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Part of the book series: NATO ASI Series ((NSSE,volume 220))

Abstract

The paper concerns boundary lubrication in the regime of mild wear.

The understanding of friction processes has greatly advanced as a result of combining contact mechanics with more detailed studies of the lubricant substances present at interface and the rheology of thin films.

We analyze the different physicochemical processes induced by lubricants, the principles of the formation of friction films, and we look for the relevant mechanical properties of the friction films.

New experimental techniques are described for measuring both the static and dynamic interactions of very thin lubricant films between two very smooth surfaces as they are moved normally or laterally relative to each other. A large range of the contact pressure range is studied, from 104 to 3. 109 Pa.

The lubricant analysed here is a colloidal suspension of overbased calcium carbonate stabilised in pure dodecane. Using first a surface force apparatus, we have observed the squeeze effect and the frictional resistance of the colloidal suspension using a sphere and plane geometry at nanometric scale. The compaction of an adsorbed layer composed of colloidal particles is responsible for the different values of the tangential force, and particularly for the friction instabilities. Secondly, using other tribometers that can support heavy loading, we have analyzed the high domain of pressure. The common feature of the experiments is that, after a critical pressure of ≈ 106 Pa, the colloidal particles do not flow within the film at the interface, but form a compacted “mattress” between the two surfaces. Sliding now takes place between solid surface and this compacted film, via a squeezed hydrocarbon layer. The mean shear strength of the interface can then be expressed by a relation of the form: τ = τ0 + α p , where p is the mean contact pressure.

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References

  1. Hardy W.B.:Collected papers Cambridge Univ.Press (1936)

    Google Scholar 

  2. Beerbower A.: Boundary Lubrication, (Off. Dep. of Army Washington) AD 747 336 (1972)

    Google Scholar 

  3. Bowden F.P.and Tabor D.: The Friction and Lubrication of Solids Part 2 ( Clarendon, Oxford, 1964 )

    Google Scholar 

  4. Akhmatov A.S:. Molecular Physics of Boundary Friction, ( Israel Program for Scientific Translations Jerusalem 1966) 381.

    Google Scholar 

  5. Lim S.C.and Ashby M.F.: Wear-Mechanism Maps Acta metall. 35, 1, (1987) 1.

    Google Scholar 

  6. Lim S.C., Ashby M.F. and Brunton J.H.: Wear-Rate Transitions and their Relationship to Wear Mechanism. Acta metall. 35, 6, (1987) 1343.

    Article  Google Scholar 

  7. Cameron A.: Lubricant Chemistry and lTibology Chemistry, Boundary and Extreme Pressure Lubrication. I. Mech. C250 (1987) 355.

    Google Scholar 

  8. Johnson K.L Contact mechanics (Cambridge University Press 1985) 105.

    Google Scholar 

  9. Halling J.: The Tribology of Surface Coatings, Particularly Ceramics Proc. Instn. Engrs. 200 C1(1986) 31.

    Google Scholar 

  10. Georges J.M.: Colloidal Behaviour of Films in Boundary Lubrication, in Microscopic aspects of Adhesion and Lubrication, J.M. Georges Eds. Tribology series 7, Elsevier, Amsterdam, (1982) 729.

    Google Scholar 

  11. Hamer J.C., Sayles S.C. and Ionnanides E.: Partic le Deformation and Counterface when Relatively Soft Particles are Squashed, Tribology transact. 3, (1989) 281.

    Article  Google Scholar 

  12. Hill R.: “The mathematical theory of plasticity”, (Oxford Clarendon press, 1967) 240.

    Google Scholar 

  13. Kendall R.: Relevance of Contact Mechani cs to Powders, Elasticity, Friction and Agglomerate Strength, “Tribology in particulate technology”, Ed. B.J. Briscoe and M.J. Adams, pp. 91–99, (1987).

    Google Scholar 

  14. Frewing J.J, The Heat of Adsorption of Long Chain Compounds and their Effect on Boundary Lubrication Proc. Royal Soc., A182 (1944) 236.

    Google Scholar 

  15. Grew W.J.S. and Cameron A. Thermodynamics of Boundary Lubrication and Scuffing, Proc. Royal Soc., A327, 47–59 (1972)

    Article  ADS  Google Scholar 

  16. Ho T., Hard and Soft Acids Bases Principle in Organic Chemistry, Academic Press (1977)

    Google Scholar 

  17. Mori S., Imaizumi Y., Adsorption of Model Compounds of Lubricant on Nascent Surfaces of Mild and Stainless Steels under Dynamic Conditions S.T.L.E. 31, 4, (1987) 449.

