Abstract
Using the European Union System for the Evaluation of Substances (EUSES) and the Geography-referenced Regional Exposure Assessment Tool for European Rivers (GREAT-ER) regional exposure assessments were performed for the polycyclic musk fragrance HHCB (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl-cyclopenta-[g]-2-benzopyrane; trade name: e.g. Galaxolide®), Starting with a generic standard region a spatial refinement was carried out for the German River Ruhr region. The refinement was realised in different scenarios by successively replacing EUSES default parameters with realistic regional values and then applying the selected region to GREAT-ER. The results were compared to monitoring data from the region of North Rhine-Westphalia (River Ruhr). It was shown that EUSES estimates the median of the measured values very well in every scenario. Spatial refinement leads to lower concentrations. Even underestimations are possible if realistic regional parameters are inserted and a ready biodegradability is assumed. The lowest deviations to measured values are the average concentrations calculated by GREAT-ER, however, much more data are needed to perform a reasonable regional assessment. Furthermore, assuming the same region, the predicted concentrations of EUSES and GREAT-ER do not differ by more than a factor of 5. In addition, GREAT-ER delivers realistic regional information with visualised concentration profiles and maps.
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References
EC (1996). Technical Guidance Document in Support of the Commission Directive 93/67/EEC on Risk Assessment for New Notified Substances and the Commission Regulation (EC) 1488/94 on Risk Assessment for Existing Substances, Parts I–IV. Office for Official Publications of the European Communities, Luxembourg
EC (1996). EUSES — the European Union System for the Evaluation of Substances. Institute of Public Health and the Environment (RIVM), The Netherlands. Available from European Chemicals Bureau, Ispra
ECETOC (1999). GREAT-ER User Manual. Special Report No. 16. ECETOC, Brussels
Matthies, M.; J.-O. Wagner; F. Koormann (1997). Combination of Regional Exposure Models for European Rivers with GIS Information. In: Proceedings of ECO-INFORMA’ 97 (Eds. K. Alef et al.), Vol. 12, 523–529, Eco-Informa Press, Bayreuth
Boeije, G.; J.-O. Wagner; F. Koormann; P. Vanrolleghem; D. Schowanek; T. Feijtel (1999). New PEC Definitions for River Basins applicable to GIS-based Environmental Exposure Assessment (Contribution to GREAT-ER #8), Chemosphere (accepted)
Ohloff, G. (1990). Riechstoffe und Geruchssinn: Die molekulare Welt der Düfte. Springer, Heidelberg
Rimkus, G.; H. Brunn (1996). Synthetische Moschusduftstoffe — Anwendung, Anreicherung in der Umwelt und Toxikologie; Teil 1: Herstellung, Anwendung, Vorkommen in Lebensmitteln, Aufnahme durch den Menschen. Ernährungs-Umschau 43, 442–449
Bester, K.; H. Hühnerfuss; W. Lange; G. Rimkus; N. Theobald (1998). Results of non target screening of lipophilic organic pollutants in the German Bight II: Polycyclic Musk Fragrances. Water Research 32, 1857–1863
Eschke, H.D.; J. Traud; H.J. Dibowski (1994). Untersuchungen zum Vorkommen polycyclischer Moschus-Duftstoffe in verschiedenen Umweltkompartimenten -Nachweis und Analytik mit GC/MS in Oberflächen-, Abwässern und Fischen (1. Mitteilung). Z. Umweltchem. Ökotox. 6, 183–189
Eschke, H.D.; J. Traud; H.J. Dibowski (1995). Untersuchungen zum Vorkommen polycyclischer Moschus-Duftstoffe in verschiedenen Umweltkompartimenten -Befunde in Oberflächen-, Abwässern und Fischen sowie in Waschmitteln und Kosmetika (2. Mitteilung). Z. Umweltchem. Ökotox. 7, 131–138
Eschke, H.D.; J. Traud; H.J. Dibowski (1995). Nachweis und Quantifizierung von polycyclischen Moschus-Duftstoffen mittels Ion-Trap GC/MS/MS in Humanfett und Muttermilch. Dt. Lebensmittel-Rundschau 12, 375–379
