Abstract
The Kupferschiefer is both one of the world’s most extensive and historic Cu—Fe—S—(Ag) deposits, with mineable concentrations located within the present borders of Germany and Poland. The grades in the Lubin (Poland) and Mansfeld-Sangerhausen (Germany) districts are both in excess of 2% Cu, and approximately 150 g/t and 30–80 g/t Ag, respectively (Kirkham, 1989). It is also a mining region well established historically. The Kupferschiefer has been mined in the eastern part of the North Sudetic Trough since the fifteenth century (Speczik et al., 1997). Agricola (1556) provided a detailed description of the Mansfeld cupriferous slates, or the Kupferschiefer. Following is a description of the overlying strata, ‘last of all, lies the cupriferous stratum, black coloured and schistose, in which there sometimes glitter scales of gold-coloured pyrites in the very thin sheets, which ... often take the forms of various living things.’ Agricola (1556) further described the smelting of the bitumenous shales, by seven repeated smeltings, which finally provided a slag containing both copper and silver.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Agricola, G. (1556) De Re Metallica. Translated by Hoover, H.C. and Hoover, L.H., Dover Publications, New York, pp. 638.
Baranger, P., Disnar, J.R., Gatellier, J.P. and Ouzounian, G. (1991) Metal reduction by sedimentary organic materials: influence of medium parameters on the reaction rate. In M. Pagel and J.L. Leroy (eds) Source, Transport and Deposition of Metals. 25th SGA Meeting, Balkema, Rotterdam, 511–514.
Barnes, H.L. (1975) Zoning of ore deposits: Types and causes. Trans. Royal Soc. Edinburgh 69: 295–311.
Bechtel, A. and Püttmann, W. (1991) The origin of the Kupferschiefer-type mineralization in the Richelsdorf hills, Germany, as deduced from stable isotope and organic geochemical studies. Chem. Geol., 91: 1–18.
Bowles, J.F.W., Gize, A.P. and Cowden, A. (1994) The mobility of the platinum-group elements in the soils of the Freetown Peninsula, Sierra Leone. Can. Miner., 32: 957–968.
Czechowski, F. and Raczynski, P. (1996) Palaeoecological observations and geochemical model of early diagenetic sulphide mineralization in the lower Zechstein deposits. Przeglad Geol. 44: 621–625 (in Polish).
Didyk, B.M., Simoneit, B.R.T., Brasell, S.C. and Eglinton, G. (1978) Organic geochemical indicators of paleoenvironmental conditions of sedimentation. Nature. 272: 216–222.
Disnar, J.R. (1981) Etude experimentale de la fixation de metaux par un materiau sedimentaire actuel d’origine algaire-II. Fixation ‘in vitro’ de UO2, Cu, Ni, Pb, Co, Mn, ainsi que de V03, Mo04, et GeO3. Geochim. Cosmochim. Acta. 45: 363–379.
Disnar, J.R. and Sureau, J.F. (1990) Organic matter in ore genesis: Progress and perspectives. Org. Geochem. 16: 577–599.
Eckardt, C.B., Wolf, M. and Maxwell, J.R. (1989) Iron porphyrins in the Permian Kupferschiefer of the Lower Rhine Basin, N, W. Germany. Org. Geochem. 14: 659–666.
Garlick, W.G. (1989) Genetic Interpretation from Ore Relations to Algal Reefs in Zambia and Zaire. Geol. Assoc. Can. Sp. Paper. 36: 471–498.
Giordano, T.H. (1985) A preliminary evaluation of organic ligands and metal-organic complexing in Mississippi Valley-Type ore solutions. Econ. Geol. 80: 96–106.
Gize, A.P. (1994) Hydrocarbon alteration in ore deposits: Resource Geol. Sp. Iss. 15: 135–140.
Gize, A.P. and Barnes, H.L. (1994) Organic contributions to Mississippi Valley-Type lead-zinc genesis–a criti-cal assessment. In: L. Fontbote and M. Boni (eds). Sediment-hosted Zn-Pb Ores. Springer-Verlag, pp. 13–26.