    Google Scholar 

  18. Spikes H.A.: Additive-additive and Additive-surface Interactions in Lubrication, Lubrication Sci. 2, 1,(1989), 3. Cann P.M.E., Johnston G.J. and Spikes H.A.: The formation of thick films by phosphorous based Antiwear-additives I.Mech. E. Conf. on Tribology Friction Wear and Lubrication C208/87 543.

    Article  Google Scholar 

  19. Sakurai T., Ikoda S., and Okabe H.: The Mechanism of Reaction of Sulphur Compounds with Steel Surfaces during Boundary Lubrication, ASLE. Trans. 25, (1982) 117.

    Article  Google Scholar 

  20. Coy R.C. and Jones R.B.: The thermal degradation of E.P. Performance of Zinc Dialkyl Dithiophosphate on Steel, ASLE Trans. 24 (1981) 24.

    Article  Google Scholar 

  21. Georges J.M., Mathia T., Kapsa Ph., Meille G. and Montes H.: Mechanism of Boundary Lubrication with Zinc Dithiophosphate, Wear, 53 (1979), 9.

    Article  Google Scholar 

  22. Furey M.: The Formation of Polymeric Films Directly on Rubbing Surfaces to Reduce Wear, Wear, 26 (1973) 369.; and Models of Tribopolymerisation as an Anti-Wear Mechanism: Proceed. of the Japan Int. Tribology Conf. Nagoya (1990) 1089.

    Article  Google Scholar 

  23. Meyer K., Weh K. and Berndt H.: Antiverschleisswirksamkeit polykondensationfâhriger Additive, Schmierungstechnik, 12, (1981) 691.

    Google Scholar 

  24. Masuko M, Ohmori T. and Okabe H.: Anti-Wear Properties of Hydroxycarboxylic Acids with Alkyl Chains, Tribology Int. 21, 4 (1988) 199.

    Article  Google Scholar 

  25. Godet M.,: The “third-body” approach: a mechanical view of wear., Wear 100 (1984) 437.

    Article  Google Scholar 

  26. Martin J.M., Mansot J.L., Berbezier I., and Belin M.: Microstructnral ASpects of Lubricated Mild-Wear with Zinc Dithiophosphate, Wear, 107, pp. 355–366 (1986). Belin M., Martin J.M. and Mansot J.L.: Role of Iron in the Amorphisation Process in Friction-Induced Phosphate Glasses, STLE Trans. 3 (1989) 410.

    Article  Google Scholar 

  27. Greaves G.N.: Local Order in Oxide Glasses, Proc. Int. Conf. Frascati, Italia (1982).

    Google Scholar 

  28. Watkins R.C.: The Anti-Wear Mechanism of ZDDP, part II, Tribology Int., 15, pp. 13–15 (1982).

    Article  Google Scholar 

  29. Hsu S.H., Klaus E.E, and Cheng H.S.: A Mechano-Chemical Descriptive Model for Wear under Mixed Lubrication Conditions, Wear, 128 (1988) 307.

    Article  Google Scholar 

  30. Marsh J.F.: Colloidal Lubricant Additives, Chemistry and Industry, 20 (1987) 470.

    Google Scholar 

  31. Kapsa Ph., Martin J.M., Blanc C., Georges J.M.: Anti-Wear Mechanism of ZDDP in the Presence of CAlcium Sulfonate Detergent, ASME Trans,Tribology J. 102 (1981) 486.

    Google Scholar 

  32. Georges J.M., Loubet J.L., Tonck A., Mazuyer D. and Hoonaert P.: ON the Mechanical Properties of Overbased Calcium Detergent Films, Proceedings of Japan International Tribology Conference, Nagoya, (1990) 517.

    Google Scholar 

  33. Elf Research Center Solaize 69 France.

    Google Scholar 

  34. Tonck A., Kapsa Ph, Sabot J.: Mechanical Behavior of Tribochemical Films under a Cyclic Tangental Load in a Ball-Flat Contact, ASME Trans., Tribology J., 108 (1986) 117.

    Article  Google Scholar 

  35. Mansot J.L., Martin J.M., Dexpert H., Faure D., Hoomaert P, Gallo R.: Local Structure AnaLysis in Overbased Reversed Micelles,, Physica B, 158 (1989) 237.

