Abstract
It is appropriate to follow the treatment in Chapter 2 of the implications of the ‘ordered’ arrangement of the different layers of adsorbate(s) at a solid surface with a discussion of the effects of possible lateral heterogeneities of such surfaces. In soil there are several reasons for the presence of such heterogeneities. These include the diversity of the materials of the soil solid phase, the presence of different faces on the crystalline constituents of the solid phase, and the heterogeneity which is associated with small scale disorder in crystal lattices. Uneven faces of crystals are included in this small scale disorder. The latter heterogeneities will, no doubt, be associated with the manner in which the formation of the crystals took place, and in particular with the presence of impurities.
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Van Riemsdijk, W.H., Bolt, G.H., Koopal, L.K. (1991). The Electrified Interface of the Soil Solid Phase. In: Bolt, G.H., De Boodt, M.F., Hayes, M.H.B., McBride, M.B., De Strooper, E.B.A. (eds) Interactions at the Soil Colloid — Soil Solution Interface. NATO ASI Series, vol 190. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-1909-4_3
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DOI: https://doi.org/10.1007/978-94-017-1909-4_3
Publisher Name: Springer, Dordrecht
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