Abstract
The behavior of the adsorption of H2 O2 and C0 on highly conducting doped polypyrrole has been studied using the gas chromatographic technique. A series of pictures which adsorbed amount and potential energy change correspondingly with temperature and the distance between the interaction of the adsorbate and adsorbent are obtained. The results are shown that the behavior of the adsorption is related to doped constituents and properties, as well as topologic property and distance between the molecules. From the adsorption of and C0 on the polypyrrole can see that due to the existence of H the amounts of C0 adsorbed increases apparently. H2 seems to be a “scavenger” or “cleaner” of the hole, but the exsistance of C0 inhibits the adsorption of H2. The relative adsorbed equations are obtained.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Reference
Liu, S.Z., Wu, L.Y., Zhang, B.F. and Yu, B.Q., Alcohol synthesis by PPCP molecular cluster catalysts, Proceedings of the Third International Meeting on Polymer Science and Technology, ed. P.J. Lemstra and L.A. Kleintjens, Elsevier Applied Science Publishers, London, to be published, 1988.
Armes, S.P., Optimum reaction conditions for the polymerization of pyrrole by iron(III) chloride in aqueous solution, Synth. Met., 1987, 20, 365–71.
Diaz, A.F. and Kanazwa, K.K., Electrochemical polymerization of polypyrrole, J.C.S. Chem. Comm., 1979, 14, 635–6.
Liu, S.Z., Gao, Y., Wu, L.Y., Yu, B.Q. and Jiang, S.M., Model study on the adsorption of small molecules on pure polypyrrole, Rolduc Polymer Meeting-4, 1989, April 23–27, The Netherlands, submitted
Gasser, R.P.H., An introduction to chemisorption and catalysis by Metals, Clarendon Press, Oxford, 1985, pp. 2–3.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1990 Elsevier Science Publishers Ltd
About this chapter
Cite this chapter
Liu, S.Z., Wu, L.Y., Gao, Y., Yu, B.Q., Jiang, S.M. (1990). Study on the Adsorption of Small Molecules on High Conducting Doped Polypyrrole by Chromatography. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—4. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0767-6_49
Download citation
DOI: https://doi.org/10.1007/978-94-009-0767-6_49
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6831-4
Online ISBN: 978-94-009-0767-6
eBook Packages: Springer Book Archive