Goossens, H., de Leeuw, J.W., Schenck, P.A. and Brassel, S.C. (1984) Tocopherols as likely precursors of pristane in ancient sediments and crude oils. Nature. 312: 440–442.
Gustafson, L.B. and Williams, N. (1981) Sediment-hosted stratiform deposits of copper, lead and zinc. Econ. Geol. 75th Anniversary Volume: 139–178.
Hammer, J., Roesler, H.J. and Gleisberg, B. (1988) Neutronenaktivierungs analytische, saeulenchromatographische and IR-spektroskopische Untersuchungen der Bitumensubstanz des Kupferschiefers der Sangerhaeuser Mulde (DDR). Chem. Erde. 48: 61–78.
Hammer, J., Junge, F. and Stiehl, G. (1989) Isotopengeochemische (C, N, O) Untersuchungen an Kupferschieferprofilen unterschiedlischer fazieller Position. Chem. Erde. 49: 137–153.
Haranczyk, C. (1972) Ore mineralization in euxinic Lower Zechtein deposits from the Fore Sudetic Monocline. Arch. Mineral. 30: 13–173 (in Polish).
ten Haven, L.H., de Leeuw, J.W., Rullkotter, J. and Sinninghe Damste, J.S. (1987) Restricted utility of the pristane/phytane ratio as a palaeoenvironmental indicator. Nature. 330: 641–643.
Ho, E.S., Meyers, P.A., and Mauk, J.L. (1990) Organic geochemical study of mineralization in the Keweenan Nonesuch Formation at White Pine, Michigan. Org. Geochem. 16: 229–234.
Hoy, L.D. and Ohmoto, H. (1989) Constraints for the genesis of redbed-associate stratiform Cu deposits from sulphur and carbon mass-balance relations. Geol. Assoc. Can. Sp. Paper. 36: 135–149.
Jowett, E.C. (1986) Genesis of Kupferschiefer Cu—Ag deposits by convective flow of Rotliegendes brines during Triassic rifting. Econ. Geol. 81: 1823–1837.
Jowett, E.C., Pearce, G.W. and Rydzewski, A. (1987) Formation of sulfide-calcite veinlets in the Kupferschiefer Cu—Ag deposits in Poland by natural hydrofracturing during basin subsidence. J. Geol. 95: 513–526.
Kettler, R.M., Giordano, T.H. and Wood, S.A. (1997) Ore Genesis and Exploration: The Roles of Organic Matter. 1997 SEG Short Course, 17–18 October 1997, Utah.
Kirkham, R.V. (1989) Distribution, settings and genesis of sediment-hosted stratiform copper deposits. Geol. Assoc. Can. Sp. Paper, 36: 3–38.
Kirst, G. (1994) Lagerstaettenkundlich geochemische Untersuchungen an Kupferschiefer-profilen im Lagerstaettenbereich der Vorsudetischen Monokline/SW-Polen. Dipl. Arbeit. Bonn, pp. 160.
Kodina, L.A. and Galimov, E.M. (1982) Isotopic composition of the carbon (humic and sapropelic) of organic matter from marine sediments. In: IX Symp. Stable Isotopes in Geochemistry. Vernadski Institute, Moscov, 23–25 (in Russian).
Kucha, H. (1976) Organic matter, Au, Ni and Co in Zechstein deposits of the Fore-Sudetic Monocline. Ann. Pol. Geol. Soc. 46: 363–410 (in Polish).
Kucha, H. (1981) Precious metal alloys and organic matter in the Zechstein copper deposits, Poland. Tschermaks Min. Petr. Mitt. 28: 1–16.
Kucha, H. (1982) Platinum-group metals in the Zechstein copper deposits, Poland. Econ. Geol. 77: 1578–1591.
