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Changes of the density of charge on mineral soil components by adsorption of some metabolites of hydrocarbons

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Surfactants and Colloids in the Environment

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 95))

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Abstract

The adsorption on clay minerals and sesquioxides of some polar degradation products of naphthalene and alkylated benzenes was investigated by 14C-tracer experiments. Surface charge density of the solids was measured by titration with sodium polyethene sulfonate and polydiallyldimethyl-ammonium chloride at pH-range 4–7. Adsorption of organic anions reduced the positive charge on oxidic surfaces and increased the density of negative charge on clay minerals, respectively. The increase of the density of charge on clay minerals indicated an effective bonding mechanism. Changes of the density of charge were due to the adsorption of anions. The method is suitable for screening the interaction between polar metabolites of hydrocarbons and mineral soil components.

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Author information

Authors and Affiliations

  1. Technische Universität Hamburg-Harburg Arbeitsbereich Umweltschutztechnik, Eissendorfer Straße 40, 21073, Hamburg

    G. Hollederer & W. Calmano

Authors
  1. G. Hollederer
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  2. W. Calmano
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Editor information

M. J. Schwuger F. H. Haegel

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© 1994 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Hollederer, G., Calmano, W. (1994). Changes of the density of charge on mineral soil components by adsorption of some metabolites of hydrocarbons. In: Schwuger, M.J., Haegel, F.H. (eds) Surfactants and Colloids in the Environment. Progress in Colloid & Polymer Science, vol 95. Steinkopff. https://doi.org/10.1007/BFb0115713

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  • DOI: https://doi.org/10.1007/BFb0115713

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0994-8

  • Online ISBN: 978-3-7985-1668-7

  • eBook Packages: Springer Book Archive

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