    Article  ADS  Google Scholar 

  36. Tonck A., Georges J.M. and Loubet J.L.: Measurements of Intermolecular Forces and Rheology of Dodecane between Alumina Surfaces, J. Colloid and Interface Sc., 126, 1 (1988) 150.

    Article  Google Scholar 

  37. Tonck A., Sabot J. and Georges J.M.: Microdisplacements between Two Elastic Bodies Separated by a Thin Film of Polystyrene, ASME Trans., Tribology J., 106 (1984) 35.

    Article  Google Scholar 

  38. Ehrburger F. and Lahaye J.: Behaviour of Colloidal Silicas during Uniaxial Compaction, J. Phys. France, 50, 11 (1989) 1349.

    Article  Google Scholar 

  39. Georges J.M., Loubet J.L. and Tonck A.: Molecular Contact Pressure in Tribology, in “New Materials Approaches to Tribology; Theory and Application”, L.E. Pope, L.L. Fehrenbacher, W.O. Winer Eds. M.R.S. (MRS Pittsburg, PA.) 140 (1989) 67.

    Google Scholar 

  40. Ashby M.F. and Jones D.H.: Int. Series. 34, Pergamon Press (1985).

    Google Scholar 

  41. Tabor D.: Friction and Wear-Developments over the last fifty years, Inst. Mech. Eng. C 245 (1987) 157.

    Google Scholar 

  42. Martin J.M., Belin M. and Mansot J.L.: Exafs of Calcium in Overbased Micelles, J. Phys. France, 47, 12, 887, (1986).

    Google Scholar 

  43. Bowers R.C. and Zisman W.A.: Pressre Effects on the Friction Coefficient of Thin-Film Solid Lubricants, J. Appl. Phys. 39, 12, (1968) 5385.

    Article  ADS  Google Scholar 

  44. Briscoe B.J. and Tabor D.: Shear Properties of Thin Polymeric Films, J. Adhesion, 9(1978) 145. and Briscoe B.J.: The Interfacial Friction of Polymer Composite Materials: General Fundamental Principles, in Friction and Wear of Composite Materials K. Freidrich Eds. (Elsevier Scientific Publishers 1985) chapt.2,39.

    Article  Google Scholar 

  45. Singer, I.L., Bolster R.N., Wegand J., Fayeulle S. and Stupp B.C.: Hertzian Stress Contribution to Low Friction Behavior of Thin MoS2 Coatings, Appl. Phys. Lett. 57, 10 (1990) 995.

    Article  ADS  Google Scholar 

  46. Georges J.M., Mazuyer D., Tonck A. and Loubet J.L.: Friction of Thin Colloidal Layer, J.Phys. Condo Mat. 2, (1990) 399.

    ADS  Google Scholar 

  47. By thin, we mean films whose thickness is much less than the Hertzian contact radius, which in these experiments varied from 10 to 200 mm.

    Google Scholar 

  48. Tabor D.: The role of Surface and Intermolecular Forces in Thin Film Lubrication, Microscopic aspects of Adhesion and Lubrication, J.M. Georges Eds. Tribology series 7, Elsevier, Amsterdam, (1982) 651.

    Google Scholar 

  49. Ducoulombier D., Zhou H., Boned C., Peyrelasse J., Saint-Guirons H., and Xans P: Viscosity of Liquid Hydrocarbons, J.Phys. Chem. 90 (1986) 1692.

    Article  Google Scholar 

  50. Bridgeman P.G.: Pressure Effect on hydrocarbons, Proc. Am. Acad. Arts Sci. 71, (1936), 387.

    Article  Google Scholar 

  51. Hallouis M., Mansot J.L. and Martin J.M.: Colloidal Anti-Wear Additives part II, Tribological, behavior., J. Colloid Int. To be publish.

    Google Scholar 

  52. Bell J.C. Delargy K.M. and Seeney A.M. The removal of substrate material through thick Zinc Dithiophosphate Antiwear Films. 18Th Leeds-Lyon Symposium 1991 (To be published.)

    Google Scholar 

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Georges, JM., Mazuyer, D., Loubet, JL., Tonck, A. (1992). Friction with Colloidal Lubrication. In: Singer, I.L., Pollock, H.M. (eds) Fundamentals of Friction: Macroscopic and Microscopic Processes. NATO ASI Series, vol 220. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2811-7_14

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  • DOI: https://doi.org/10.1007/978-94-011-2811-7_14

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5249-8

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