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Characterization of Cathode/Sulfide Electrolyte Interface Using a Thin-Film Model Battery

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Next Generation Batteries

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Abstract

Interfacial phenomena of oxide cathode/sulfide electrolytes are crucial for the improvement of energy density and cycle stability of all-solid-state batteries. Thin-film batteries provide a simple reaction field for mechanistic studies. We fabricated a model film battery consisted of LiCoO2 cathode, LiNbO3 buffer layer, amorphous Li3PS4 electrolyte, and Li metal anode by physical vapor deposition. Structural changes at the cathode-side interface were investigated by in situ X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) using Ar etching. The LiCoO2 lattice showed a reversible change under high voltage operation with the upper cutoff voltage of 4.5 V. A cathode electrolyte interphase (CEI) layer was formed at the interface by decomposition of LiNbO3 and Li3PS4. The ionic and electronic conductivities of the CEI layer could be crucial to improve the reaction resistance and the cycle stability of the oxide cathode/sulfide electrolyte interface.

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Author information

Authors and Affiliations

  1. Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, Yokohama, 226-8502, Japan

    Masaaki Hirayama & Kota Suzuki

  2. All-Solid-State Battery Unit, Institute of Innovative Research, Tokyo Institute of Technology, Yokohama, 226-8503, Japan

    Ryoji Kanno

  3. Research Center for Advanced Materials and Characterization, National Institute for Materials Science, Ibaraki, 305-0044, Japan

    Takuya Masuda

  4. Synchrotron Radiation Research Center, Japan Atomic Energy Agency, Hyogo, 679-5148, Japan

    Kazuhisa Tamura

Authors
  1. Masaaki Hirayama
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  2. Kota Suzuki
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  3. Ryoji Kanno
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  4. Takuya Masuda
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  5. Kazuhisa Tamura
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Corresponding author

Correspondence to Masaaki Hirayama .

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Editors and Affiliations

  1. Applied Chemistry Graduate School of Engineering, Tokyo Metropolitan University, Hachioji-shi, Japan

    Kiyoshi Kanamura

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Hirayama, M., Suzuki, K., Kanno, R., Masuda, T., Tamura, K. (2021). Characterization of Cathode/Sulfide Electrolyte Interface Using a Thin-Film Model Battery. In: Kanamura, K. (eds) Next Generation Batteries. Springer, Singapore. https://doi.org/10.1007/978-981-33-6668-8_16

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  • DOI: https://doi.org/10.1007/978-981-33-6668-8_16

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-33-6667-1

  • Online ISBN: 978-981-33-6668-8

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