Abstract
A series of O-alkyl methylphosphonic acids were synthesized by reaction of methylphosphonic dichloride with appropriate alcohol. Obtained acids, after derivatization were examined using GC/MSD/FTIR Hewlett Packard system. Diazomethane methylation and BSTFA silylation were used to obtain derivatives convenient to GC process. Van den Doole retention indices against M-series, EI and ammonia CI MS spectra as well as FTIR spectra were obtained and discussed in the paper.
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References
E. R. J. Wills, A. G. Hulst, Frasenius Z. Anal. Chem., 321 (1985) 471
J. G. Purdon, J. G. Pagotto, R. K. Miller, J. Chromatogr., 475 (1989) 261
P. A. D’ Agostino, L. R. Provost, J. Visentini, J. Chromatogr., 402 (1987) 221
P. A. D’ Agostino, L. R. Provost, K. M. Looye, J. Chromatogr., 465 (1989) 271
P. A. D’ Agostino, A. S. Hansen, P. A. Lockwood, L. R. Provost, J. Chromatogr., 347 (1985) 257
P. A. D’ Agostino, L. R. Provost, J. Chromatogr., 598 (1992) 89
P. A. D’ Agostino, L. R. Provost, J. Chromatogr., 600 (1992) 267
S. Sass, T. L. Fisher, Org. Mass Spectr., 14(5) (1979) 257
E. R. J. Wills, A. G. Hulst, Org. Mass Spectr., 21 (1986) 763
J. L. Occlowitz, J. M. Swan, Aust. J. Chem., 19 (1966) 1187
G. Crank, J. K. Haken, J. Chromatogr., 245 (1982) 346
P. A. D’ Agostino, L. R. Provost, J. Chromatogr., 436 (1988) 399
A. Manninen, M. L. Kuitunen, L. Julin, J. Chromatogr., 394 (1987) 465
M. Kokko, J. Chromatogr., 630 (1993) 231
P. A. D’ Agostino, L. R. Provost, J. Chromatogr., 331(1) (1985) 47
M. Sokolowski, Z. Witkiewicz, Chem. Anal., 38 (1993) 139
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Sokolowski, M. (1997). Mass Spectra and Retention Parameters of Some O-Alkyl Methylphosphonic Acids. In: Heyl, M., McGuire, R. (eds) Analytical Chemistry Associated with the Destruction of Chemical Weapons. NATO ASI Series, vol 13. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5600-4_8
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DOI: https://doi.org/10.1007/978-94-011-5600-4_8
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