Abstract
The variation in geochemistry of Ariyalur region was investigated by analyzing 71 samples for cations and anions like K+, Na+, F−, Cl−, HCO3−, Mg2+, Ca2+, SO42−, PO43−, NO3− and H4SiO4 along with the physico-chemical variables like pH, total dissolved Solid (TDS) and electrical conductivity (EC) to investigate the influence of anthropogenic activities in the study area. The statistical analysis reveals that the main factors governing the geochemistry of the regions are dissolution of secondary salts, anthropogenic activities and ion exchange. The study findings also suggest that, the enriched samples are mostly along the Archean and Cretaceous formation with high chloride, reflecting the recharge from open water source. Relatively enriched samples are observed in Cretaceous, Tertiary and Quaternary formation with low chloride indicating the recharge from meteoric source. However, depleted samples of Quaternary and Tertiary formation with high chloride indicates recharge from anthropogenic sources.
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References
Adelana SMA, Olasehinde PI, Vrbka P (2006) A quantitative estimation of groundwater recharge in parts of Sokoto Basin, Nigeria. J Environ Hydrol 14(5):1–17
Adelana SMA, Olasehinde PI, Vrbka P (2002) Groundwater recharge in the Cretaceous and Tertiary sediment aquifers of northwestern Nigeria, using hydrochemical and isotopic techniques. In: Bocanegra E-Martinez D, Massone H (eds) Groundwater and human development, pp 907–915
Aggarwal PK, Frohlich K, Kulkarni KM, Gourcy LL (2004) Stable isotope evidence for moisture sources in the Asian summer monsoon under present and past climate regimes. Geophys Res Lett 31. https://doi.org/10.1029/2004gl019911
Ayyasami K (2006) Role of oysters in biostratigraphy: a case study from the Cretaceous of the Ariyalur area, Southern India. Geosci J 10(3):237–247
Banerji RK (1972) Stratigraphy and micropaleontology of the Cauvery basin part-I exposed area. J Paleontol Soc India 17:1–24
Bruno J, Casas I (1992) The kinetics of dissolution of UO2 under reducing conditions and the influence of an oxidized surface layer: application of a continuous flow-through reactor. Geochim Cosmochim Acta 55:647–658
Caro T, Gardner TA, Stoner C, Fitzherbert E, Davenport TRB (2009) Assessing the effectiveness of protected areas paradoxes call for pluralism in evaluating conservation performance. Divers Distrib 15:178–182
Charalambous M, Raftopoulos V, Lambrinou E, Charalambous A (2013) The effectiveness of honey for the management of radiotherapy-induced mucositis in head and neck patients: a systematic review of RCT. Eur J Integr Med 5(3):217–225
Chidambaram S, Ramanathan AL, Anandhan P, Srinivasamoorthy K, Prasanna MV, Vasudevan S (2008) A statistical approach to identify the hydrogeochemically active regimes in ground waters of Erode district, Tamilnadu. Asian J Water Environ Pollut 5(3):123–135
Chidambaram S, Senthil kumar G, Prasanna MV, John Peter A, Ramanthan AL, Srinivasamoorthy K (2009) A study on the hydrogeology and Hydrogeochemistry of groundwater from different depths in a coastal aquifer: Annamalai Nagar, Tamilnadu, India. Environ Geol 57:59–73. https://doi.org/10.1007/s00254-008-1282-4
Chidambaram S, Vijayakumar V, Srinivasamoorthy K, Anandhan P, Prasanna MV, Vasudevan S (2007) A study on variation in ionic composition of aqueous system in different lithounits around Perambalur region, Tamil Nadu. Geol Soc India 70:1061–1069
Chidambaram S, Ramanathan AL, Prasanna MV, Karmegam U, Dheivanayagi V, Ramesh R, Manikandan S (2010) Study on the hydrogeochemical characteristics in groundwater, post-and pre-tsunami scenario, from Portnova to Pumpuhar, southeast coast of India. Environ Monit Assess 169(1):553–568
Coplen TB (1993) Uses of environmental isotopes. In: Alley WM (ed) Regional groundwater quality. van Nostrand Reinhold, New York, pp 227–254
Dalai TK, Krishnaswami S, Sarin MM (2002) Major ion chemistry in the headwaters of the Yamuna river system: chemical weathering, its temperature dependence and CO2 consumption in the Himalaya. Geochim Cosmochim Acta 66:3397–3416
Dansgaard W (1964) Stable isotopes in precipitation. Tellus 16(4):436–468
Das N, Deka JP, Shim J, Patel AK, Kumar A, Sarma KP, Kumar M (2016) Effect of river proximity on the arsenic and fluoride distribution in the aquifers of the Brahmaputra floodplains, Assam, Northeast India. Groundw Sustain Dev 2:130–142
Das A, Kumar M (2015) Arsenic enrichment in the groundwater of Diphu, Northeast India: coupled application of major ion chemistry, speciation modeling, and multivariate statistical techniques. CLEAN–Soil, Air, Water 43(11):1501–1513
Das N, Patel AK, Deka G, Das A, Sarma KP, Kumar M (2015) Geochemical controls and future perspective of arsenic mobilization for sustainable groundwater management: a study from Northeast India. Groundw Sustain Dev 1(1–2):92–104
Das N, Sarma KP, Patel AK, Deka JP, Das A, Kumar A, ... Kumar M (2017) Seasonal disparity in the co-occurrence of arsenic and fluoride in the aquifers of the Brahmaputra flood plains, Northeast India. Environ Earth Sci 76(4):183
Devaraj N, Thivya C, Chidambaram S, Thilagavathi R (2016) A study on the hydrogeochemical processes groundwater quality of Ariyalur region, Tamil Nadu. Int J Curr Res Dev 4(1):1–13
Gosk E, Levins I, Jørgensen LF (2006) Agricultural influence on groundwater in Latvia. Danmarks og Grønlands Geologiske Under—søgelse Rapport 85:98
Harrison S, Safford JB (2006) Regional and local species richness in an insular environment: serpentine plants in California. Ecol Monogr 76:41–56
Howari F, Abu-Rakah Y, Shinaq R (2005) Hydrochemical composition of spring waters in North Jordan. J Water Resour 32(5):607–616
Jirakova H (2010) Carbone isotopes to constrain the origin and circulation pattern of groundwater in the north-western part of the Bohemian Cretaceous Basin Czech Republic. Appl Geochem 2:1265–1279
Jouzel J, Vostok IC (1984) A continuous isotope temperature record over the last climatic cycle (160,000 years). Nature 329(6138):403–408
Karmegam U (2012) A study on the hydrogeochemical modeling of coastal aquifers in and around Kalpakkam. Unpublished Ph.D thesis, Department of Earth Sciences, Annamalai University, India
Krishnamurti TNJ, Xue HS, Bedi K, Ingles D, Oosterh O (1991) Physical initialization for numerical weather prediction over the tropics. Tellus 43AB:53–81
Kumar M, Patel AK, Das A, Kumar P, Goswami R, Deka P, Das N (2017) Hydrogeochemical controls on mobilization of arsenic and associated health risk in Nagaon district of the central Brahmaputra Plain, India. Environ Geochem Health 39(1):161–178
Ledesma-Ruiz R, Pastén-Zapata E, Parra R, Harter T, Mahlknecht J (2015) Investigation of the geochemical evolution of groundwater under agricultural land: a case study in Northeastern Mexico. J Hydrol 521:410–423
Liu AR, Chen SC, Lin XM, Wu SY, Xu T, Cai FM, Raesh J (2010) Endophytic Pestalotiopsis species spp. associated with plants of Palmae, Rhizophoraceae, Planchonellae and Podocarpaceae in Hainan, China. Afr J Microbiol Res 4:2661–2669
Madhavaraju J, Lee YI (2010) Geochemistry of the Dalmiapuram formation of the Uttatur group (Early Cretaceous), Cauvery basin, southeastern India: implications on provenance and paleo-redox conditions. Rev Mex Cienc Geol 26(2):380–394
