Abstract
The application of physical methods is extremely important for the inorganic chemist [1], The fact that computer controlled, automated, four circle diffractometers are commercially available has led to a renaissance in inorganic chemistry in the last two decades. (The structural variety of inorganic compounds is much larger than that of organic ones). Though the knowledge of the geometric structure of a compound is necessary to understand its properties, the important information about the electron distribution in molecules can only be obtained from spectroscopic methods (like NMR, ESR, UP, XP, UV/VIS/NIR, IR, Raman, Mossbauer and, NQR spectroscopy) [1–3]. Before the application of a single crystal structure determination was routine, infrared spectra were mostly used for obtaining information about the structure of compounds.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 3rd ed.; Wiley-Interscience, New York, 1972.
H. A. O. Hill and P. Day (Ed.), Physical Methods in Advanced Inorganic Chemistry, Interscience Publishers, London, 1968.
P. Day (Ed.), Electronic States of Inorganic Compounds: New Experimental Techniques, D. Reidel, Dardrecht, Holland, 1975.
F. J. Comes, A. Müller, and W. J. Orville-Thomas (Ed.), Spectroscopy in Chemistry and Physics - Modern Trends, Elsevier, Amsterdam, 1980.
P. R. Griffith, Chemical Infrared Fourier Transform Spectroscopy, Wiley-Interscience, New York, 1975.
J. R. Ferraro and L. Basile (Ed.), Fourier Transform Spectroscopy, Application to Chemical Systems, Vol. 1 and Vol. 2, Academic Press, New York, 1978.
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, 3rd Ed., Wiley-Interscience, New York, 1977.
H. Siebert, Anwendungen der Schwingungsspektroskopie in der Anorganischen Chemie, Springer-Verlag, Berlin, 1966.
W. H. Chan, R. J. Nordstrom, J. G. Calvert and J. H. Shaw, Env. Sci. Technol., 10, 674 (1976).
M. J. D. Low, A. J. Goodsel, and N. Takezawa, Env. Sci. Technol., 5, 1191 (1971).
A. J. Goodsel, M. J. D. Low, and N. Takezawa, Env. Sci. Technol., 6, 268 (1972).
M. J. D. Low, A. J. Goodsel, and H. Mark, in Molecular Spectroscopy, ( P. Hepple, ed.), Inst, of Petroleum, London, 1972.
M. J. D. Low and J. C. McManus, Chem. Comm., 1166 (1967).
M. J. D. Low and I. Colema, Appl. Opt., 5, 1453 (1966).
S. S. Barshay and J. S. Lewis, Icarus, 33, 593 (1978).
J. G. Moehlmann, J. T, Gleaves, J. W. Hudgens, and J. D. McDonald, J. Chem. Phys., 60, 4790 (1974).
P. L. Hanst, W. E. Wilson, R. K. Patterson, B. W. Gay Jr., L. W. Chaney, and C. S. Burton, Rep. No. EPA-650/4-75-006. Environ. Prot. Agency, Research Triangle Park, North Carolina (1975)
D. S. Erley and B. H. Blake, Infrared Spectra of Gases and Vapors, Vol. 2., Dow Chem. Co., Midland, Michigan, 1965.
R. H. Pierson, A. N. Fletcher, and E0 St. Clair Gantz, Anal. Chem., 28, 1218 (1956).
P. L. Hanst, A. S. Lefohn, and B. W. Gay Jr., Appl. Spectrosc., 27, 188 (1973).
P. L. Hanst, Adv. Env. Sci. Technol., 2, 91 (1971).
J. N. Pitts, J. M. McAfee, W. D. Long, and A. M. Winter, Env. Sci. Technol., 10, 787 (1976).
A. Müller, “Isotopic Substitution” in Vibrational Spectroscopy Modern Trends, ( A. J. Barnes and W. J. Orvilie-Thomas, ed.), Elsevier, Amsterdam, 1977.
F. Königer and A Müller, J. Mol. Spectrosc., 65, 339 (1977).
A. Müller and F. Königer, J. Mol. Struct., 30, 195 (1976).
F. Königer, C. E. Blom, and A. Müller, J. Mol. Spectrosc., 77, 76 (1979).
H. Bürger, S. Dobos, P. Schulz, and A, Ruoff, J. Mol. Spectrosc., in press.
K. Burczyk, H. Bürger, P. Schulz, and A. Ruoff, to be published.
D. M. Adams, Metal-Ligand and Related Vibrations, Arnold, London, 1967.
K. H. Schmidt and A. Müller, Coord. Chem. Rev., 19, 41 (1976).
N. Mohan, A. Müller and K. Nakamoto, “Metal Isotope Effect on Molecular Vibrations” in Advances in Infrared and Raman Spectroscopy, Vol 1, R. J. H0 Clark and R E. Hester, (ed.), p. 173, Heyden, London, 1975.