Kucha, H. and Wieczorek, A. (1988) Graphite in Kupferschiefer, Poland, and its genetic meaning. Mineral. Deposita. 23: 178–184.
Kucha, H., Mayer, W. and Piestrzynski, A. (1983) Vanadium in the copper ore deposit on the Fore-Sudetic Monocline. Mineral. Pol. 14: 35–43.
Kucha, H., Przyblowicz, W., Lankosz, M., van Langevelde, F. and Traxel, K. (1993) EPMA, micro-PIXE, synchrotron microprobe and TEM study of visible and invisible accumulations of Au and PGE in black shale and organic matrix, Kupferschiefer, Poland. Min. Mag. 57: 103–112.
Landais, P. and Gize, A.P. (1997) Organic matter in hydrothermal systems. In: H.L. Barnes (ed.) The Geochemistry of Hydrothermal Ore Deposits. J. Wiley & Sons, New York, pp. 613–655.
Large, D.J. and Gize, A.P. (1996) Pristane/phytane ratios in the mineralised Kupferschiefer of the ForeSudetic Monocline, southwest Poland. Ore Geol. Rev. 11: 89–103.
Large, D.J., MacQuaker, J., Vaughan, D.J., Sawlowicz, Z. and Gize, A.P. (1995) Evidence for low-temperature alteration of sulphides in the Kupferschiefer copper deposits of southwestern Poland. Econ. Geol. 90: 2143–2155.
Leventhal, J.S. (1986) Roles of organic matter in ore deposits. In: W.E. Dean (ed.) Organic and Ore Deposits. The Denver Region Exploration Geologists Society Symposium, pp. 7–20.
Marowsky, G. (1969) Schwefel-, Kohlenstoff-and Sauerstoffisotopenuntersuchungen aus Kupferschiefer als Beitrag zur genetischen Deutung. Contr. Miner. Petrol. 22: 290–334.
Mayer, W. and Piestrzynski, A. (1985) Ore Minerals from Lower Zechstein Sediments at the Rudna Mine, Fore-Sudetic Monocline, SW Poland. Mineral. Trans. 75: 1–72.
Michalik, M. (1995). Diagenesis of the Weissliegendes sandstones in the Fore-Sudetic Zechstein copper deposit (Poland). In: J. Pasava et al. (eds) Mineral Deposits: From Their Origin to Their Environmental Impacts. A.A. Balkema. Rotterdam, pp. 957–960.
Nakashima, S. (1991) Kinetics and thermodynamics of U reduction by natural and simple organic matter. Org Geochem. 19: 421–430.
Nakashima, S., Disnar, J.-R., Perruchet, A. and Trichet, J. (1984) Experimental study of mechanism of fixation and reduction of uranium by sedimentary organic matter under diagenetic or hydrothermal conditions. Geochim. Cosmochim. Acta. 48: 2321–2329.
Obere, J. and Serkies, J. (1968) Evolution of the Fore-Sudetian copper deposit. Econ. Geol. 63: 372–379.
Ohmoto, H. and Lasaga, A.C. (1982) Kinetics of reactions between aqueous sulphates and sulphides in hydrothermal systems. Geochim. Cosmochim. Acta 46: 1727–1745.
Oszczepalski, S. (1986) On the Zechstein copper shale lithofacies and paleoenvironments in SW Poland. Geol. Soc. Spec. Publ. 22: 171–182.
Oszczepalski, S. (1989) Kupferschiefer in Southwestern Poland: sedimentary environments, metal zoning, and ore controls. Geol. Assoc. Can. Sp. Paper. 36: 571–600.
Oszczepalski, S. and Rydzewski, A. (1991) The Kupferschiefer mineralisation in Poland. Zentralblatt Geol. Paleontol. 1: 975–999.
Parnell, J., Kucha, H. and Landais, P. (1993) (eds) Bitumens in Ore Deposits. Springer—Verlag, Berlin Heidelberg, 520 pp.
