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Segregation at Interfaces

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Chemistry and Physics of Fracture

Part of the book series: NATO ASI Series ((NSSE,volume 130))

Abstract

Surfaces, grain boundaries and interfaces of inclusions or precipitates are a sink for elements dissolved in metals. The segregation of dissolved C, Si, P, Sn…to interfaces in Fe, Ni and other metals or alloys leads to an enrichment in the range of one or only a few monolayers at and near the interfaces. This equilibrium segregation is induced by the decrease of interfacial energy upon segregation, additionally a release of elastic energy occurs in case of the interstitial elements which are too large in size for the interstices, and in case of substitutional elements being larger than the atoms of the host metal.

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Author information

Authors and Affiliations

  1. Max-Planck-Institut für Eisenforschung GMBH, 4000, Düsseldorf 1, Federal Republic of Germany

    H. J. Grabke

Authors
  1. H. J. Grabke
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Editor information

Editors and Affiliations

  1. Department of Materials Science and Engineering, Massachusetts Institute of Technology, Room 8-202, 02139, Cambridge, MA, USA

    R. M. Latanision

  2. Materials Science and Technology Department, Battelle Northwest Laboratories, P.O. Box 999, 99352, Richland, WA, USA

    R. H. Jones

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© 1987 Martinus Nijhoff Publishers, Dordrecht

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Grabke, H.J. (1987). Segregation at Interfaces. In: Latanision, R.M., Jones, R.H. (eds) Chemistry and Physics of Fracture. NATO ASI Series, vol 130. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3665-2_19

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  • DOI: https://doi.org/10.1007/978-94-009-3665-2_19

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8140-5

  • Online ISBN: 978-94-009-3665-2

  • eBook Packages: Springer Book Archive

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