Madhavaraju J, Ramasamy S, Alastair R, Mohan SP (2002) Clay mineralogy of the late cretaceous and early tertiary succession of the Cauvery Basin (southeastern India) Implication for sediment source and paleoclimates at the K/T boundary. Cretac Res 23:153–163
Negrel P, Pauwels H, Dewandel B, Gandolfi JM, Mascré C, Ahmed S (2011) Understanding groundwater systems and their functioning through the study of stable water isotopes in a hard-rock aquifer (Maheshwaram watershed, India). J Hydrol 397:55–70. https://doi.org/10.1016/j.jhydrol.2010.11.033
Patel AK, Das N, Goswami R, Kumar M (2019a) Arsenic mobility and potential co-leaching of fluoride from the sediments of three tributaries of the upper Brahmaputra floodplain, Lakhimpur, Assam, India. J Geochem Explor 203:45–58
Patel AK, Das N, Kumar M (2019b) Multilayer arsenic mobilization and multimetal co-enrichment in the alluvium (Brahmaputra) plains of India: a tale of redox domination along the depth. Chemosphere 224:140–150
Perry E, Paytan A (2009) Groundwater geochemistry of the Yucatan Peninsula, Mexico 1258 constraints on stratigraphy and hydrogeology. J Hydrol 1259 and 367(1–2):27–40
Prasanna MV, Chidambaram S, Pethaperumal S, Srinivasamoorthy K, John Peter A, Anandhan P, Vasanthavigar M (2008) Integrated geophysical and chemical study in the lower subbasin of Gadila River, Tamilnadu, India. Environ Geosci 15(4):145–152
Rama Rao L (1960) The problem of cretaceous-tertiary boundary. Proc Nat Inst Sci India 26:134–141
Saxena K, Ahmed S (2003) Inferring the chemical parameters for the dissolution of fluoride in groundwater. Environ Geol 43:731–736
Senthilkumar M, Elango L (2013) Geochemical processes controlling the groundwater quality in lower Palar river basin, southern India. J Earth Syst Sci 122(2):419–432
Swan JE, Trawick FI Jr, Silva DW (1985) How industrial salespeople gain customer trust. Ind Mark Manage 14:203–211
Thilagavathi R, Chidambaram S, Thivya C, Prasanna MV, Singaraja C, Tirumalesh K, Pethaperumal S (2013) Delineation of natural and anthropogenic process controlling hydrogeochemistry of layered aquifer sequence. Proc Natl Acad Sci India Sect A Phys Sci. https://doi.org/10.1007/s40010-013-0114-4
Thilagavathi R, Chidambaram S, Thivya C, Prasanna MV, Tirumalesh K (2014) An attempt to understand the weathering and anthropogenic process in a layered aquifer sequence using hydro geochemical tool. Proc Natl Acad Sci India Sect A Phys Sci. https://doi.org/10.1007/s40010-013-0114-4
WHO (2011) Uranium in drinking water. Background document for development of WHO guidelines for drinking-water quality. who/sde/wsh/03.04/118/rev/1; http://www.who.int/uraniumforcomment
Acknowledgements
The authors wish to express their sincere thanks to Isotope Hydrology Section, BARC, Mumbai for providing necessary support to carry out the isotope sample analysis for this study. Authors are also thankful to the hydro-geochemistry lab of Department of Earth Sciences for providing necessary facilities to carry out the hydrogeochemical analysis.
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Devaraj, N., Chidambaram, S., Panda, B., Thivya, C., Tirumalesh, K., Thilagavathi, R. (2020). Determination of Anthropogenic Sources in the Groundwater Chemistry Along KT Boundary of South India. In: Kumar, M., Snow, D., Honda, R. (eds) Emerging Issues in the Water Environment during Anthropocene. Springer Transactions in Civil and Environmental Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-32-9771-5_7
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