Piestrzynski, A. (1990) Uranium and thorium in the Kupferschiefer formation, Lower Zechstein, Poland. Mineral Deposita. 25: 146–151.
Piestrzynski, A., Pieczonka, J., Speczik, S., Osczepalski, S. and Banaszak, A. (1997) Noble metals from the Kupferschiefer-type deposits, Lubin-Sieroszowice, SW Poland. In: H. Papunen (ed.) Mineral Deposits: Research and Exploration—Where do They Meet? A.A. Balkema, Rotterdam, pp. 563–566.
Püttmann, W. and Gossel, W. (1990) The Permian Kupferschiefer of southwest Poland: a geochemical trap for migrating, metal-bearing solutions. Appl. Geochem. 5: 227–235.
Püttmann, W., Hagemann, H.W., Merz C. and Speczik S. (1987) Influence of organic material on mineralization processes in the Permian Kupferschiefer Formation. Org. Geochem. 13: 357–363.
Püttmann, W., Hagemann, H.W., Merz, C. and Speczik, S. (1988) Influence of organic matter on mineralization processes in the Permian Kupferschiefer Formation, Poland. Org. Geochem. 14: 357–363.
Püttmann, W., Merz, C. and Speczik, S. (1989) The secondary oxidation of organic material and its influence on Kupferschiefer mineralization of southwest Poland. Appl. Geochem. 4: 151–161.
Püttmann, W., Fermont, W.J.J., and Speczik, S. (1991a) The possible role of organic matter in transport and accumulation of metals exemplified at the Permian Kupferschiefer formation. Ore Geol. Rev. 6: 563–579.
Püttmann, W., Merz, C. and Speczik, S. (1991b) Oxidation of organic material in the Kupferschiefer and its relation to mineralization processes. Zbl. Geol. Palaeont. 4: 957–974.
Radtke, M., Welte, D.H. and Willsch, H. (1982) Geochemical study on a well in the Western Canada Basin: relation of the aromatic distribution pattern to maturity of organic matter. Geochim. Cosmochim. Acta. 46: 1–10.
Read, H.H. and Watson, J. (1975) Introduction to Geology, Earth History, vol. 2. MacMillan Press Ltd., London, pp. 371 pp.
Rentzsch, J. (1974) The Kupferschiefer in comparison with the deposits of Zambian Copperbelt. In: P. Bartholome (ed.) Gisements Stratiformes et Provinces Cupriferes. Liege: Soc. Geol. Belge, 395–418.
Rentzsch, J., Schirmer, B., Roelling, G. and Tischendorf, G. (1976) On the metal source of non-ferrous mineralizations in the Zechstein basement (Kupferschiefer type). In: J. Fedak (ed.) The Current Metallogenic Problems of Central Europe. Geol. Inst., Warsaw, pp. 171–188.
Rose, A.W. (1989) Mobility of copper and other heavy metals in sedimentary environments. Geol. Assoc. Can. Sp. Paper. 36: 97–110.
Rospondek, M. (1998). Origin and role of organic sulphur compounds in the stratiform copper deposits of the Fore-Sudetic Monocline. Ph.D. Thesis, Jagiellonian University, Krakow, 145 pp (in Polish).
Rospondek, M.J., Fijalkowska, A. and Lewandowska, A. (1993) The origin of organic matter in Lower Silesian copper-bearing shales. Ann. Soc. Geol. Polon. 63: 85–99.
Rospondek, M.J., de Leeuw, J.W., Baas, M., van Bergen, P.F. and Leereveld, H. (1994) The role of organically bound sulphur in stratiform ore sulphide deposits. Org Geochem. Geochem. 21: 1181–1191.
Rydzewski, A. (1978) Oxidized facies of the Zechstein copper-bearing shale from the Fore-Sudetic mono-cline. Przeglad. Geol. 2: 102–108 (in Polish).
Ryka, W. (1989) Rotliegendes volcanics, sediment lithologies and paleoenvironments, and Polish Basin history: an overview. Geol. Assoc. Can. Sp. paper, 36: 627–633.
