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Reformulation of the Concept of Jahn-Teller Vibronic Coupling Effects in Theoretical Chemistry

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Fundamental World of Quantum Chemistry

Abstract

Per-Olov Lowdin understood the role and place of vibronic coupling effects in theoretical chemistry at early stages of development of this trend. We met first in 1976, and he invited me to prepare a review of this topic for Advanced Quantum Chemistry. Two such reviews coauthored with my coworkers were published in 1982 and 1986 [1, 2]. From that time the problem of vibronic coupling of two or several electronic states under nuclear displacements from the reference high-symmetry configuration, known as the Jahn-Teller (JT) vibronic coupling effects, grew up to a whole approach to (a tool for) solving molecular and crystal problems (see [3, 4] and references therein). Research activity in this field is being especially pronounced during the last decade when it became clear that the JT effects play a significant role in understanding the origin of molecular and crystal properties, including such novel aspects as high-temperature superconductivity and colossal magnetoresistance.

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Authors and Affiliations

  1. Institute for Theoretical Chemistry Department of Chemistry & Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX, 78712-0165, USA

    I. B. Bersuker

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  1. I. B. Bersuker
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Editors and Affiliations

  1. Uppsala University, Uppsala, Sweden

    Erkki J. Brändas

  2. Bogoliubov Institute for Theoretical Physics, Kiev, Ukraine

    Eugene S. Kryachko

  3. University of Leuven, Leuven, Belgium

    Eugene S. Kryachko

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Bersuker, I.B. (2004). Reformulation of the Concept of Jahn-Teller Vibronic Coupling Effects in Theoretical Chemistry. In: Brändas, E.J., Kryachko, E.S. (eds) Fundamental World of Quantum Chemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0448-9_13

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  • DOI: https://doi.org/10.1007/978-94-017-0448-9_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-6687-9

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