Abstract
The paper concerns boundary lubrication in the regime of mild wear.
The understanding of friction processes has greatly advanced as a result of combining contact mechanics with more detailed studies of the lubricant substances present at interface and the rheology of thin films.
We analyze the different physicochemical processes induced by lubricants, the principles of the formation of friction films, and we look for the relevant mechanical properties of the friction films.
New experimental techniques are described for measuring both the static and dynamic interactions of very thin lubricant films between two very smooth surfaces as they are moved normally or laterally relative to each other. A large range of the contact pressure range is studied, from 104 to 3. 109 Pa.
The lubricant analysed here is a colloidal suspension of overbased calcium carbonate stabilised in pure dodecane. Using first a surface force apparatus, we have observed the squeeze effect and the frictional resistance of the colloidal suspension using a sphere and plane geometry at nanometric scale. The compaction of an adsorbed layer composed of colloidal particles is responsible for the different values of the tangential force, and particularly for the friction instabilities. Secondly, using other tribometers that can support heavy loading, we have analyzed the high domain of pressure. The common feature of the experiments is that, after a critical pressure of ≈ 106 Pa, the colloidal particles do not flow within the film at the interface, but form a compacted “mattress” between the two surfaces. Sliding now takes place between solid surface and this compacted film, via a squeezed hydrocarbon layer. The mean shear strength of the interface can then be expressed by a relation of the form: τ = τ0 + α p , where p is the mean contact pressure.
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References
Hardy W.B.:Collected papers Cambridge Univ.Press (1936)
Beerbower A.: Boundary Lubrication, (Off. Dep. of Army Washington) AD 747 336 (1972)
Bowden F.P.and Tabor D.: The Friction and Lubrication of Solids Part 2 ( Clarendon, Oxford, 1964 )
Akhmatov A.S:. Molecular Physics of Boundary Friction, ( Israel Program for Scientific Translations Jerusalem 1966) 381.
Lim S.C.and Ashby M.F.: Wear-Mechanism Maps Acta metall. 35, 1, (1987) 1.
Lim S.C., Ashby M.F. and Brunton J.H.: Wear-Rate Transitions and their Relationship to Wear Mechanism. Acta metall. 35, 6, (1987) 1343.
Cameron A.: Lubricant Chemistry and lTibology Chemistry, Boundary and Extreme Pressure Lubrication. I. Mech. C250 (1987) 355.
Johnson K.L Contact mechanics (Cambridge University Press 1985) 105.
Halling J.: The Tribology of Surface Coatings, Particularly Ceramics Proc. Instn. Engrs. 200 C1(1986) 31.
Georges J.M.: Colloidal Behaviour of Films in Boundary Lubrication, in Microscopic aspects of Adhesion and Lubrication, J.M. Georges Eds. Tribology series 7, Elsevier, Amsterdam, (1982) 729.
Hamer J.C., Sayles S.C. and Ionnanides E.: Partic le Deformation and Counterface when Relatively Soft Particles are Squashed, Tribology transact. 3, (1989) 281.
Hill R.: “The mathematical theory of plasticity”, (Oxford Clarendon press, 1967) 240.
Kendall R.: Relevance of Contact Mechani cs to Powders, Elasticity, Friction and Agglomerate Strength, “Tribology in particulate technology”, Ed. B.J. Briscoe and M.J. Adams, pp. 91–99, (1987).
Frewing J.J, The Heat of Adsorption of Long Chain Compounds and their Effect on Boundary Lubrication Proc. Royal Soc., A182 (1944) 236.
Grew W.J.S. and Cameron A. Thermodynamics of Boundary Lubrication and Scuffing, Proc. Royal Soc., A327, 47–59 (1972)
Ho T., Hard and Soft Acids Bases Principle in Organic Chemistry, Academic Press (1977)
Mori S., Imaizumi Y., Adsorption of Model Compounds of Lubricant on Nascent Surfaces of Mild and Stainless Steels under Dynamic Conditions S.T.L.E. 31, 4, (1987) 449.
Spikes H.A.: Additive-additive and Additive-surface Interactions in Lubrication, Lubrication Sci. 2, 1,(1989), 3. Cann P.M.E., Johnston G.J. and Spikes H.A.: The formation of thick films by phosphorous based Antiwear-additives I.Mech. E. Conf. on Tribology Friction Wear and Lubrication C208/87 543.
Sakurai T., Ikoda S., and Okabe H.: The Mechanism of Reaction of Sulphur Compounds with Steel Surfaces during Boundary Lubrication, ASLE. Trans. 25, (1982) 117.
Coy R.C. and Jones R.B.: The thermal degradation of E.P. Performance of Zinc Dialkyl Dithiophosphate on Steel, ASLE Trans. 24 (1981) 24.
Georges J.M., Mathia T., Kapsa Ph., Meille G. and Montes H.: Mechanism of Boundary Lubrication with Zinc Dithiophosphate, Wear, 53 (1979), 9.
Furey M.: The Formation of Polymeric Films Directly on Rubbing Surfaces to Reduce Wear, Wear, 26 (1973) 369.; and Models of Tribopolymerisation as an Anti-Wear Mechanism: Proceed. of the Japan Int. Tribology Conf. Nagoya (1990) 1089.
Meyer K., Weh K. and Berndt H.: Antiverschleisswirksamkeit polykondensationfâhriger Additive, Schmierungstechnik, 12, (1981) 691.
Masuko M, Ohmori T. and Okabe H.: Anti-Wear Properties of Hydroxycarboxylic Acids with Alkyl Chains, Tribology Int. 21, 4 (1988) 199.
Godet M.,: The “third-body” approach: a mechanical view of wear., Wear 100 (1984) 437.