Sawlowicz, Z. (1985) Significance of metalloporphyrins for the metal accumulation in the copper-bearing shales from the Zechstein copper deposits. Mineral. Pol. 16: 35–42.
Sawlowicz, Z. (1989a) Organic matter in the Zechstein in Kupferschiefer from the Fore-Sudetic Monocline. I. Bitumen. Mineral. Pol. 20: 69–86.
Sawlowicz, Z. (1989b) Isotopic composition of C, O, S from the organic-rich copper-bearing shale from the Kupferschiefer in Poland. Arch. Mineral. 44: 5–19.
Sawlowicz, Z. (1989c) On the origin of copper mineralization in the Kupferschiefer: a sulphur isotope study. Terra Nova. 1: 339–343.
Sawlowicz, Z. (1990) Primary copper sulphides from the Kupferschiefer, Poland. Mineral. Deposita, 25: 262–271.
Sawlowicz, Z. (199la) Organic matter in the Zechstein Kupferschiefer from the Fore-Sudetic Monocline. II. Kerogen. Mineral. Pol. 22: 49–67.
Sawlowicz, Z. (1991b) The relationship between copper mineralization and organic matter in the Polish Kupferschiefer. In: M. Pagel and J.L. Leroy (eds). In: Source, Transport and Deposition of Metals. A.A. Balkema. Rotterdam, pp. 589–592.
Sawlowicz, Z. (1992) Primary sulphides in the Cu—Fe—S zones of the Kupferschiefer Bed, Fore-Sudetic Monocline, Poland. Trans. Inst. Min. Met., 101: B1 — B8.
Sawlowicz, Z. (1993a) Organic matter and its significance for the genesis of the copper-bearing shales (Kupferschiefer) from the Fore-Sudetic monocline (Poland). In: J. Parnell et al. (eds). Bitumens in Ore Deposits Springer—Verlag, Berlin, pp. 431–446.
Sawlowicz, Z. (1993b) Iridium and other platinum-group elements as geochemical markers in sedimentary environments. Palaeogeogr. Palaeoclimatol. Palaeoecol 104: 253–270.
Sawlowicz, Z. and Kosacz, R. (1995) On the origin of high-grade copper ores in the Weissliegendes elevations from the Polish Kupferschiefer deposits. In: J. Pasava et al. (eds). Mineral Deposits: From Their Origin to Their Environmental Impacts. A.A. Balkema. Rotterdam, pp. 977–980.
Sawlowicz, Z. and Wedepohl, K.H. (1992) The origin of rhythmic sulphide bands from the Permian sandstones (Weissliegendes) in the footwall of the Fore-Sudetic ‘Kupferschiefer; (Poland). Mineral. Deposita. 27: 242–248.
Saxby, J.D. (1976) The significance of organic matter in ore genesis. In: K.H. Wolf (ed.). Handbook of Strata-bound and Stratiform Ore Deposits, vol. 2. Elsevier, pp. 111–133.
SCEP (1981) International Symposium Central European Permian, Jablonna, April 27–29, 1978, Proceedings, Wydawnictwa Geologiczne, Warsaw, 656.
Schouten, S., van Driel, G.B., Sinninghe Damste, J.S. and de Leeuw, J.W. (1993) Natural sulphurization of ketones and aldehydes: A key reaction in the formation of organic sulphur compounds. Geochim. Cosmochim. Acta. 57: 5111–5116.
Schwark, L. and Püttmann, W. (1990) Aromatic hydrocarbon composition of the Permian Kupferschiefer in the Lower Rhine Basin, NW Germany. Org. Geochem. 16: 749–761.
Sinninghe Damste, J.S. and de Leeuw, J.W. (1990) Analysis, structure and geochemical significance of organically-bound sulphur in geosphere: State of the art and future research. Org Geochem. 16: 1077–110.
