Abstract
Suspension polymerization for divinylbenzene droplets including n-hexadecane as a nonsolvent for polydivinylbenzene (PDVB) was carried out. The hollow particles were produced under conditions where phase separation in the droplet occurred at an early stage of polymerization. The time when phase separation begins, depends on both the content of n-hexadecane and the crosslinking reaction of PDVB. Phase separation behavior during polymerization is discussed by means of phase diagrams.
Acknowledgement This work was partially supported by Grant-in-Aid for Scientific Research (Grant 14205098) from the Japan Society for the Promotion of Science (JSPS).
Part CCXXXVIII of the series “Studies on Suspension and Emulsion”.
This is a preview of subscription content, log in via an institution to check access.
Preview
Unable to display preview. Download preview PDF.
Author information
Authors and Affiliations
Corresponding author
Editor information
Rights and permissions
About this paper
Cite this paper
Okubo, M., Konishi, Y., Minami, H. Production of hollow particles by suspension polymerization of divinylbenzene with nonsolvent. In: Tauer, K. (eds) Aqueous Polymer Dispersions. Progress in Colloid and Polymer Science, vol 124. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-36474-0_11
Download citation
DOI: https://doi.org/10.1007/978-3-540-36474-0_11
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-00578-0
Online ISBN: 978-3-540-36474-0
eBook Packages: Springer Book Archive