Abstract
The preparation of composite electrodes by using wet chemical processes is briefly reviewed in this chapter. Electrode materials and conductive additive or binder are first dispersed in precursor solutions (dissolution–reprecipitation process) or suspensions (suspension process) of solid electrolytes, and then the solvent is evaporated to form the electrode–electrolyte composite. By using these processes, solid electrolyte covers the surface of active material, and lithium conduction path in the composite electrode can be formed with very small amount of solid electrolyte loading, and thus all-solid-state battery with composite electrode of high loading of solid electrolyte can be constructed. The wet chemical process must be very important for the practical application of the all-solid-state batteries.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Miura, A., Rosero-Navarro, N. C., Sakuda, A., Tadanaga, K., Phuc, N. H. H., Matsuda, A., et al. (2019). Liquid-phase syntheses of sulfide electrolytes for all-solid-state lithium battery. Nature Reviews Chemistry, 3, 189–193.
Park, K. H., Bai, Q., Kim, D. H., Oh, D. Y., Zhu, Y. Z., Mo, Y. F., & Jung, Y. S. (2018). Design strategies, practical considerations, and new solution processes of sulfide solid electrolytes for all-solid-state batteries. Advanced Energy Materials, 8, 1800035.
Teragawa, S., Aso, K., Tadanaga, K., Hayashi, A., & Tatsumisago, M. (2014). Preparation of Li2S–P2S5 solid electrolyte from N-methylformamide solution and application for all-solid-state lithium battery. Journal of Power Sources, 248, 939–942.
Yubuchi, S., Teragawa, S., Aso, K., Tadanaga, K., Hayashi, A., & Tatsumisago, M. (2015). Preparation of high lithium-ion conducting Li6PS5Cl solid electrolyte from ethanol solution for all-solid-state lithium batteries. Journal of Power Sources, 293, 941–945.
Park, K. H., Oh, D. Y., Choi, Y. E., Nam, Y. J., Han, L. L., Kim, J. Y., et al. (2016). Solution-processable glass LiI-Li4SnS4 superionic conductors for all-solid-state Li-ion batteries. Advanced Materials, 28, 1874–1883.
Choi, Y. E., Park, K. H., Kim, D. H., Oh, D. Y., Kwak, H. R., Lee, Y. G., & Jung, Y. S. (2017). Coatable Li4SnS4 solid electrolytes prepared from aqueous solutions for all-solid-state lithium-ion batteries. Chemsuschem, 10, 2605–2611.
Rosero-Navarro, N. C., Kinoshita, T., Miura, A., Higuchi, M., & Tadanaga, K. (2017). Effect of the binder content on the electrochemical performance of composite cathode using Li6PS5Cl precursor solution in an all-solid-state lithium battery. Ionics, 23, 1619–1624.
Kim, D. H., Oh, D. Y., Park, K. H., Choi, Y. E., Nam, Y. J., Lee, H. A., et al. (2017). Infiltration of solution-processable solid electrolytes into conventional Li-Ion-battery. Nano Letters, 17, 3013–3020.
Rosero-Navarro, N. C., Miura, A., & Tadanaga, K. (2019). Preparation of lithium ion conductive Li6PS5Cl solid electrolyte from solution for the fabrication of composite cathode of all-solid-state lithium battery. Journal of Sol-Gel Science and Technology, 89, 303–309.
Rosero-Navarro, N. C., Miura, A., & Tadanaga, K. (2018). Composite cathode prepared by argyrodite precursor solution assisted by dispersant agents for bulk-type all-solid-state batteries. Journal of Power Sources, 396, 33–40.
Yubuchi, S., Nakamura, W., Bibienne, T., Rousselot, S., Taylor, L. W., Pasquali, M., et al. (2019). All-solid-state cells with Li4Ti5O12/carbon nanotube composite electrodes prepared by infiltration with argyrodite sulfide-based solid electrolytes via liquid-phase processing. Journal Power Sources, 417, 125–131.
Kim, D. H., Lee, H. A., Song, Y. B., Park, J. W., Lee, S. M., & Jung, Y. S. (2019). Sheet-type Li6PS5Cl-infiltrated Si anodes fabricated by solution process for all-solid-state lithium-ion batteries. Journal of Power Sources, 426, 143–150.
Phuc, N. H. H., Morikawa, K., Mitsuhiro, T., Muto, H., & Matsuda, A. (2017). Synthesis of plate-like Li3PS4 solid electrolyte via liquid-phase shaking for all-solid-state lithium batteries. Ionics, 23, 2061–2067.
Yao, X., Liu, D., Wang, C., Long, P., Peng, G., Hu, Y. S., et al. (2016). High-energy all-solid-state lithium batteries with ultralong cycle life. Nano Letters, 16, 7148–7154.
Zhang, Q., Mwizerwa, J. P., Wan, H., Cai, L., Xu, X., & Yao, X. (2017). Fe3S4@Li7P3S11 nanocomposites as cathode materials for all-solid-state lithium batteries with improved energy density and low cost. Journal Materials Chemistry A, 5, 23919–23925.
Xu, R. C., Wang, X. L., Zhang, S. Z., Xia, Y., Xia, X. H., Wu, J. B., & Tu, J. P. (2018). Rational coating of Li7P3S11 solid electrolyte on MoS2 electrode for all-solid-state lithium ion batteries. Journal of Power Sources, 374, 107–112.
Oh, D. Y., Kim, D. H., Jung, S. H., Han, J. G., Choi, N. S., & Jung, Y. S. (2017). Single-step wet-chemical fabrication of sheet-type electrodes from solid-electrolyte precursors for all-solid-state lithium-ion batteries. Journal Materials Chemistry A, 5, 20771–20779.
Chida, S., Miura, A., Rosero Navarro, N. C., Higuchi, M., Phuc, N. H. H., Muto, H., et al. (2018). Liquid-phase synthesis of Li6PS5Br using ultrasonication and application to cathode composite electrodes in all-solid-state batteries. Ceramics International, 44, 742–746.
Yubuchi, S., Uematsu, M., Hotehama, C., Sakuda, A., Hayashi, A., & Tatsumisago, M. (2019). An argyrodite sulfide-based superionic conductor synthesized by a liquid-phase technique with tetrahydrofuran and ethanol. Journal Materials Chemistry A, 7, 558–566.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Tadanaga, K., Rosero-Navarro, N.C., Miura, A. (2021). Wet Chemical Processes for the Preparation of Composite Electrodes in All-Solid-State Lithium Battery. In: Kanamura, K. (eds) Next Generation Batteries. Springer, Singapore. https://doi.org/10.1007/978-981-33-6668-8_8
Download citation
DOI: https://doi.org/10.1007/978-981-33-6668-8_8
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-33-6667-1
Online ISBN: 978-981-33-6668-8
eBook Packages: EnergyEnergy (R0)