Skip to main content

Automated Analysis of Stable Isotopes of H, C, N, O and S by Isotope Ratio Mass Spectrometry

  • Conference paper
Chemistry for the Protection of the Environment 4

Part of the book series: Environmental Science Research ((ESRH,volume 59))

Abstract

This paper reviews the principles and history of gas isotope ratio monitoring focusing on the instrumentation used in isotope ratio monitoring. We review the analytical systems currently available both for traditional dual-inlet isotope ratio mass spectrometry (DI-IRMS) and the newer continuous-flow isotope ratio mass spectrometry (CF-IRMS).

Selected applications of isotope ratio monitoring technique in mass spectrometry to geochemistry, biology, medicine and other areas of science are described. It was shown that gas isotope ratio mass spectrometry has greatly increased our understanding of the biogeochemical cycles of C, N, S and H2O in natural and agricultural ecosystems.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Barrie, A., Prosser, S.J. Automated analysis of light-element stable isotopes by isotope ratio mass spectrometry. Unpublished Materials. Europa Scientific Ltd. Crewe, Cheshire, England, 2000.

    Google Scholar 

  2. Brand, W.A. High precision isotope ratio monitoring in mass spectrometry. J. of Mass Spectrometery. 31, 1996, 225–235.

    Article  CAS  Google Scholar 

  3. Garaj, J. Fizyczne i fizyko — chemiczne metody analizy. W N T, 1981, Warsaw.

    Google Scholar 

  4. Hilkert, A.W., Douthitt, C.B., Schluter H.J., Brand W.A. Isotope ratio monitoring gas chromatography/mass spectrometry of D/H by high temperature conversion isotope ratio mass spectrometry. Rapid communications in mass spectrometry. 13, 1999, 1226–1230.

    Article  CAS  Google Scholar 

  5. McKinney, C.R., McCrea, J.M., Epstein, S., Allen, H.A., Urey, H.C. Improvements in mass spectrometers for the measurement of small differences in isotope abundance ratios. Rev. Sci. Instrum. 21, 1950, 724.

    Article  CAS  Google Scholar 

  6. Murphey, B.F. Phys. Rev. 72, 1947, 834.

    Article  CAS  Google Scholar 

  7. Namiestnik, J. Metody instrumentalne w kontroli środowiska. Gdańsk University of Technology Publisher, 1992, Gdańsk, Poland.

    Google Scholar 

  8. Oebelmann, J., Juchelka, D., Hilkert, A., Avak, H., Douthitt Ch. Authenticity control by multiple element isotope ratio determination. Unpublished Materials. Thermo Finnigan, 2001.

    Google Scholar 

  9. Nier A.O. Rev. Sci. Instrum. 11, 1940, 212.

    Article  CAS  Google Scholar 

  10. Nier A.O. Rev. Sci. Instrum. 18, 1947, 398.

    Article  CAS  Google Scholar 

  11. Prosser, S.J. A novel magnetic sector mass spectrometer for isotope ratio determination of light gases. Int. J. of Mass Spectrometry and Ion Processes. 125, 1993, 241–266.

    Article  CAS  Google Scholar 

  12. Zimnoch, M. Wachniew, P. (2000). V Isotope Wokshop. July, 1–6, 2000, Krakow, Poland

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2005 Springer Science+Business Media, Inc.

About this paper

Cite this paper

Tomaszek, J.A. (2005). Automated Analysis of Stable Isotopes of H, C, N, O and S by Isotope Ratio Mass Spectrometry. In: Mournighan, R., Dudzińska, M.R., Barich, J., Gonzalez, M.A., Black, R.K. (eds) Chemistry for the Protection of the Environment 4. Environmental Science Research, vol 59. Springer, Boston, MA. https://doi.org/10.1007/0-387-27448-0_13

Download citation

Publish with us

Policies and ethics