Carbon nanotubes are tiny structures made of “rolled-up” layers of interconnected carbon atoms. Due to their extraordinary properties, nanotubes could be used in a wide range of products across several industries. Their huge commercial potential has resulted in a frenzy to establish broad patent protection on nanotube inventions. As a result, anyone attempting to commercialize nanotube faces a dense “thicket” of patents and patent applications held by various firms, universities, and government labs.
These carbon nanotube patent thickets are a vivid case study of the complicated and untested patent issues that face the nanotechnology industry as a whole. This essay explores the myriad issues posed by carbon nanotube patents. First, nanotubes and their potential commercial applications are briefly outlined. Next, the difficulty in navigating the nanotube patent thicket is presented through serious questions as to the validity and scope of some nanotube patent claims. Legal uncertainties are being raised in applying patent law doctrines— such as patentable subject matter, novelty, obviousness, and enablement—to challenge nanotube patent claims. For example, prior carbon fiber research from the 1970s and 1980s is being discovered that could potentially be used as invalidating prior art.
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References
Allison, J. and M. Lemley. 2002. The Growing Complexity of the United States Patent System. Boston University Law Review 82: 77.
Amgen, Inc. v. Chugai Pharmaceutical Co., Ltd. 13 U.S.P.Q.2d 1737, 1989 WL 169006 (D. Mass.1989).
Barton, J.A. 2002. Antitrust Treatment of Oligopolies with Mutually Blocking Patent Portfolios. ABA: Antitrust L.J. 3: 69, 854.
Baker, R.T.K. and P.S. Harris. 1978. Formation of Filamentous Carbon. Chemistry and Physics of Carbon 14: 83.
Baluch, A.S. et al. 2005. In re Kumar: The First Nanotech Patent Case in the Federal Circuit. Nanotech. L.&Bus. 2: 342.
Chen, R. et al. 2005. Noncovalent Functionalization of Carbon Nanotubes for Highly Specific Electronic Biosensors. Proceedings of the National Academy of Sciences 100: 4984.
Cheng, Y. and O. Zhou. 2003. Electron Field Emission from Carbon Nanotubes. Comptes Rendus Physique 4.9: 1021.
Chisum, D.S. et al. 2001. Principles of Patent Law. New York: Foundation Press, 2001.
Collines, P. and J. Hagerstrom. Creating High Performance Conductive Composites with Carbon Nanotubes. http://www.fibrils.com/PDFs/SPE%20Auto%20Composites%202002-09-13%20.pdf. Cited 5 December 2006.
Continental Can Co. v. Monsanto Co. 948 F.2d 1264 (Fed. Cir. 1991).
Cyrix Corp. v. Intel Corp., 846 F. Supp. 522, 537–38 (E.D. Tex) aff'd, 42 F.3d 1411 (Fed. Cir.1994).
Dalton, A.B. et al. 2003. Super-Tough Carbon-Nanotube Fibres. Nature 423.703. doi:10.1038/423703a.
Diamond v. Chakrabarty. 447 U.S. 303, 309 (1980).
Dresselhaus, M.S. et al. 1996. Science of Fullerenes and Carbon Nanotubes. San Diego, CA: Academic Press, Inc.
Du, C. et al. 2005. High Power Density Supercapacitors Using Locally Aligned Carbon Nanotube Electrodes. Nanotechnology 16: 350.
Easton Sports. Easton CNT Is Real Nanotechnology. http://baseball.eastonsports.com/pdf/EastonCNT_baseball.pdf. Cited 5 December 2006.
Endo, M. 1988. Grow Carbon Fibers in the Vapor Phase: What You Can Make Out of These Strong Materials and How to Make Them. Chemtech: 568–578.
Fang, P.H. and R. Wong. 1997. Evidence for Fullerene in a Coal of Yunnan, Southwestern China. Materials Research Innovations 1.2: 130–132.
Fontcuberta i Morral, A. et al. 2005. Carbon Nanotubes: A Solution to the Burning Interconnect Problem? Nanotech Law&Business 2.4: 321.
Forman, D. 2006. On the History and Future of Carbon Nanotubes. Small Times (July 2006). http://www.smalltimes.com/Articles/Article_Display.cfm?Section = ARTCL&ARTICLE_ID = 260008&VERSION_NUM = 2&p = 109. Cited 1 June 2007.
Fountain, H. 2006. Antique Nanotubes. New York Times (28 November 2006): D3.
Fujitsu. 2005. Fujitsu Pioneers Use of Carbon Nanotubes for Heatsinks for Semiconductors. 5 December 2005. http://www.fujitsu.com/global/news/pr/archives/month/2005/20051205-01.html. Cited 5 December 2006.
Gardner, E. 2006. Endo Cultivates Catalytic Growth—of Nanotubes and Nano Industry. Small Times Magazine 6.5 (Sept./Oct.): 28.
Gogotsia, Y. and J.A. Libera. 2000. Hydrothermal Synthesis of Multiwall Carbon Nanotubes. Journal of Materials Research 15.12: 2591–2594
Graham v. John Deere Co. 383 U.S. 1 (1966)
Heller, M. and R. Eisenberg. 1998. Can Patents Deter Innovation? The Anticommons in Biomedical Research. Science 280 (May): 698.
Hirscher, M. and M. Becher. 2003. Hydrogen Storage in Carbon Nanotubes. Journal of Nanoscience and Nanotechnology 3: 3–17.
Hu, L. et al. 2004. Percolation in Transparent and Conducting Carbon Nanotube Networks. Nano Letters 4.12: 2513. doi: 10.1021/nl048435y.
Keesman, T. et al. 2003. Field Emission Cathode Having an Electrically Conducting Material Shaped of a Narrow Rod or Knife Edge. U.S. Patent RE38,223. Issued 19 August 2003.
