Abstract
Modern solid-state NMR employs a range of rf pulse sequences for a variety of tasks. There are decoupling sequences which reinforce the averaging effect of the magic-angle rotation, causing different spin species to evolve approximately independently of each other. There are also recoupling sequences which undo the averaging effect of the magic-angle rotation, temporarily restoring couplings which are otherwise inactivated by the sample spinning. The success of solid-state NMR in biological research may depend on the development of decoupling and recoupling pulse sequences which are robust with respect to a variety of undesirable spin interactions and experimental imperfections, and which function over a wide range of static magnetic fields and/or spinning frequencies.
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Lee, Y.K., Kurur, N.D., Helmle, M., Johannessen, O.G., Nielsen, N.C. and Levitt, M.H., Chem. Phys. Lett. 242 (1995) 304.
Hohwy, M., Jakobsen, H.J., Edén, M., Levitt, M.H. and Nielsen, N.C., J. Chem. Phys. 108 (1998) 2686.
Rienstra, C.M., Hatcher, M.E., Mueller, L.J., Sun, B., Fesik, S.W. and Griffin, R.G., J. Am. Chem. Soc. 120 (1998) 10602.
Edén, M. and Levitt, M.H., J. Chem. Phys. 111 (1999) 1511.
Hohwy, M., Rienstra, C.M., Jaroniec, C.P. and Griffin, R.G., J. Chem. Phys. 110 (1999) 7983.
Brinkmann, A., Edén, M. and Levitt, M.H., J. Chem. Phys. 112 (2000) 8539.
Carravetta, M., Edén, M., Zhao, X., Brinkmann, A. and Levitt, M.H., Chem. Phys. Lett. 321 (2000) 205.
Tycko, R. and Dabbagh, G., J. Am. Chem. Soc. 113 (1991) 9444.
Nielsen, N.C., Bildsoe, H., Jakobsen, H.J. and Levitt, M.H., J. Chem. Phys. 101 (1994) 1805.
Hamanaka, T., Mitsui, T., Ashida, T. and Kakudo, M., Acta Cryst. B28 (1972) 214.
Bennett, A.E., Ok, J.H., Griffin, R.G. and Vega, S., J. Chem. Phys. 96 (1992) 8624.
Baldus, M., Tomaselli, M., Meier, B.H. and Ernst, R.R., Chem. Phys. Lett. 230 (1994) 329.
Baldus, M., Geurts, D.G. and Meier, B.H., Sol. State Nucl. Magn. Reson. 11 (1998) 157.
Gullion, T. and Schaeffer, J., J. Magn. Reson. 81 (1989) 196.
Garbow, J.R. and Gullion, T., J. Magn. Reson. 95 (1991) 442.
Holl, S.M., Marshall, G.R., Beusen, D.D., Kociolek, K., Redlinski, A.S., Leplawy, M.T., McKay, R.A., Vega, S. and Schaefer, J., J. Am. Chem. Soc. 114 (1992) 4830.
Jaroniec, C.P., Tounge, B.A., Rienstra, C.M., Herzfeld, J. and Griffin, R.G., J. Magn. Reson. 146 (2000) 132.
Bennett, A.E., Rienstra, C.M., Auger, M., Lakshmi, K.V. and Griffin, R.G., J. Chem. Phys. 103 (1995) 1.
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Brinkmann, A., Carravetta, M., Zhao, X., Edén, M., auf der Günne, J.S., Levitt, M.H. (2001). Using symmetry to design pulse sequences in solid-state NMR. In: Kiihne, S.R., de Groot, H.J.M. (eds) Perspectives on Solid State NMR in Biology. Focus on Structural Biology, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2579-8_1
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DOI: https://doi.org/10.1007/978-94-017-2579-8_1
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