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Using symmetry to design pulse sequences in solid-state NMR

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Perspectives on Solid State NMR in Biology

Abstract

Modern solid-state NMR employs a range of rf pulse sequences for a variety of tasks. There are decoupling sequences which reinforce the averaging effect of the magic-angle rotation, causing different spin species to evolve approximately independently of each other. There are also recoupling sequences which undo the averaging effect of the magic-angle rotation, temporarily restoring couplings which are otherwise inactivated by the sample spinning. The success of solid-state NMR in biological research may depend on the development of decoupling and recoupling pulse sequences which are robust with respect to a variety of undesirable spin interactions and experimental imperfections, and which function over a wide range of static magnetic fields and/or spinning frequencies.

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© 2001 Springer Science+Business Media Dordrecht

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Brinkmann, A., Carravetta, M., Zhao, X., Edén, M., auf der Günne, J.S., Levitt, M.H. (2001). Using symmetry to design pulse sequences in solid-state NMR. In: Kiihne, S.R., de Groot, H.J.M. (eds) Perspectives on Solid State NMR in Biology. Focus on Structural Biology, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2579-8_1

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  • DOI: https://doi.org/10.1007/978-94-017-2579-8_1

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-5744-0

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