Koppikar, V. et al. 2004. Current Trends in Nanotech Patents: A View From Inside the Patent Office. Nanotech Law&Business 1: 24, 29.
Kymakis, E. and G.A.J. Amaratunga. 2002. Single-Wall Carbon Nanotube/Conjugated Polymer Photovoltaic Devices. Applied Physics Letters 80: 112. doi: 10.1063/1.1428416.
Lemley, M.A. 2005. Patenting Nanotechnology. Stanford Law Review 58: 601–630.
Li, J. et al. 2004. Catalyst Patterning For Nanowire Devices. U.S. Patent 6,831,017. Issued 14 December 2004.
Lux Research. 2006. Nanotech IP Battles Worth Fighting. 25 July 2006. http://www.luxresearchinc.com/press/RELEASE_Nanotech_IP_Battles_Worth_Fighting.pdf. Cited 1 June 2007.
Mack, P. et al. 2001. Electromagnetic Shielding Composite Comprising Nanotubes. U.S. Patent Number 6,265,466. Issued 24 July 2001.
Martel, R. et al. 1998. Single and Multi-wall Carbon Nanotube Field-Effect Transistors. Applied Physics Letters 73.17: 2447.
Martel, R. et al. 2002. Carbon Nanotube Field-Effect Transistors and Logic Circuits. 39th Design Automation Conference 94.
MEHL/Biophile Int'l Corp. v. Milgraum. 192 F.3d 1362, 1365 (Fed. Cir. 1999).
Merges, R.P. 1996. Contracting into Liability Rules: Intellectual Property Rights and Collective Rights Organizations. California Law Review 84 (Oct.): 1293, 1353.
Met-Coil Sys. Corp. v. Korners Unlimited, Inc. 803 F.2d 684, 686 (Fed. Cir. 1986).
Miller, J.C. et al. 2005. The Handbook of Nanotechnology Business, Policy, and Intellectual Property Law. Hoboken, NJ: John Wiley and Sons.
MPEG-2 Business Review Letter from Joel I. Klein, Assistant Attorney General, Department of Justice, Antitrust Division, to Carey R. Ramos, Esq. (June 10, 1999), 11.
Nano Science and Technology Institute. 2005. GE Global Research Develops “Ideal” Carbon Nanotube Diode. 18 Aug. 2005. http://www.crd.ge.com/04_media/news/20050819_cnd.shtml. Cited 5 Dec. 2006.
Oberlin, A. et al. 1976. Filamentous Growth of Carbon Through Benzene Decomposition. Journal of Crystal Growth 32: 335–349.
Reibold, M. et al. 2006. Carbon Nanotubes in an Ancient Damascus Sabre. Nature 444: 286.
Schutzenberger, P. and L. Schutzenberger. C. R. Academy of Sciences Paris 111 (1890).
Schwaller, M.D. and G. Goel. 2006. Getting Smaller: What Will Enablement of Nanotechnology Require? Nanotechnology Law&Business 3: 145.
Scotchmer, S. 1991. Standing on the Shoulders of Giants: Cumulative Research and the Patent Law. Journal of Economic Perspectives 5: 29–32.
Serrato, R. et al. 2005. Nanotech IP Landscape. Nanotechnology Law&Business 2: 150, 152.
Shapiro, C. 2001. Navigating the Patent Thicket: Cross Licenses, Patent Pools, and Standard-Setting. In Innovation Policy and the Economy, eds. Adam Jaffe et al., 119–150. Cambridge, MA: MIT Press.
Shi, X. et al. 2005. Rheological Behavior and Mechanical Characterization of Injectable Poly(propylene fumarate)/Single-Walled Carbon Nanotube Composites for Bone Tissue Engineering. Nanotechnology 16: S531.
Shibuya, M. et al. 1999. Detection of Buckminsterfullerene in Usual Soots and Commercial Charcoals. Fullerene Science and Technology 7.2: 181–193
Shimoda, H. et al. 2002. Lithium Intercalation into Opened Single-Wall Carbon Nanotubes: Storage Capacity and Electronic Properties. Physical Review Letters 88.1: 15502.
Stukenborg v. United States. 372 F.2d 498 (Ct. Cl. 1967).
Tennent, H. et al. 2000. Graphitic Nanofibers in Electrochemical Capacitors. U.S. Patent 6,031,711. Issued 29 February 2000.
TG Daily. 2006. Nantero to Roll Out Carbon Nanotube Memory in 2007. 3 February 2006. http://www.tgdaily.com/2006/02/03/nantero_cnt_memory/. Cited 5 December 2005.
United States v. Univis Lens Co., Inc. 316 U.S. 241 (1942).
Veedu, S.T. et al. 2005. Macroscopic Fiber Comprising Single-wall Carbon Nanotubes and Acrylonitrile-based Polymer and Process for Making the Same. U.S. Patent 6,852,410. Issued 8 February 2005.
Wong Shi Kam, N. 2005. Carbon Nanotubes as Multifunctional Biological Transporters and Near-Infrared Agents For Selective Cancer Cell Destruction. Proceedings of the National Academy of Sciences 102: 11600.
Yakobson, B.I. and R.E. Smalley. 1997. Fullerene Nanotubes: C1,000,000 and Beyond. American Scientist 85.4: 324
Zhao, B. et al. 2005. A Bone Mimic Based on the Self-Assembly of Hydroxyapatite on Chemically Functionalized Single-Walled Carbon Nanotubes. Chemistry of Materials 17: 3235.
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Harris, D.L. (2009). Carbon Nanotube Patent Thickets. In: Allhoff, F., Lin, P. (eds) Nanotechnology & Society. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-6209-4_9
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