Abstract
Photoelectron spectroscopy is concerned with the study of ionic states in atoms, molecules and solids. It has developed to become a very useful tool for the understanding of the electronic structure of the system. Actually it is not just a single type of spectroscopy but represents rather a spectrum of spectroscopies. The incident radiation may be varied both in type and energy. The most frequent excitation sources are UV radiation (HeI line at 21.21eV, HeII line at 40.8eV, X-rays of various energies and nowadays also synchroton radiation as well as electrons ((e,2e)-spectroscopy) or excited atoms (Penning ionization). The electrons and/or ions formed in the process can be spectro-scopically examined. There also exists the possibility of coincidence measurements which may supply additional data. The photoelectron spectrum (PES) contains a lot of information. There are the different electronic states, each ionization process giving rise to a band. These bands show vibrational and rotational structure in the case of molecules.
This article consists of a set of lectures given by one of the authors (WVN) at the NATO Advanced Study Institute on the Island of Cos, Greece, June 4–18, 1978
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von Niessen, W., Cederbaum, L.S., Domcke, W. (1978). On Green’s Function Methods for the Study of Ionic States in Atoms and Molecules. In: Nicolaides, C.A., Beck, D.R. (eds) Excited States in Quantum Chemistry. NATO Advanced Study Institutes Series, vol 46. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9902-2_8
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