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Free Radicals and Polymerization of Resinous Materials Used in Dentistry

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Electron Spin Resonance Spectroscopy in Medicine

Abstract

A composite is generally defined as a material composed of two or more distinct phases. Dental composites consist of a polymerizable resin base containing a ceramic filler that does not interfere on the polymerization reaction. Most dental polymers are based on acrylic resins made up of monomethacrylate, dimethacrylate, or trimethacrylate monomers. The most common restorative materials are based on the bisphenol A-bis(glycidyl methacrylate) (Bis-GMA), which copolymerizes with triethylene glycol dimethacrylate (TEGDMA). Also the dimethacrylate monomers bisphenol A-dimethacrylate (Bis-EMA) and a urethane dimethacrylate (UDMA) are commonly used [1].

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References

  1. Vicentin BLS, Netto AM, Dall’Antonia LH, Di Mauro E, Blümich B. Real-time polymerization monitoring in a dual-cured resin cement by magnetic resonance. Polym Bull. 2017; https://doi.org/10.1007/s00289-017-2007-1.

    Article  CAS  Google Scholar 

  2. da Silva Fontes A, Vicentin BLS, Valezi DF, da Costa MF, Sano W, Di Mauro E. A Multifrequency (X-, Q-, and W-band) EPR and DFT study of a photopolymerizable dental resin. Appl Magn Reson. 2014;45(7):681–92.

    Article  Google Scholar 

  3. Vicentin BLS, Netto AM, Blümich B, Di Mauro E. Identification of free radicals generated by different curing modes in a dental resin cement. Appl Magn Reson. 2016;47(9):1003–14.

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  4. Vicentin BLS, Salomão FM, Hoeppner MG, Di Mauro E. Influence of geometrical configuration of a translucent fiberglass post on the polymerization of a dual cure resin cement analyzed by epr spectroscopy. Appl Magn Reson. 2016;47(2):211–22.

    Article  CAS  Google Scholar 

  5. Salomão FM, Vicentin BLS, Contreras EFR, Hoeppner MG, Di Mauro E. The influence of a translucent fiberglass post on the polymerization of dual cure resin cement analyzed by electron paramagnetic resonance. Materi Res. 2015;18(5):1023–8.

    Article  Google Scholar 

  6. Truffier-Boutry D, Gallez XA, Demoustier-Champagne S, Devaux J, Mestdagh M, Champagne B, Leloup G. Identification of free radicals trapped in solid methacrylated resins. J Polym Sci A Polym Chem. 2003;41(11):1691–9.

    Article  CAS  Google Scholar 

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Correspondence to Bruno Luiz Santana Vicentin .

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Vicentin, B.L.S., Di Mauro, E. (2019). Free Radicals and Polymerization of Resinous Materials Used in Dentistry. In: Shukla, A. (eds) Electron Spin Resonance Spectroscopy in Medicine. Springer, Singapore. https://doi.org/10.1007/978-981-13-2230-3_6

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  • DOI: https://doi.org/10.1007/978-981-13-2230-3_6

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  • Publisher Name: Springer, Singapore

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  • Online ISBN: 978-981-13-2230-3

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