized alumina platelets as reinforcements. Compos. Sci. Technol. 68, 3055–3063 (2008)

    Article  Google Scholar 

  8. Guo, Z., Pereira, T., Choi, O., Wang, Y., Hahn, H.T.: Surface functionalized alumina nanopar-ticle filled polymeric nanocomposites with enhanced mechanical properties. J. Mater. Chem. 16, 2800–2808 (2006)

    Article  Google Scholar 

  9. Zunjarrao, S.C., Singh, R.P.: Characterization of the fracture behavior of epoxy reinforced with nanometer and micrometer sized aluminum particles. Compos. Sci. Technol. 66, 2296–2305 (2006)

    Article  Google Scholar 

  10. Mukherjee, N., Wavhal, D., Timmons, R.B.: Composites of plasma surface functionalized barium titanate nanoparticles covalently attached to epoxide matrices: synthesis and evaluation. Appl. Mater. Interfaces 2(2), 397–407 (2010)

    Article  Google Scholar 

  11. Putz, K.W., Palmeri, M.J., Cohn, R.B., Andrews, R., Brinson, L.C.: Effect of cross-link density on interphase creation in polymer nanocomposites. Macromolecules 41, 6752–6756 (2008)

    Article  Google Scholar 

  12. Karlsson, P.M., Baeza, A., Palmuvist, A.E.C., Holmberg, K.: Surfactant inhibition of aluminium pigments for waterborne printing inks. Corros. Sci. 50, 2282–2287 (2008)

    Article  Google Scholar 

  13. Wetzel, B.: Mechanische Eigenschaften von Nanoverbundwerkstoffen aus Epoxydharz und keramischen Nanopartikeln. Dissertation, Technische Universität Kaiserslautern (2006)

    Google Scholar 

  14. Holst, M.: Reaktionsschwindung von Epoxidharz-Systemen. Dissertation, Technische Universität Darm-stadt (2001)

    Google Scholar 

  15. Solomko, W.P.: Eine Modellvorstelleung über Polymer-Füllstoff-Systeme. Plaste Kautsch. 22(11), 858–860 (1975)

    Google Scholar 

  16. Hoebbel, D., Nacken, M., Schmidt, H.: The effect of nanoscaled metal oxide sols on the structure and properties of glycidoxypropyltrimethoxysilane derived sols and gels. J. Sol-Gel. Sci. Technol. 19, 305–309 (2000)

    Article  Google Scholar 

  17. Fröhlich, J.: Nanostructured thermoset resins and nanocomposites containing hyperbranched blockcopolyether liquid rubbers and organophilic layered silicates. Doctoral Thesis, Universität Freiburg (2003)

    Google Scholar 

Download references

Acknowledgments

The authors would like to thank the Helmholtz Association for the funding of the virtual institute ‘nanotechnology in polymer composites’. Under its umbrella most of the research could be done. Furthermore the authors thank Sasol Germany GmbH for providing the particles and for the great cooperation all the years.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Christine Arlt .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Arlt, C., Exner, W., Riedel, U., Sturm, H., Sinapius, M. (2013). Nanoscaled Boehmites’ Modes of Action in a Polymer and its Carbon Fiber Reinforced Plastic. In: Wiedemann, M., Sinapius, M. (eds) Adaptive, tolerant and efficient composite structures. Research Topics in Aerospace. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-29190-6_4

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-29190-6_4

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-29189-0

  • Online ISBN: 978-3-642-29190-6

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics