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Problems of Micromixing Effects and Reactor Performance in Free Radical Polymerization of Binary and Ternary Systems

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Integration of Fundamental Polymer Science and Technology—4

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Abstract

On the basis of experimental data obtained from copolymer systems composed of donor, acceptor and neutral monomers the copolymerization behaviour as a function of the conversion degree was derived. The heterogeneity of the composition was calculated for experiments carried out under discontinuous process conditions (batch reactor). The influence of the reaction conditions on the chemical polydispersity was investigated in connection with continuous process conditions. The effects of incomplete micromixing on free radical copolymerization processes are presented and discussed by model calculations.

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References

  1. Hay, W.H., Mathematical modeling of polymerization reactors. J Macromol. Sci. - Rev. Macromol. Chem. 1972, C8, pp.1–15.

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  2. Schmidt-Naake, G., Schmidt H. and Engelmann, U., Zum Copolymerisationsverhalten von ternaeren Donator- Accep tormonomeren bei kontinuierlicher Reaktionsfuehrung. Angew. Makromol. Chemie, submitted.

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  3. Sharma, D.K. and Soane, D.S., High-conversion diffusion controlled copolymerization kinetics. Macromolecules, 1988, 21, pp. 700–710.

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  4. Schmidt-Naake, G., Seifert, P. and Noriega, M., Einfluss der Mikromischung auf die radikalische Polymerisation. Chemische Technik, 1989, submitted.

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  5. Schmidt-Naake, G., Schmidt, H. and Hamann B., Vergleich diskontinuierlicher und kontinuierlicher Experimente be der radikalischen Copolymerisation, Acta Polymerica, submitted.

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Author information

Authors and Affiliations

  1. Sektion Chemie, Technische Universitaet Dresden, Mommsenstrasse 13, DDR-8027, Dresden, Germany

    Gudrun Schmidt-Naake, Hermann Schmidt & Winfried Pippel

Authors
  1. Gudrun Schmidt-Naake
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  2. Hermann Schmidt
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  3. Winfried Pippel
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Editor information

Editors and Affiliations

  1. Eindhoven University of Technology, Eindhoven, The Netherlands

    P. J. Lemstra

  2. DSM-Research, Geleen, The Netherlands

    L. A. Kleintjens

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© 1990 Elsevier Science Publishers Ltd

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Schmidt-Naake, G., Schmidt, H., Pippel, W. (1990). Problems of Micromixing Effects and Reactor Performance in Free Radical Polymerization of Binary and Ternary Systems. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—4. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0767-6_6

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  • DOI: https://doi.org/10.1007/978-94-009-0767-6_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6831-4

  • Online ISBN: 978-94-009-0767-6

  • eBook Packages: Springer Book Archive

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