Skip to main content

Combination of Melamine Cyanurate and Black Phosphorus for Enhancing the Flame Retardant Properties of Epoxy Resin Composites

  • Chapter
  • First Online:
Functionalized Two-Dimensional Black Phosphorus and Polymer Nanocomposites as Flame Retardant

Part of the book series: Springer Theses ((Springer Theses))

  • 277 Accesses

Abstract

In Chap. 6, in order to explore the P-N synergistic effect between traditional nitrogenous flame retardant MCA and black phosphorus, MCA supramolecular/BP-NH2 nanohybrid was prepared by in situ self-assembly method. By studying the pyrolysis and combustion behavior of the composite system, the flame retardant effect and physical barrier effect of this kind of inorganic-organic hybrid flame retardant were revealed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 189.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 249.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 249.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Qiu S, Zhou Y, Zhou X, Zhang T, Wang C, Yuen RK, Hu W, Hu Y (2019) Air-stable polyphosphazene-functionalized few-layer black phosphorene for flame retardancy of epoxy resins. Small 15:1805175

    Article  Google Scholar 

  2. Kang J, Wood JD, Wells SA, Lee J-H, Liu X, Chen K-S, Hersam MC (2015) Solvent exfoliation of electronic-grade, two-dimensional black phosphorus. ACS Nano 9:3596–3604

    Article  CAS  Google Scholar 

  3. Erande MB, Pawar MS, Late DJ (2016) Humidity sensing and photodetection behavior of electrochemically exfoliated atomically thin-layered black phosphorus nanosheets. ACS Appl Mater Interfaces 8:11548–11556

    Article  CAS  Google Scholar 

  4. Chen Y, Jiang G, Chen S, Guo Z, Yu X, Zhao C, Zhang H, Bao Q, Wen S, Tang D (2015) Mechanically exfoliated black phosphorus as a new saturable absorber for both Q-switching and mode-locking laser operation. Opt Exp 23:12823–12833

    Article  CAS  Google Scholar 

  5. Ramanathan T, Abdala A, Stankovich S, Dikin D, Herrera-Alonso M, Piner R, Adamson D, Schniepp H, Chen X, Ruoff R (2008) Functionalized graphene sheets for polymer nanocomposites. Nat Nanotechnol 3:327

    Article  CAS  Google Scholar 

  6. He L, Liu Y, Lin M, Awika J, Ledoux DR, Li H, Mustapha A (2008) A new approach to measure melamine, cyanuric acid, and melamine cyanurate using surface enhanced Raman spectroscopy coupled with gold nanosubstrates. Sens Instrum Food Qual Saf 2:66–71

    Article  Google Scholar 

  7. Seki T, Yagai S, Karatsu T, Kitamura A (2008) Formation of Supramolecular polymers and discrete dimers of perylene bisimide dyes based on melamine−cyanurates hydrogen-bonding interactions. J Org Chem 73:3328–3335

    Article  CAS  Google Scholar 

  8. Liu Y, Wang Q (2006) Melamine cyanurate-microencapsulated red phosphorus flame retardant unreinforced and glass fiber reinforced polyamide 66. Polym Degrad Stabil 91:3103–3109

    Article  CAS  Google Scholar 

  9. Gijsman P, Steenbakkers R, Fürst C, Kersjes J (2002) Differences in the flame retardant mechanism of melamine cyanurate in polyamide 6 and polyamide 66. Polym Degrad Stabil 78:219–224

    Article  CAS  Google Scholar 

  10. Yang W, Song L, Hu Y, Lu H, Yuen RK (2011) Enhancement of fire retardancy performance of glass-fibre reinforced poly (ethylene terephthalate) composites with the incorporation of aluminum hypophosphite and melamine cyanurate. Compos Part B Eng 42:1057–1065

    Article  Google Scholar 

  11. Yanagimoto A, Kumazawa S, Takakuwa Y (1979) Melamine cyanurate as a flame retardant agent. In: Google Patents

    Google Scholar 

  12. Feng X, Wang X, Cai W, Hong N, Hu Y, Liew KM (2016) Integrated effect of supramolecular self-assembled sandwich-like melamine cyanurate/MoS2 hybrid sheets on reducing fire hazards of polyamide 6 composites. J Hazard Mater 320:252–264

    Article  CAS  Google Scholar 

  13. Peeterbroeck S, Alexandre M, Nagy J, Pirlot C, Fonseca A, Moreau N, Philippin G, Delhalle J, Mekhalif Z, Sporken R (2004) Polymer-layered silicate-carbon nanotube nanocomposites: unique nanofiller synergistic effect. Compos Sci Technol 64:2317–2323

    Article  CAS  Google Scholar 

  14. Zhu C, Zhai J, Wen D, Dong S (2012) Graphene oxide/polypyrrole nanocomposites: one-step electrochemical doping, coating and synergistic effect for energy storage. J Mater Chem 22:6300–6306

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shuilai Qiu .

Rights and permissions

Reprints and permissions

Copyright information

© 2021 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Qiu, S. (2021). Combination of Melamine Cyanurate and Black Phosphorus for Enhancing the Flame Retardant Properties of Epoxy Resin Composites. In: Functionalized Two-Dimensional Black Phosphorus and Polymer Nanocomposites as Flame Retardant. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-16-3552-6_6

Download citation

Publish with us

Policies and ethics