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Heterogeneous Catalysis for Chemical Fixation of CO2 via Carbonylation Reactions

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Climate Change and Green Chemistry of CO2 Sequestration

Part of the book series: Green Energy and Technology ((GREEN))

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Abstract

One of the major constituents of greenhouse gases is carbon dioxide whose concentration in the atmosphere is increasing at an alarming rate due to the disorganized human activities. Therefore, capturing CO2 and utilizing it to make various value-added chemicals is regarded as a green transformation, which thereby balances the carbon footprint. In this chapter, the advances in CO2 as the C1 source by utilizing it as a carbonylating agent for important organic transformations for the synthesis of cyclic carbonate, substituted urea, cyclic urea, carbamates, glycerol carbonate and dimethyl carbonate are discussed. These products have a wide range of applications as specialty solvents, starting materials/intermediates for polymer, paint, agrochemicals, pesticides, herbicides and pharmaceutical industries. Also, a few products like dimethyl carbonate have potential applications as fuel additives. Although CO2 is thermodynamically and kinetically stable molecule, it can be activated by basic sites in the catalyst due to the electron deficiency of the carbonyl carbon at appropriate reaction condition. Various catalyst systems such as metal oxides, mixed metal oxides, supported metal oxides, metal-organic framework, bifunctional catalysts and importance of solvent have been highlighted and discussed in detail for the efficient production of these commercially important chemicals from CO2.

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Abbreviations

ACN:

Acetonitrile

BBA:

N-benzylidenebenzylamine

BDC:

1,4-Benzenedicarboxylicacid

CDI:

1,1’-Carbonyldiimidazole

CLZ:

Conventional co-precipitation method

COCl2:

Phosgene

2-Cypy:

2-Cyanopyridine

DBU:

Dibenzylurea

DMC :

Dimethyl carbonate

DMF:

N,N-Dimethylformamide

DMSO:

Dimethyl sulfoxide

DPU:

Diphenyl urea

ECH:

Epichlorohydrin

GC:

Glycerol carbonate

MBA:

N-methylbenzylamine

MBC:

Methyl benzyl carbamate

MDI :

4,4’-Diphenylmethane diisocyanate

MeOH:

Methanol

MOF:

Metal organic framework

MPC:

Methyl-N-phenylcarbamate

MS:

Molecular sieve

NLZ:

Novel ethylene glycol combustion method

PC:

Propylene carbonate

TBAB:

Tetra-n-butylammonium bromide

TOF:

Turnover frequency

TPD:

Temperature programmed desorption

XDI :

p-Xylylene diisocyanate

ZnGly:

Zinc glycerolate

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Author information

Authors and Affiliations

  1. Materials Science and Catalysis Division, Poornaprajna Institute of Scientific Research (PPISR), Bidalur Post, Devanahalli, Bengaluru, 562164, India

    Ganapati V. Shanbhag, Nagendra Kulal & B. J. Vaishnavi

Authors
  1. Ganapati V. Shanbhag
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  2. Nagendra Kulal
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  3. B. J. Vaishnavi
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Corresponding author

Correspondence to Ganapati V. Shanbhag .

Editor information

Editors and Affiliations

  1. Climate Change Research Institute, New Delhi, India

    Malti Goel

  2. Netaji Subhas University of Technology, New Delhi, India

    T. Satyanarayana

  3. Centre for Marine Living Resources and Ecology, Kochi, Kerala, India

    Maruthadu Sudhakar

  4. Climate Change Research Institute, New Delhi, India

    D. P. Agrawal

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Shanbhag, G.V., Kulal, N., Vaishnavi, B.J. (2021). Heterogeneous Catalysis for Chemical Fixation of CO2 via Carbonylation Reactions. In: Goel, M., Satyanarayana, T., Sudhakar, M., Agrawal, D.P. (eds) Climate Change and Green Chemistry of CO2 Sequestration. Green Energy and Technology. Springer, Singapore. https://doi.org/10.1007/978-981-16-0029-6_10

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  • DOI: https://doi.org/10.1007/978-981-16-0029-6_10

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