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Self Fuelled Transformable Liquid Metal Machine

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Liquid Metal Soft Machines

Part of the book series: Topics in Mining, Metallurgy and Materials Engineering ((TMMME))

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Abstract

Synthetic self-fuelled motors, which can spontaneously convert chemical energy into mechanical activity to induce autonomous locomotion, are excellent candidates for making self-powered machines, detectors/sensors, and novel robots. The present lab (Zhang et al. in Adv Mater 27:2648–2655, 2004 [1]). discovered an extraordinary self-propulsion mechanism of synthetic motors based on liquid metal objects. Such motors could swim in a circular Petri dish or different structured channels containing aqueous solution with a pretty high velocity on the order of centimeters per second, and surprisingly long lifetime lasting for more than one hour without any assistance of external energy. The soft material liquid metal enables the motors to self-deform, which makes them highly adaptable for accomplishing tough missions in special environment. Interestingly, the motors work just like biomimetic mollusk since they closely resemble the nature by “eating” aluminum as “food”, and can change shape by closely conforming to the geometrical space it voyages in. From practical aspect, one can thus develop a self-powered pump based on the actuation of the liquid metal enabled motor. Further, such pump can also be conceived to work as a cooler. Apart from different geometrical channels, several dominating factors, including the volume of the motor, the amount of aluminum, the property of the solution and the material of the substrate etc., have been disclosed to influence the performance of the autonomous locomotion evidently. This artificial mollusk system suggests an exciting platform for molding the liquid metal science to fundamentally advance the field of self-driven soft machine design, microfluidic systems, and eventually lead to the envisioned dynamically reconfigurable intelligent soft robots in the near future. In this chapter, the typical behaviors and fundamental phenomena of the self fuelled transformable liquid metal machines were illustrated.

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References

  1. Zhang J, Yao YY, Sheng L et al (2015) Self-fueled biomimetic liquid metal mollusk. Adv Mater 27:2648–2655

    Article  CAS  Google Scholar 

  2. Wang W, Duan WT, Ahmed S et al (2013) Small power: autonomous nano and micromotors propelled by self-generated gradients. Nano Today 8:531–534

    Article  CAS  Google Scholar 

  3. Gao W, Wang J (2014) Synthetic micro/nanomotors in drug delivery. Nanoscale 6:10486–10494

    Article  CAS  Google Scholar 

  4. Sun Y, Xu S, Tan S, Liu J (2018) Multiple electrohydrodynamic effects on the morphology and running behavior of tiny liquid metal motors. Micromachines 9:192–202

    Article  Google Scholar 

  5. Yu XP, Li Y, Wu J et al (2014) Motor-based autonomous microsensor for motion and counting immunoassay of cancer biomarker. Anal Chem 86(9):4501–4507

    Article  CAS  Google Scholar 

  6. Kagan D, Calvo-Marzal P, Balasubramanian S et al (2009) Chemical sensing based on catalytic nanomotors: motion-based detection of trace silver. J Am Chem Soc 131:12082–12083

    Article  CAS  Google Scholar 

  7. Wu J, Balasubramanian S, Kagan D et al (2010) Motion-based DNA detection using catalytic nanomotors. Nat Commun 1:36

    Article  Google Scholar 

  8. Wang L, Yuan B, Lu J et al (2016) Self-propelled and long-time transport motion of PVC particles on a water surface. Adv Mater 28:4065–4070

    Article  CAS  Google Scholar 

  9. Mou F, Chen C, Ma H et al (2013) Self-propelled micromotors driven by the magnesium-water reaction and their hemolytic properties. Angew Chem Int Edit 125:7208–7212

    Article  Google Scholar 

  10. Wang Y, Hernandez RM, Jr DJB et al (2006) Bipolar electrochemical mechanism for the propulsion of catalytic nanomotors in hydrogen peroxide solutions. Langmuir 22, 10451–10456

    Article  CAS  Google Scholar 

  11. Gao W, D’Agostino M, Garcia-Gradilla V et al (2013) Multi-fuel driven Janus micromotors. Small 9:467–471

    Article  CAS  Google Scholar 

  12. Chen X, Wu G, Lan T et al (2014) Autonomous micromotor based on catalytically pneumatic behavior of balloon-like MnO(x)-graphene crumples. Chem Comm 50:7157–7159

    Article  CAS  Google Scholar 

  13. Gao W, Uygun A, Wang J (2012) Hydrogen-bubble-propelled zinc-based microrockets in strongly acidic media. J Am Chem Soc 134(2):897–900

    Article  CAS  Google Scholar 

  14. Tang X, Tang SY, Sivan V et al (2013) Photochemically induced motion of liquid metal marbles. Appl Phys Lett 103:8432–8435

    Google Scholar 

  15. Dreyfus R, Baudry J, Roper ML et al (2005) Microscopic artificial swimmers. Nature 437(7060):862–865

    Article  CAS  Google Scholar 

  16. Phillips DB, Padgett MJ, Hanna S et al (2014) Shape-induced force fields in optical trapping. Nat Photonics 8:400–405