Speczik, S. (1988) Relation of Permian base metal occurrences to the Variscan paleogeothermal field of the Fore-Sudetic Monocline (Southwestern Poland). In: G.H. Friedrich and P.M. Herzig (eds). Base Metal Sulfide Deposits. Springer Verlag, Berlin, pp. 12–23.
Speczik, S. (1993) The origin of Kupferschiefer mineralization in the Variscan Fold belt of southwestern Poland. In: R.A. Hayer et al. (eds) Rhenohercynian and Subvariscan Fold Belts VI, Vieweg Publ., Braunschweig, pp. 369–384.
Speczik, S. (1994) Kupferschiefer mineralization in the light of organic geochemistry and coal petrology studies. Geol. Q. 38: 639–650.
Speczik, S. (1995) The Kupferschiefer mineralization of Central Europe: New aspects and major areas of future research. Ore Geol. Rev. 9: 411–426.
Speczik, S. and Püttmann, W. (1987) Origin of Kupferschiefer mineralization as suggested by coal petrology and organic geochemical studies. Acta Geol. Pol. 37: 167–187.
Speczik, S., Rydzewski, A., Oszczepalski, S. and Piestrzynski, A. (1997) Exploration for Cu-Ag and Au-Pt-Pd Kupferschiefer-type deposits in SW Poland. In: H. Papunen (ed.) Mineral Deposits: Research and Exploration–Where do They Meet? A.A. Balkema, Rotterdam, 119–122.
Sun, Y., Püttmann, W. and Speczik, S. (1995) Differences in the depositional environment of basal Zechstein in southwest Poland: implication for base metal mineralization. Org. Geochem. 23: 819–835.
ten Haven, L.H., de Leeuw, J.W., Rullkotter, J. and Sinninghe Damste, J.S. (1987) Restricted utility of the pristane/phytane ratio as a palaeoenvironmental indicator. Nature. 330: 641–643.
Tissot, B. and Welte, D. (1984) Petroleum Formation and Occurrence. 2nd edn., Springer, Berlin, 365 pp.
Tokarska, K. (1971) Geochemical characteristics of bitumens from the Zechstein copper shales. Geol. Qt., 15: 67–76 (in Polish).
Trudinger, P.A., Lambert, I.B. and Skyring, G.W. (1972) Biogenic sulfide ores: a feasibility study. Econ. Geol. 67: 1114–1127.
Wedepohl, K.H. (1964) Untersuchungen am Kupferschiefer in Nordwestdeutschland. Ein Beitrag zur Deutung der genese bituminoeser Sedimente. Geochim. Cosmochim. Acta. 28: 305–364.
Wedepohl, K.H. (1994) Composition and origin of the Kupferschiefer bed. Geol. Q., 38: 623–638.
Wodzicki, A. and Piestrzynski, A. (1994) An ore genetic model for the Lubin-Sieroszowice mining district, Poland. Mineral. Deposita. 29: 30–43.
Wolf, M., David, P., Eckardt, C.B., Hagemann, H.W. and Püttmann, W. (1989) Facies and rank of the Permian Kupferschiefer from the Lower Rhine Basin and NW Germany. Int. J. Coal. Geol. 14: 119–136.
Yawanarajah, S.R., Kruge, M., Mastalerz, M. and Sliwinski, W. (1993) Organic geochemistry of Permian organic-rich sediments from the Sudetes area, Poland. Org. Geochem. 20: 267–281.
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2000 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Sawlowicz, Z., Gize, A.P., Rospondek, M. (2000). Organic matter from Zechstein copper deposits (Kupferschiefer) in Poland. In: Glikson, M., Mastalerz, M. (eds) Organic Matter and Mineralisation: Thermal Alteration, Hydrocarbon Generation and Role in Metallogenesis. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-9474-5_11
Download citation
DOI: https://doi.org/10.1007/978-94-015-9474-5_11
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-4019-0
Online ISBN: 978-94-015-9474-5
eBook Packages: Springer Book Archive