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Carbon-13 nuclear magnetic resonance analysis, lignin content and carbohydrate composition of humic substances from salt marsh estuaries

  • Session 2: Biological And Chemical Transformation And Degradation
  • Conference paper
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Humic Substances in the Aquatic and Terrestrial Environment

Part of the book series: Lecture Notes in Earth Sciences ((LNEARTH,volume 33))

Abstract

13C nuclear magnetic resonance spectroscopy, CuO oxidation products of lignin and hydrolyzable carbohydrates were measured for fulvic and humic acids extracted from living and dead Spartina alterniflora and salt marsh sediments. With these methods, there was little evidence for early diagenetic alteration of the humic materials. No trends consistent for fulvic and humic acids were observed for either hydrolyzable carbohydrates or lignin derived phenols, and chemical measurements of these fractions did not agree with spectral estimates. Humic acids appear to contain secondary amide linkages typical of proteins and peptides.

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References

  1. Filip, Z., J. J. Alberts, M. V. Cheshire, B. A. Goodman and J. R. Bacon. Sci. Tot. Environ. 71:157 (1988).

    Google Scholar 

  2. Filip, Z. and J. J. Alberts. Sci. Tot. Environ. 73:143 (1988).

    Google Scholar 

  3. Alberts, J. J., Z. Filip, M. T. Price, D. J. Williams and M. C. Williams. Org. Geochem. 12:455 (1988).

    Google Scholar 

  4. Alberts, J. J. and Z. Filip. Sci. Tot. Environ. 81/82:353 (1989).

    Google Scholar 

  5. Alberts, J. J., Z. Filip and G. J. Leversee. Marine Chem., 28:77 (1989).

    Google Scholar 

  6. Hatcher, P. G. Organic Geochem. 11:31 (1987).

    Google Scholar 

  7. Hedges, J. I. and J. R. Ertel. Anal. Chem. 54:174 (1982).

    Google Scholar 

  8. Cowie, G. L. and J. I. Hedges. Anal. Chem. 56:497 (1984).

    Google Scholar 

  9. Raudnitz, H. Chemistry and Industry (London) 1650 (1957).

    Google Scholar 

  10. Raudnitz, H. Science 728 (1958).

    Google Scholar 

  11. Ertel, J. R. and J. I. Hedges. Geochim. Cosmochim. Acta 48:2065 (1985).

    Google Scholar 

  12. Hedges, J. I. In: F. H. Frimmel and R. F. Christman, Eds., Humic Substances and Their Role in the Environment, pp. 45–58 (Chichester: Wiley, 1988).

    Google Scholar 

  13. Hatcher, P. G. and E. C. Spiker. In: F. H. Frimmel and R. F. Christman, Eds., Humic Substances and Their Role in the Environment, pp. 59–74 (Chichester: Wiley, 1988).

    Google Scholar 

  14. Thurman, E. M., G. R. Aiken, M. Ewald, W. R. Fischer, U. Forstner, A. H. Hack, R. F. C. Mantoura, J. W. Parsons, R. Pocklington, F. J. Stevenson, R. S. Swift and B. Szpakowska. In: F. H. Frimmel and R. F. Christman, Eds., Humic Substances and Their Role in the Environment, pp. 31–43 (Chichester: Wiley, 1988).

    Google Scholar 

  15. Filip, Z., R. H. Newman and J. J. Alberts. Sci. Tot. Environ., in press (1990).

    Google Scholar 

  16. Kogel-Knabner, I., W. Zech and P. G. Hatcher. Z. Pflanzenernahr. Bodenk. 151:331 (1988).

    Google Scholar 

  17. Orem, W. H. and P. G. Hatcher. Org. Geochem. 11:73 (1987).

    Google Scholar 

  18. Gillam, A. H. and M. A. Wilson. Am. Chem. Soc. Symp. Ser. 305:128 (1986).

    Google Scholar 

  19. Ertel, J. R. and J. I. Hedges. Geochim. Cosmochim. Acta 48:2065 (1984).

    Google Scholar 

  20. Ertel, J. R., J. I. Hedges and E. M. Perdue. Science 223:485 (1984).

    Google Scholar 

  21. Piotrowski, E. G., K. M. Valentine and P. E. Pfeffer. Soil Sci. 137:194 (1984).

    Google Scholar 

  22. Wilson, M. A. and P. G. Hatcher. Org. Geochem. 12:539 (1988).

    Google Scholar 

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Bert Allard Hans Borén Anders Grimvall

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© 1991 Springer-Verlag

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Alberts, J.J., Hatcher, P.G., Price, M.T., Filip, Z. (1991). Carbon-13 nuclear magnetic resonance analysis, lignin content and carbohydrate composition of humic substances from salt marsh estuaries. In: Allard, B., Borén, H., Grimvall, A. (eds) Humic Substances in the Aquatic and Terrestrial Environment. Lecture Notes in Earth Sciences, vol 33. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0010471

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  • DOI: https://doi.org/10.1007/BFb0010471

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-53702-1

  • Online ISBN: 978-3-540-46985-8

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