    Article  CAS  Google Scholar 

  17. Loget G, Kuhn A (2011) Electric field-induced chemical locomotion of conducting objects. Nat Comm 2:535

    Article  Google Scholar 

  18. Chang ST, Paunov VN, Petsev DN et al (2007) Remotely powered self-propelling particles and micropumps based on miniature diodes. Nat Mater 6:235–40

    Article  CAS  Google Scholar 

  19. Brzoska JB, Brochardwyart F, Rondelez F (1993) Motions of droplets on hydrophobic model surfaces induced by thermal gradients. Langmuir 9:2220–2224

    Article  CAS  Google Scholar 

  20. Ebbens S, Tu MH, Howse JR et al (2012) Size dependence of the propulsion velocity for catalytic Janus-sphere swimmers. Phys Rev E 85:020401–020404

    Article  Google Scholar 

  21. Zhao G, Pumera M (2012) Macroscopic self-propelled objects. Chem Asian J 7:1994–2002

    Article  CAS  Google Scholar 

  22. Zhao G, Seah TH, Pumera M (2011) External-energy-independent polymer capsule motors and their cooperative behaviors. Chemistry 17:12020–120206

    Article  CAS  Google Scholar 

  23. Bassik N, Abebe BT, Gracias DH (2008) Solvent driven motion of lithographically fabricated gels. Langmuir 24:12158–12163

    Article  CAS  Google Scholar 

  24. Toyota T, Maru N, Hanczyc MM et al (2009) Self-propelled oil droplets consuming “Fuel” surfactant. J Am Chem Soc 131:5012–5013

    Article  CAS  Google Scholar 

  25. Hanczyc MM, Toyota T, Ikegami T et al (2007) Fatty acid chemistry at the oil-water interface: self-propelled oil droplets. J Am Chem Soc 129:9386–9391

    Article  CAS  Google Scholar 

  26. Chen YJ, Nagamine Y, Yoshikawa K (2012) Self-propelled motion of a droplet induced by Marangoni-driven spreading. Phy Rev E 80:016303–016307

    Article  Google Scholar 

  27. Wang Q, Yu Y, Liu J (2017) Preparations, characteristics and applications of the functional liquid metal materials. Adv Eng Mater 1700781–1700801

    Article  Google Scholar 

  28. Xu S, Zhao X, Liu J (2018) Liquid metal activated aluminum-water reaction for direct hydrogen generation at room temperature. Renew Sust Energ Rev 92:17–37

    Article  CAS  Google Scholar 

  29. Yao YY, Sheng L, Liu J (2015) Injectable spontaneous generation of tremendous self-fueled liquid metal droplet motors in a moment. arXiv:1504.02851

  30. Sheng L, He Z, Yao Y, Liu J (2015) Transient state machine enabled from the colliding and coalescence of a swarm of autonomously running liquid metal motors. Small 11:5253–5261

    Article  CAS  Google Scholar 

  31. Yuan B, Tan SC, Zhou YX, Liu J (2015) Self-powered macroscopic Brownian motion of spontaneously running liquid metal motors. Sci Bull 60:1203–1210

    Article  Google Scholar 

  32. Flamini DO, Saidman SB, Bessone JB (2006) Aluminium activation produced by gallium. Corros Sci 48:1413–1425

    Article  CAS  Google Scholar 

  33. Lee HJ, Kim CJ (2009) Surface-tension-driven microactuation based on continuous electrowetting. Microelectromechanical Syst J Microelectromech Syst 9:171–180

    Google Scholar 

  34. Zhang J, Yao YY, Liu J (2015) Autonomous convergence and divergence of the self-powered soft liquid metal vehicles. Sci Bull 60:943–951

    Article  CAS  Google Scholar 

  35. Ilyukhina AV, Ilyukhin AS, Shkolnikov EI (2012) Hydrogen generation from water by means of activated aluminum. Int J Hydrogen Energ 37:16382–16387

    Article  CAS  Google Scholar 

  36. Deng YG, Liu J (2009) Corrosion development between liquid gallium and four typical metal substrates used in chip cooling device. Appl Phys A 95:907–915

    Article  CAS  Google Scholar 

  37. Yuan B, Tan SC, Liu J (2016) Dynamic hydrogen generation phenomenon of aluminum fed liquid phase Ga-In alloy inside NaOH electrolyte. Int J Hydrogen Energ 41:1453–1459

    Article  CAS  Google Scholar 

  38. Ilyukhina AV, Kravchenko OV, Bulychev BM et al (2010) Mechanochemical activation of aluminum with gallams for hydrogen evolution from water. Int J Hydrogen Energ 35:1905–1910

    Article  CAS  Google Scholar 

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Correspondence to Jing Liu .

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Liu, J., Sheng, L., He, ZZ. (2019). Self Fuelled Transformable Liquid Metal Machine. In: Liquid Metal Soft Machines. Topics in Mining, Metallurgy and Materials Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-13-2709-4_7

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  • DOI: https://doi.org/10.1007/978-981-13-2709-4_7

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-13-2708-7

  • Online ISBN: 978-981-13-2709-4

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