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Applications of the hard-soft acid-base (HSAB) principle to solid adhesion and surface tribointeractions

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Surfactants and Macromolecules: Self-Assembly at Interfaces and in Bulk

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 82))

Abstract

We attempt to extend the Hard-Soft Acid-Base (HSAB) principle for the reactions in solutions to interactions in solids. First we point out the important link between the absolute hardness of acid-and-base and the average energy gap. Then we discuss the electronic band structures of various solids, e.g., metals, semimetals, semiconductors, and insulators. On the basis of energy gaps, we elaborate various consequences of the acid-base interactions in solids. The applications of the HSAB principle and the frontier orbital concept to the solid adhesion and surface interactions between metals and polymers will be verified by experimental results reported in the literature. The new findings reported in this paper should be beneficial to those who are carrying outd research in or processing thin-film microelectronic devices or thick-film multilayer structures.

Honorary professor of the Chinese academy of Sciences.

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Author information

Authors and Affiliations

  1. Webster Research Center, Xerox Corporation, 14580, Webster, New York, USA

    L. H. Lee

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  1. L. H. Lee
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Editor information

B. Lindman J. B. Rosenholm P. Stenius

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© 1990 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Lee, L.H. (1990). Applications of the hard-soft acid-base (HSAB) principle to solid adhesion and surface tribointeractions. In: Lindman, B., Rosenholm, J.B., Stenius, P. (eds) Surfactants and Macromolecules: Self-Assembly at Interfaces and in Bulk. Progress in Colloid & Polymer Science, vol 82. Steinkopff. https://doi.org/10.1007/BFb0118276

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  • DOI: https://doi.org/10.1007/BFb0118276

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0838-5

  • Online ISBN: 978-3-7985-1688-5

  • eBook Packages: Springer Book Archive

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