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Part of the book series: Fundamental Theories of Physics ((FTPH,volume 31-32))

Abstract

We trace the development of the technical ideas showing that the Second Law of Thermodynamics became, over a Century ago, a general principle of reasoning, applicable to scientific inference in other fields than thermodynamics. Both the logic and the procedure of our present maximum entropy applications are easily recognized in the methods for predicting equilibrium conditions introduced by Gibbs in 1875. Chemical thermodynamics has been based on them ever since. What is new in this field is not the method, but the recognition of its generality.

The opening talk at the EMBO Workshop on Maximum-Entropy Methods in x-ray crystallographic and biological macromolecule structure detennination. Orsay, France, April 24–28, 1984.

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References

  • B. Alberts, D. Bray, J. Lewis, M. Raff, K. Roberts & J. D. Watson, Molecular Biology of the Cell, Garland Publishing Co., New York; pp. 550–609 (1983).

    Google Scholar 

  • Sadi Carnot, Reflexions sur la puissance motrice du feu, Bachelier, Paris, (1824).

    Google Scholar 

  • J. Willard Gibbs, “On the Equilibrium of Heterogeneous Substances”, Trans. Conn. Acad. Sci (1875-78). Reprinted in The Scientific Papers of J. Willard Gibbs, Vol. 1; Dover Publications, Inc., N. Y. (1961).

    Google Scholar 

  • C. C. Gillispie, Lazare Carnot, Savant, Princeton University Press (1971). A technical analysis of his work, and its relation to that of his son Sadi. Original manuscripts.

    Google Scholar 

  • E. T. Jaynes, “The Minimum Entropy Production Principle”, in Annual Review of Physical Chemistry, Vol. 31, 579–601 (1980). Reprinted in E. T. Jaynes, Papers on Probability, Statistics and Statistical Physics, R. Rosenkrantz, Ed., D. Reidel Publishing Co., Dordrecht-Holland (1983)

    Google Scholar 

  • A. L. Lehninger, Bioenergetics, W. A. Benjamin, N. Y. (1965)

    Google Scholar 

  • A. L. Lehninger, Biochemistry, the Molecular Basis of Cell Structure and Function, Worth Publishers, Inc., 444 Park Ave. South, New York, N. Y. (1975).

    Google Scholar 

  • L. Onsager, Phys. Rev. 37, 405; 38, 2265 (1931)

    Article  MATH  Google Scholar 

  • M. Planck, Scientific Autobiography, Philosophical Library, N. Y. (1949); pp.17–18.

    Google Scholar 

  • M. Reinhard, Le Grand Carnot, 2 vols., Paris, 1950–52.

    Google Scholar 

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© 1988 Kluwer Academic Publishers

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Jaynes, E.T. (1988). The Evolution of Carnot’s Principle. In: Erickson, G.J., Smith, C.R. (eds) Maximum-Entropy and Bayesian Methods in Science and Engineering. Fundamental Theories of Physics, vol 31-32. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3049-0_15

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  • DOI: https://doi.org/10.1007/978-94-009-3049-0_15

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7871-9

  • Online ISBN: 978-94-009-3049-0

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