Rimkus, G.; M. Wolf (1996). Polycyclic musk fragrances in human adipose tissue and milk. Chemosphere 33, 2033–2043
Winkler, M.; G. Kopf; C. Hauptvogel; T. Neu (1998). Fate of artificial musk fragrances associated with suspended particulate matter (SPM) from the River Elbe (Germany) in comparison to other organic contaminants. Chemosphere 37, 1139–1158
Gatermann, R.; J. Hellou; H. Hühnerfuss; G. Rimkus; V. Zitko (1999). Polycyclic and Nitro Musks in the Environment: A comparison between Canadian and European Aquatic Biota. Chemosphere 38, 3431–3441
Spencer, P.S.; A.B. Sterman; D.S. Horopian; M.M. Foulds (1979). Neurotoxic fragrance produces ceroid and Myelin Disease. Science 20, 633–635
Plassche, E.J. van de; F. Balk (1997). Environmental risk assessment of the polycyclic musks AHTN and HHCB accord ing to the EU-TGD. National Institute of Public Health and the Environment (RIVM), Report 601503008, Bilthoven
Schwartz, S.; V. Berding; M. Matthies (1999). Aquatic Fate Assessment of the Polycyclic Musk Fragrance HHCB -Scenario and Variability Analysis in Accordance with the EU Risk Assessment Guidelines. Chemosphere (accepted)
Schwartz, S.; V. Berding; M. Matthies (1999). Umweltexpositionsabschätzung des polycyclischen Moschus-Duftstoffes HHCB -Szenarienanalyse mit EUSES. Umweltmed. Forsch. Prax. 4, 7–11
AWWR (1997). Ruhrwassergütebericht. The study group of the waterworks at the Ruhr (AWWR) and Ruhrverband, Essen
Berding, V.; S. Schwartz; M. Matthies (1999). Visualisation of the Complexity of EUSES. Environ. Sci. & Pollut. Res. 6, 37–43
Berding, V.; S. Schwartz; M. Matthies (1999). Scenario analysis of a Level III multimedia model using generic and regional data. Environ. Sci. & Pollut. Res. (submitted)
Feijtel, T.C.J.; G. Boeije; M. Matthies; A. Young; G. Morris; C. Gandolfi; B. Hansen; K. Fox; M. Holt: V. Koch; R. Schröder; G. Cassani; D. Schowanek; J. Rosenblom; H. Niessen (1997). Development of a Geography-referenced Regional Exposure Assessment Tool for European Rivers GREAT-ER; Chemosphere 34 (11), 2351–2374
Struijs, J. (1996): SimpleTreat 3.0: a model to predict the distribution and elimination of chemicals by sewage treatment plants. Report No. 719101025. National Institute of Public Health and Environmental Protection (RIVM), Bilthoven, The Netherlands
Boeije, G. (1999). Chemical fate prediction for use in the gee-referenced environmental exposure assessment, PhD thesis, University of Gent, Belgium
Dyck, S. (1980). Angewandte Hydrologie, Teil 1 — Berechnung und Regelungdes Durchflusses der Flüsse. Ernst, Berlin, München, Germany
Bundesanstalt fur Gewässerkunde (1993). Jahrbuch Bundesrepublik Deutschland, (German Hydrologic Yearbook, Federal Institute of Hydrology) Koblenz, Germany
Round, C.E., A.R. Young; K. Fox (1998). A regional1y applicable model for estimating flow velocity at ungauged river sites in the UK. Journal of the Chartered Institution of Water and Environmental Management 12(6), 402–405
Ruhrverband (1999). Basic information on sewage treatment plants of the Ruhrverband — Personal communication. Ruhrverband (Institution for River Ruhr Water Management), Essen
NRW (1994). Ternes Jahresberichte, Tabellenband 1994. Landesumweltamt Nordrhein-Westfalen, Düsseldorf
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Berding, V., Koormann, F., Schwartz, S., Wagner, JO., Matthies, M. (2001). Spatial Refinement of Regional Exposure Assessment. In: Linders, J.B.H.J. (eds) Modelling of Environmental Chemical Exposure and Risk. NATO ASI Series, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0884-6_18
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DOI: https://doi.org/10.1007/978-94-010-0884-6_18
Publisher Name: Springer, Dordrecht
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