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Helium Atom Scattering Studies of the Surface Phonons of Layered Materials

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Surface Properties of Layered Structures

Abstract

The scattering of He atoms provides a nearly ideal probe of the structure and vibrations of crystal surfaces because the energy and momentum of the neutral He atoms match closely those of the surface phonons. Moreover He atoms are by virtue of their low energy only sensitive to the outer layer and are non-destructive and chemically inert. In this review we describe He scattering studies in which the surface phonon dispersion curves of the layered compounds of graphite, 21-1-TaSe2, iT-TaS27 GaSe and the high Te. superconductor Bi2Sr2CaCu2Os were measured. Despite the small coupling between the two-dimensional layers in the bulk of these systems, only the graphite surface behaves as predicted by theoretical modeling based on its bulk properties. The other surfaces show special phenomena such as phase changes, critical phenomena, charge-density-waves and commensurate-incommensurate behavior which are different than similar phenomena observed in the bulk.

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© 1992 Springer Science+Business Media Dordrecht

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Skofronick, J.G., Toennies, J.P. (1992). Helium Atom Scattering Studies of the Surface Phonons of Layered Materials. In: Benedek, G. (eds) Surface Properties of Layered Structures. Physics and Chemistry of Materials with Low-Dimensional Structures, vol 16. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2684-7_4

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  • DOI: https://doi.org/10.1007/978-94-011-2684-7_4

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