R. T. Hall, and J. M. Dowling, J. Chem. Phys., 45, 1899 (1966).
A. Anderson, S. H. Walmsley, and H A. Gebbie, Phil. Mag., 7, 1243 (1962).
A. Anderson,. S. H. Walmsley, and H. A. Gebbie, Phil. Mag., 7, 1243 (1962).
S. H. Walmsley and A. Anderson, Mol. Phys., 7, 411 (1964).
A. Anderson and S. H. Walmsley, Mol. Phys., 9, 1 (1965).
A. Anderson and S. H. Walmsley, Mol. Phys., 7, 583 (1964).
A. Anderson and S. H. Walmsley, Mol. Phys., 10, 391 (1966).
R. F. Lake and H. W. Thompson, Proc. Roy. Soc. (London), A291, 469 (1966).
H. A. Gebbie, W. J, Burroughs, J. Chamberlain, J. E. Harries, and R. G. Jones, Nature, 221, 143 (1969).
S. G. Kroon and J. van der Elsken, Chem. Phys. Lett., 1, 285 (1967).
H. A. Gebbie, N. W. B. Stone, F. D. Findlay, and E. C. Pyatt, Nature (London), 205, 377 (1965).
N. E. Hill, Proc. Phys. Soc., 78, 311 (1961).
R. J. Jakobsen and J. W. Brasch, J. Am. Chem. Soc., 86, 3571 (1964).
J. E. Harries, N. R. W. Swann, J. E. Beckman, and P. A. R. Ade, Nature (London), 236, 159 (1972).
J. R. Durig, S. M. Craven, and W. C. Harris, “Determination of Torsional Barriers from Far-Infrared Spectra” in Vibrational Spectra and Structure, Vol. 1, ( J. R. Durig, ed.), Marcel Dekker, New York, 1972.
Ibid: C. S. Blackwell and R. C. Lord, “Far-Infrared Spectra of Four-Membered-Ring Compounds”; and J. Laane, “Pseudo-rotation of Five-Membered Rings”.
W. H. Smith and G. E. Leroi, J. Chem. Phys., 45, 1778 (1966).
L. A. Carreira, R. O. Carter, J. R0 Durig, R C. Lord, and C. C. Milionis, J. Chem. Phys., 59, 1028 (1973).
G. A. Ozin, Catal. Rev. Sci. Eng., 16, 191 (1977).
A. Müller, R. Jostes and F. A Cotton, Angew. Chem., (in press).
T0 G. Spiro, Progress in Inorg. Chem., 11, 1 (1970).
A. Müller and W. Jaegermann, Inorg. Chem., 18, 2631 (1979).
A. Müller and U. Reinsch, Angew. Chem., 92, 69 (1980); Angew. Chem. Int. Ed. Engl., 19, 72 (1980).
M. Laing, P. M. Kieran, and W. P. Griffith, Chem. Comm., 221 (1977).
W. P. Griffith, P. M, Kieran, and B. P. O’Hare, J. Mol. Struct., 46, 307 (1978).
C. Perrin, A. Perrin, and P. Caillet, J. Chim Phys., 70, 105 (1972–1973).
A. Müller et al., unpublished results.
A. Müller et al., unpublished results.
A. Müller et al., unpublished results.
S. J. Cyvin, A. Müller et al., unpublished results.
L. E. Lyhamn, S. J. Cyvin, B. N. Cyvin, and J. Brunvoll, Z. Naturforsch., 31a, 1589 (1976).
S. J. Cyvin, B. N. Cyvin, W. Brockner, and A. F. Demiray, Z. Naturforsch., 33a, 714 (1978).
A. Müller, W. O. Nolte, S. J. Cyvin, B. N. Cyvin, and A. J. P. Alix, Spectrochim. Acta, 34A, 383 (1978).
J. C. Whitmer and S. J. Cyvin, J. Mol. Struct., 50, 21 (1978).
L. E. Lyhamn and S. J. Cyvin, Z. Naturforsch., 34a, 867 (1979).
A. Müller, H. BÖgge, U. Schimanski, and T. K. Hwang, Chem. Comm., 91 (1980).
A. Müller, H. Bogge, E. Koniger-Ahlborn, and W. Hellmann, Inorg. Chem., 18, 2301 (1979) and references cited therein.
A. Müller, R. Jostes, V. Flemming, and R. Potthast, Inorg. Chim. Acta, 44, L33 (1980).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1980 D. Reidel Publishing Company
About this paper
Cite this paper
Müller, A. (1980). Application of FT-IR to Inorganic Species and Problems in Inorganic Chemistry. In: Durig, J.R. (eds) Analytical Applications of FT-IR to Molecular and Biological Systems. NATO Advanced Study Institutes Series, vol 57. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9070-8_16
Download citation
DOI: https://doi.org/10.1007/978-94-009-9070-8_16
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-009-9072-2
Online ISBN: 978-94-009-9070-8
eBook Packages: Springer Book Archive