Martin J.M., Mansot J.L., Berbezier I., and Belin M.: Microstructnral ASpects of Lubricated Mild-Wear with Zinc Dithiophosphate, Wear, 107, pp. 355–366 (1986). Belin M., Martin J.M. and Mansot J.L.: Role of Iron in the Amorphisation Process in Friction-Induced Phosphate Glasses, STLE Trans. 3 (1989) 410.
Greaves G.N.: Local Order in Oxide Glasses, Proc. Int. Conf. Frascati, Italia (1982).
Watkins R.C.: The Anti-Wear Mechanism of ZDDP, part II, Tribology Int., 15, pp. 13–15 (1982).
Hsu S.H., Klaus E.E, and Cheng H.S.: A Mechano-Chemical Descriptive Model for Wear under Mixed Lubrication Conditions, Wear, 128 (1988) 307.
Marsh J.F.: Colloidal Lubricant Additives, Chemistry and Industry, 20 (1987) 470.
Kapsa Ph., Martin J.M., Blanc C., Georges J.M.: Anti-Wear Mechanism of ZDDP in the Presence of CAlcium Sulfonate Detergent, ASME Trans,Tribology J. 102 (1981) 486.
Georges J.M., Loubet J.L., Tonck A., Mazuyer D. and Hoonaert P.: ON the Mechanical Properties of Overbased Calcium Detergent Films, Proceedings of Japan International Tribology Conference, Nagoya, (1990) 517.
Elf Research Center Solaize 69 France.
Tonck A., Kapsa Ph, Sabot J.: Mechanical Behavior of Tribochemical Films under a Cyclic Tangental Load in a Ball-Flat Contact, ASME Trans., Tribology J., 108 (1986) 117.
Mansot J.L., Martin J.M., Dexpert H., Faure D., Hoomaert P, Gallo R.: Local Structure AnaLysis in Overbased Reversed Micelles,, Physica B, 158 (1989) 237.
Tonck A., Georges J.M. and Loubet J.L.: Measurements of Intermolecular Forces and Rheology of Dodecane between Alumina Surfaces, J. Colloid and Interface Sc., 126, 1 (1988) 150.
Tonck A., Sabot J. and Georges J.M.: Microdisplacements between Two Elastic Bodies Separated by a Thin Film of Polystyrene, ASME Trans., Tribology J., 106 (1984) 35.
Ehrburger F. and Lahaye J.: Behaviour of Colloidal Silicas during Uniaxial Compaction, J. Phys. France, 50, 11 (1989) 1349.
Georges J.M., Loubet J.L. and Tonck A.: Molecular Contact Pressure in Tribology, in “New Materials Approaches to Tribology; Theory and Application”, L.E. Pope, L.L. Fehrenbacher, W.O. Winer Eds. M.R.S. (MRS Pittsburg, PA.) 140 (1989) 67.
Ashby M.F. and Jones D.H.: Int. Series. 34, Pergamon Press (1985).
Tabor D.: Friction and Wear-Developments over the last fifty years, Inst. Mech. Eng. C 245 (1987) 157.
Martin J.M., Belin M. and Mansot J.L.: Exafs of Calcium in Overbased Micelles, J. Phys. France, 47, 12, 887, (1986).
Bowers R.C. and Zisman W.A.: Pressre Effects on the Friction Coefficient of Thin-Film Solid Lubricants, J. Appl. Phys. 39, 12, (1968) 5385.
Briscoe B.J. and Tabor D.: Shear Properties of Thin Polymeric Films, J. Adhesion, 9(1978) 145. and Briscoe B.J.: The Interfacial Friction of Polymer Composite Materials: General Fundamental Principles, in Friction and Wear of Composite Materials K. Freidrich Eds. (Elsevier Scientific Publishers 1985) chapt.2,39.
Singer, I.L., Bolster R.N., Wegand J., Fayeulle S. and Stupp B.C.: Hertzian Stress Contribution to Low Friction Behavior of Thin MoS2 Coatings, Appl. Phys. Lett. 57, 10 (1990) 995.
Georges J.M., Mazuyer D., Tonck A. and Loubet J.L.: Friction of Thin Colloidal Layer, J.Phys. Condo Mat. 2, (1990) 399.
By thin, we mean films whose thickness is much less than the Hertzian contact radius, which in these experiments varied from 10 to 200 mm.
Tabor D.: The role of Surface and Intermolecular Forces in Thin Film Lubrication, Microscopic aspects of Adhesion and Lubrication, J.M. Georges Eds. Tribology series 7, Elsevier, Amsterdam, (1982) 651.
Ducoulombier D., Zhou H., Boned C., Peyrelasse J., Saint-Guirons H., and Xans P: Viscosity of Liquid Hydrocarbons, J.Phys. Chem. 90 (1986) 1692.
Bridgeman P.G.: Pressure Effect on hydrocarbons, Proc. Am. Acad. Arts Sci. 71, (1936), 387.
Hallouis M., Mansot J.L. and Martin J.M.: Colloidal Anti-Wear Additives part II, Tribological, behavior., J. Colloid Int. To be publish.
Bell J.C. Delargy K.M. and Seeney A.M. The removal of substrate material through thick Zinc Dithiophosphate Antiwear Films. 18Th Leeds-Lyon Symposium 1991 (To be published.)
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Georges, JM., Mazuyer, D., Loubet, JL., Tonck, A. (1992). Friction with Colloidal Lubrication. In: Singer, I.L., Pollock, H.M. (eds) Fundamentals of Friction: Macroscopic and Microscopic Processes. NATO ASI Series, vol 220. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2811-7_14
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